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31.
Solid-matrix phosphorescence (SMP) spectra and lifetimes were used to characterize the (±)-anti-benzo[a]pyrene diolepoxide [(±)-anti-B[a]PDE] and (±)-anti-dibenzo[a,l]pyrene diolepoxide [(±)-anti-DB[a,l]PDE] bonded to the same sample of DNA. SMP spectra and lifetimes were also acquired for two samples of DNA that had only (±)-anti-B[a]PDE or (±)-anti-DB[a,l]PDE bonded to the individual samples of DNA. A detailed comparison of the SMP properties was made among the three samples of DNA. The SMP excitation spectra for the (±)-anti-B[a]PDE-DNA and the (±)-anti-DB[a,l]PDE-DNA adducts were very similar. However, the SMP emission spectra of the two DNA adduct systems were very dissimilar with a major emission band for the (±)-anti-B[a]PDE-DNA adducts appearing at 613 nm and for the (±)-anti-DB[a,l]PDE-DNA adducts a major band was at 558 nm. It was possible to selectively use SMP emission wavelengths and obtain a SMP excitation of spectrum of the (±)-anti-DB[a,l]PDE-DNA adducts in the dual adducted DNA sample without the (±)-anti-B[a]PDE-DNA adducts emitting SMP. In addition, it was shown that the SMP emission spectrum of the dual adducted DNA sample could be used to detect both adduct systems in the modified DNA sample. It was demonstrated that the SMP lifetimes could be effectively employed to characterize the dual adducted DNA sample. For example, the SMP decay curve for the (±)-anti-DB[a,l]PDE-DNA adducts could be acquired without any SMP emission from the (±)-anti-B[a]PDE-DNA adducts. Also, ln(SMP intensity) versus time plots were very useful in characterizing the dual adducted DNA sample.  相似文献   
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We exhibit the elliptic Calogero–Moser system as a Hitchin system of G-principal Higgs pairs. The group G, though naturally associated to any root system, is not semi-simple. We then interpret the Lax pairs with spectral parameter of d'Hoker and Phong [dP1] and Bordner, Corrigan and Sasaki [BCS1] in terms of equivariant embeddings of the Hitchin system of G into that of GL(N). Received: 8 May 2000 / Accepted: 2 July 2001  相似文献   
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本文报导了采用氩离子激光器来泵浦Pr3+:YLF晶体,应用声光调制器实现了主动锁模;同时应用振动─高反射平面镜也实现了被动锁模,两种锁模均得到了ps光脉冲.据作者了解这是这种晶体材料的第一次锁模运转.  相似文献   
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The approach to isospectral Hamiltonian flow introduced in part I is further developed to include integration of flows with singular spectral curves. The flow on finite dimensional Ad*-invariant Poisson submanifolds of the dual of the positive part of the loop algebra is obtained through a generalization of the standard method of linearization on the Jacobi variety of the invariant spectral curveS. These curves are embedded in the total space of a line bundleTP 1(C), allowing an explicit analysis of singularities arising from the structure of the image of a moment map from the space of rank-r deformations of a fixedN×N matrixA. It is shown how the linear flow of line bundles over a suitably desingularized curve may be used to determine both the flow of matricial polynomialsL() and the Hamiltonian flow in the spaceM N,r×MN,r in terms of -functions. The resulting flows are proved to be completely integrable. The reductions to subalgebras developed in part I are shown to correspond to invariance of the spectral curves and line bundles under certain linear or anti-linear involutions. The integration of two examples from part I is given to illustrate the method: the Rosochatius system, and the CNLS (coupled non-linear Schrödinger) equation.Research supported in part by the Natural Sciences and Engineering Research Council of Canada and by U.S. Army grant DAA L03-87-K-0110  相似文献   
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