首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1232篇
  免费   166篇
  国内免费   133篇
化学   861篇
晶体学   10篇
力学   77篇
综合类   9篇
数学   159篇
物理学   415篇
  2024年   5篇
  2023年   33篇
  2022年   47篇
  2021年   57篇
  2020年   72篇
  2019年   55篇
  2018年   50篇
  2017年   53篇
  2016年   55篇
  2015年   48篇
  2014年   75篇
  2013年   98篇
  2012年   112篇
  2011年   103篇
  2010年   68篇
  2009年   55篇
  2008年   62篇
  2007年   69篇
  2006年   65篇
  2005年   52篇
  2004年   25篇
  2003年   30篇
  2002年   23篇
  2001年   26篇
  2000年   29篇
  1999年   23篇
  1998年   11篇
  1997年   11篇
  1996年   23篇
  1995年   10篇
  1994年   17篇
  1993年   9篇
  1992年   17篇
  1991年   10篇
  1990年   3篇
  1989年   2篇
  1988年   4篇
  1987年   7篇
  1986年   7篇
  1985年   3篇
  1984年   1篇
  1983年   1篇
  1982年   1篇
  1976年   1篇
  1970年   1篇
  1965年   1篇
  1958年   1篇
排序方式: 共有1531条查询结果,搜索用时 15 毫秒
51.
A model for competition between antibiotic-sensitive and antibiotic-resistant bacteria with nutrient recycling and antibiotic treatment in a chemostat is considered. The sufficient and necessary conditions for boundedness of the solution and existence of non-negative equilibria are derived. The extinction and uniform persistence of antibiotic-sensitive and antibiotic-resistant bacteria are also carried out. Numerical simulations are then given to illustrate our main results.  相似文献   
52.
Triarylaminium salt was disclosed as a highly efficient nonmetallic initiator for the Friedel–Crafts reaction between chalcone epoxides and heteroarenes to construct a series of complex β-heteroaryl α-ketols in mild conditions and with good yields. Chalcone epoxides were presented as valuable halogen-free pre-electrophile in Friedel–Crafts alkylation through the formation of the stabilized benzylic cation intermediates. A plausible radical cation chain mechanism was also proposed.  相似文献   
53.
54.
55.
In the present paper, we introduce some new subclasses of meromorphic starlike,convex, close-to-convex and quasi-convex functions of β-reciprocal in terms of the linear operator using subordination. We obtain the coefficient estimates, convolution properties, integral preserving properties and inclusion relationships of the classes. The results presented here include several results as their special cases.  相似文献   
56.
The polyhydroxyurethane/attapulgite nanocomposites (PHU/ATP) were prepared by in-situ surface-initiated polymerization of a five-membered cyclic carbonate, 2, 2-bis [p-(1, 3-dioxolan-2-one-4-yl-methoxy) phenyl] propane (B5CC) and hexamethylene diamine, from the surface of the aminopropyl attapulgite nanoparticles (APATP) for the first time. The chemical grafting of the polymer on the surface of ATP was confirmed by FTIR and the morphology of the attapulgite nanoparticles in the nanocomposites was examined by TEM. The thermal stabilities of the polyhydroxyurethane (PHU) and the polyhydroxyurethane/attapulgite nanocomposites (PHU/ATP) were compared with thermogravimetric analysis (TGA).The %G of the attapulgite nanoparticles was also calculated from the results of TGA after the free polyhydroxyurethane was washed off.  相似文献   
57.
58.
59.
Torreyanoxane, a novel 3,4‐secoglutinane triterpenoid, was isolated from the pulp of Torreya nucifera. The structure was determined on the basis of spectroscopic methods.  相似文献   
60.
A series of heterometallic LnIII–SbIII edta‐containing compounds with the formulas [Sb2(edta)2Ln]NO3 · nH2O [edta = ethylenediaminetetraacetate; Ln = Eu, n = 7 ( 1 ); Gd, n = 7.5 ( 2 ) and Tb, n = 8 ( 3 )] were synthesized and characterized by elemental analyses (EA), powder X‐ray diffraction (PXDP), Fourier transform infrared spectroscopy (FT‐IR), and thermogravimetric analyses (TGA). Their fluorescence and magnetic properties were also studied. The thermal analysis demonstrates the compounds formation of the antimony, lanthanide ions, and edta4– ligands. FT‐IR spectra reveal that the antimony and lanthanide ions are connected through the carboxylate bridges. The studies of luminescence properties show that compounds 1 and 3 exhibit typical luminescence in the visible region. Furthermore, magnetic properties reveal compounds 2 and 3 have weak ferromagnetic behavior.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号