首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4599篇
  免费   178篇
  国内免费   29篇
化学   2572篇
晶体学   51篇
力学   181篇
数学   1131篇
物理学   871篇
  2023年   42篇
  2022年   125篇
  2021年   137篇
  2020年   127篇
  2019年   157篇
  2018年   155篇
  2017年   144篇
  2016年   194篇
  2015年   150篇
  2014年   205篇
  2013年   337篇
  2012年   309篇
  2011年   324篇
  2010年   177篇
  2009年   196篇
  2008年   236篇
  2007年   204篇
  2006年   156篇
  2005年   126篇
  2004年   129篇
  2003年   95篇
  2002年   89篇
  2001年   77篇
  2000年   58篇
  1999年   39篇
  1998年   30篇
  1997年   38篇
  1996年   52篇
  1995年   42篇
  1994年   33篇
  1993年   42篇
  1992年   36篇
  1991年   37篇
  1990年   31篇
  1989年   23篇
  1988年   28篇
  1987年   37篇
  1986年   39篇
  1985年   35篇
  1984年   27篇
  1983年   25篇
  1982年   32篇
  1981年   29篇
  1980年   22篇
  1979年   37篇
  1978年   28篇
  1977年   21篇
  1976年   23篇
  1975年   20篇
  1974年   14篇
排序方式: 共有4806条查询结果,搜索用时 15 毫秒
101.
Radiochemical neutron activation analysis (RNAA) has been applied for determination of rare earth elements (REE) in Vietnamese monazite. The chemical separation procedure used is based on the chromatographic elution of rare earth groups, after the separation of233Pa(Th) in irradiated monazite samples by coprecipitation with MnO2, the rare earth elements were retained by Biorad AG1×8 resin column in 10% 15.4M HNO3-90% methanol solution. The elution of heavy rare earth (HREE) and middle rare earth (MREE) groups was carried out with 10% 1M HNO3-90% methanol and 10% 0.05M HNO3-90% methanol solution, respectively; while the light rare earths (LREE) were eluted from the column by 0.1M HNO3 solution. The accuracy of the method was checked by the analysis of granodiorite GSP-I and the rare earth values were in good agreement.  相似文献   
102.
D-D4FC (1) is an anti-HIV agent currently under phase II clinical trial (Pharmaset Inc). Its molecular architecture is suitable for a Ferrier rearrangement kind of operation on a furanoid glycal to fix the position of the double bond and the relative stereochemistry. Despite the fact that classical Ferrier rearrangement does not work on furanoid glycals, a palladium mediated modified protocol has been developed for the glycosidation of an aromatization prone xylo-furanoid glycal (5) for the synthesis of D-D4FC.  相似文献   
103.
104.
The electronic and geometric structures, energy stability, normal mode frequencies, and spin density distribution have been calculated by the density functional theory B3LYP method with the Gen = 6-31+G*(Fe) + 6-31G(C,H,N,O), 6-31G*, and 6-311++G** basis sets for the deep fragmentation products of the free hemin ion with successive removal of methyl and vinyl groups in the electronic states with different multiplicities. The computation results are compared with the available experimental data and previous computation results for the fragmentation products of the isolated heme molecule and hemin ion with removal of carboxymethyl groups. The trends in the behavior of these properties are analyzed as a function of multiplicity, external charge, and the number of peripheral substituents at the porphyrin core.  相似文献   
105.
106.
107.
Conclusions The simple synthesis of optically active R,Z-14-methyl-8-hexadecenal (cis-trogodermal), the principal components of the aggregation pheromone ofTrogoderma granarium, was accomplished. The synthesis was based on the use of R-1-bromo-4-methylhexane and Z-4-chloro-2-buten-1-ol as the sources of the chiral and olefin fragments.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 906–910, April, 1987.  相似文献   
108.
The binding energies and other characteristics of the light 1P-shell nuclei (N, Z8) are calculated. We use the method denoted as modified oscillator shell model (MOSM), proposed by one of the authors (Nguyen tien Nguyen: Czech. J. Phys. B31 (1981) 16). We succeed in choosing the parameter set of the Skyrme-type force, which gives satisfactory and interesting results.On leave fromFaculty of Physics, Hanoi University, Vietnam.The authors would like to thank I. Wilhelm for the useful discussion.  相似文献   
109.
Exposure of (C5H5)2MO(CH3)2 and (C5H5)2W(CH3)2, prepared from the corresponding dichlorides, to 20Co γ-rays at 77 K gave H2C.CML3 carbene species characterised by their ESR spectra, together with a central feature possibly due to the parent cations. Dilute solutions in CD3OD gave features assigned to the parent anions which were converted on bleaching with visible light into methyl radicals, and H2C.ML3 radicals. From the magnitude of the 1H and 183W hyperfine coupling constants, it is deduced that the SOMO for H2C.WL3 radicals is strongly localised on carbon.Dilute solutions in aqueous sulphuric acid also gave species with A(2H) = 20 G, identified as the carbene derivatives, H2C.Ml3. These were formed on annealing, as signals assigned to HSO4 · radicals were lost.  相似文献   
110.
Selective thinning of forests in the western United States will generate a large, sustainable quantity of softwood residues that can be an attractive feedstock for fuel ethanol production. The major species available from thinning of forests in northern California and the eastern Rocky Mountains include white fir (Abies concolor), Douglas fir (Pseudotsuga menziesii), and Ponderosa pine (Pinus ponderosa). Douglas fir chips were soaked in 0.4% sulfuric acid solution, then pretreated with steam at 200 – 230°C for 1 – 5 min. After pretreatment, 90 – 95% of the hemicellulose and as much as 20% of the cellulose was solubilized in water, and 90% of the remaining cellulose can be hydrolyzed to glucose by cellulase enzyme. The prehydrolysates, at as high as 10% total solid concentration, can be readily fermented by the unadapted yeastSaccharomyces cerevisiae D5A.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号