Synthèse dc la pyrido[2,3-f] phtalazine et des diformyl-6,7; -4,6; -4,7; -2,4 quinoleines

This article describes the synthesis of a new heterocycle, pyrido[2,3,f]phtalazine and three new diformylquinolincs.     

Differential cross sections for the charge exchange process π+p → π0 (π+p) at 8, 16 and 23 GeV/c

The differential cross section $\text{d}\text{σ}\text{d}\text{t′}$ for the charge-exchange process π⁺p → π⁰ (π⁺p) at 8, 16 and 23 GeV/c is presented for several regions of the π⁺p effective mass. It is found that the dip at t′ ≈ 0.6 (GeV/c)² which is observed in the Δ(1236) mass band becomes a less pronounced structure in the higher mass regions. However, while the slope of the $\text{d}\text{σ}\text{d}\text{t′}$ distributions in the near-forward direction decreases strongly with increasing π⁺p mass, there is no evidence that the observed structure moves to higher values of t′ as the π⁺p mass increases. These results are consistent with a Regge-exchange picture where the position of the dip is determined by the exchanged trajectory, but are inconsistent with a simple geometrical picture.     

Synthèse des pyrido[2,3-d] el [3,2-d] -s-triazolo[3,4-f] pyrimidines el de (pyrazolyl-1')-4 pyrido[2,3-d] et [3,2-d] pyrimidines

The synthesis of two new heterocycles is described: pyrido-[2,3-d]-.s-triazolo[ 3,4-f] pyrimidine and pyrido[3,2-d]-.s-triayzolo-[3,4-f] pyrimidine. 4-[I'-Pyrazolyl]pyrido[2,3-d]pyrimidines and 4-[1′-pyrazoly1] pyrido[ 3,2-d] pyrimidine are obtained by the action of 4-hydrazinopyrido[2,3-d]pyrimidine and 4-hydrazinopyrido-[3,2-d]pyrimidine with several β-diketones.     

Impact parameter description of the charge exchange process π+ p → π° (π+ p)

The “Reggeometry” model — universal impact parameter profile and Reggen behaviour — is applied to recent data on π⁺ p → π° (π⁺ p) at different energies and (π⁺p) missing masses, including Δ production. We are able, in particular, to explain the filling of the dips and the variation of the slope with respect to the missing mass.     

The developmental pattern of stimulus and response interference in a color-object Stroop task: an ERP study

Background

Several studies have shown that Stroop interference is stronger in children than in adults. However, in a standard Stroop paradigm, stimulus interference and response interference are confounded. The purpose of the present study was to determine whether interference at the stimulus level and the response level are subject to distinct maturational patterns across childhood. Three groups of children (6–7 year-olds, 8–9 year-olds, and 10–12 year-olds) and a group of adults performed a manual Color-Object Stroop designed to disentangle stimulus interference and response interference. This was accomplished by comparing three trial types. In congruent (C) trials there was no interference. In stimulus incongruent (SI) trials there was only stimulus interference. In response incongruent (RI) trials there was stimulus interference and response interference. Stimulus interference and response interference were measured by a comparison of SI with C, and RI with SI trials, respectively. Event-related potentials (ERPs) were measured to study the temporal dynamics of these processes of interference.

Results

There was no behavioral evidence for stimulus interference in any of the groups, but in 6–7 year-old children ERPs in the SI condition in comparison with the C condition showed an occipital P1-reduction (80–140 ms) and a widely distributed amplitude enhancement of a negative component followed by an amplitude reduction of a positive component (400–560 ms). For response interference, all groups showed a comparable reaction time (RT) delay, but children made more errors than adults. ERPs in the RI condition in comparison with the SI condition showed an amplitude reduction of a positive component over lateral parietal (-occipital) sites in 10–12 year-olds and adults (300–540 ms), and a widely distributed amplitude enhancement of a positive component in all age groups (680–960 ms). The size of the enhancement correlated positively with the RT response interference effect.

Conclusion

Although processes of stimulus interference control as measured with the color-object Stroop task seem to reach mature levels relatively early in childhood (6–7 years), development of response interference control appears to continue into late adolescence as 10–12 year-olds were still more susceptible to errors of response interference than adults.     

Skimming and skipping stones

This article presents an example of skimming and skipping stonemotion in mathematical terms available to students studyingA-level mathematics. The theory developed in the article postulatesa possible mathematical model that is verified by experimentalresults.     

Transition Metal Ion-binding Properties of a 14-Membered N2O2S2- Macrobicyclic Ligand

The selective liquid–liquid extraction of various transition metal cations from the aqueous phase to the organic phase was carried out using a 14-membered N₂O₂S₂-macrobicycle. Metal picrates such as Pb²⁺, Co²⁺, Zn²⁺, Ni²⁺,Cu²⁺ and Cd²⁺ were used in this extraction studies. It was found that the ligand showed moderate selectivity towards Pb²⁺ only among the other metals. The extraction constant (log K _ex) was determined to be 13.8 for Pb²⁺ complex.     

Particle image velocimetry measurements of a shock wave/turbulent boundary layer interaction

Particle image velocimetry is used to investigate the interaction between an incident shock wave and a turbulent boundary layer at Mach 2.1. A particle response assessment establishes the fidelity of the tracer particles. The undisturbed boundary layer is characterized in detail. The mean velocity field of the interaction shows the incident and reflected shock wave pattern, as well as the boundary layer distortion. Significant reversed flow is measured instantaneously, although, on average no reversed flow is observed. The interaction instantaneously exhibits a multi-layered structure, namely, a high-velocity outer region and a low-velocity inner region. Flow turbulence shows the highest intensity in the region beneath the impingement of the incident shock wave. The turbulent fluctuations are found to be highly anisotropic, with the streamwise component dominating. A distinct streamwise-oriented region of relatively large kinematic Reynolds shear stress magnitude appears within the lower half of the redeveloping boundary layer. Boundary layer recovery towards initial equilibrium conditions appears to be a gradual process.