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941.
Humberto Prado 《Semigroup Forum》2008,77(3):456-462
We study stability properties of certain evolution equations including the fractional Cauchy problem. Under some spectral
assumptions these equations are governed either by a resolvent or a regularized resolvent or a k-convoluted semigroup. We investigate the long time behavior for bounded solutions by a direct application of the ergodic
theorems for regularized resolvents of Lizama and Prado (J. Approx. Theory 122:42–61, 2003), Prado (Semigroup Forum 73:243–252, 2006). We apply our results to the qualitative study of the fractional diffusion-wave equation on L
p
(ℝ).
The author is partially supported under FONDECYT Grant no 1070127. 相似文献
942.
Ma. Eulalia Vanegas Raúl Quijada Daniel Serafini Griselda B. Galland Humberto Palza 《Journal of Polymer Science.Polymer Physics》2008,46(8):798-806
Syndiotactic polypropylenes and their copolymers with 1‐olefins were synthesized using two metallocene/MAO catalytic systems, and the effect of the different microstructures on nonisothermal crystallization and subsequent melting was studied. Using differential scanning calorimetry (DSC) it was observed that samples with lower content of defects showed crystallization on cooling from the melt, and a double melting peak in the subsequent heating scan, the latter associated with melt, recrystallization and remelt processes that it was confirmed by its nonreversing exothermic process found by means of temperature modulated DSC (MDSC). However, polymers with high amount of defects showed cold crystallization on heating followed by a melting process, that it was observed by MDSC. Wide angle X‐ray diffraction was used for characterizing the changes of crystalline forms in relationship with crystallization process. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 798–806, 2008 相似文献
943.
Nikolaos I. Karageorgakis Andre HeelThomas Graule Ludwig J. Gauckler 《Solid State Ionics》2011,192(1):464-471
Nanocrystalline dense sub-micron thin films of Ce0.8Gd0.2O2 − δ have been successfully deposited by flame spray deposition. The deposition mechanism has been identified as droplet deposition. The deposition temperature of the substrate was as low as 200 °C and the deposition rate ∼ 30 nm/min. Under these conditions the droplets have a very limited residence time in the hot zone of the flame and are deposited as liquid, forming smooth films free of particles. They exhibited a dense and crack-free microstructure. Grain growth, lattice constant, crystallographic density and surface roughness have been investigated as a function of annealing temperature. The good quality of the films, in association with the high deposition rates at low deposition temperatures shows the preeminence of the flame spray method for depositing thin films for micro-solid oxide fuel cells. 相似文献
944.
Jun Lu Yun Yu Jianer Zhou Lixin Song Xingfang Hu Andre Larbot 《Applied Surface Science》2009,255(22):9092-9099
The hydrophobic properties of γ-Al2O3 membrane have been obtained by grafting fluoroalkylsilane (FAS) on the surface of the membrane. The following grafting parameters were studied: the eroding time of the original membrane, the grafting time, the concentration of FAS solution and the multiplicity of grafting. Hydrophobicity of the membranes was characterized by contact angle (CA) measurement. The thermogravimetric analysis (TGA) was used to investigate the weight loss process (25–800 °C) of the fluoroalkylsilane grafted on Al2O3 powders under different grafting conditions. The morphologies of the membranes modified under different parameters were examined by field emission scanning electron microscopy (FE-SEM) and the surface roughness (Ra) was measured using white light interferometers. A needle-like structure was observed on the membrane surface after modification, which causes the change of Ra. On the results above, we speculated a model to describe the reaction between FAS and γ-Al2O3 membrane surface as well as the formed surface morphology. 相似文献
945.
Meng Zhou XiaoHua Deng Song Fu RongXin Tang YunHui Hu ShiYou Li A. Vaivads M. Andre Xi Lin MingHui Lin XiaoMin Zhou 《中国科学G辑(英文版)》2009,52(4):626-630
Magnetic reconnection is a fundamental process in plasma, which is thought to play important roles both in laboratory and
natural plasmas through affecting magnetic topology, heating and accelerating particles. During an event on Oct. 1st, 2001,
the Cluster tetrahedron circled around the magnetic reconnection region several times, and Xiao et al. first identified the
null pair and found that the spectrum of the null-point oscillation shows the maximum power near the lower-hybrid frequency.
In this paper we report the observation of electromagnetic and electrostatic wave enhancements near lower hybrid frequency
associated with the reconnection process near the null pair. The lower hybrid waves (LHWs) with quasi-perpendicular propagation
were identified and also confirmed by the power law of the spectrum of electric and magnetic fields.
Supported by the National Natural Science Foundation of China (Grant Nos. 40325012, 40390151, 40574073, 40574074, and 40640420563),
the Research Foundation from Ministry of Education of China (Grant No. 40174043), and the China Plan on the International
Polar Year 相似文献
946.
S. Andre F. Guida‐Pietrasanta A. Rousseau B. Boutevin 《Journal of polymer science. Part A, Polymer chemistry》2001,39(14):2414-2425
The insertion of soft polysiloxane segments into a polyimide backbone introduces changes in its properties (processability, low surface tension, gas permeability, and lower dielectric constant). Generally, these polyimide–polysiloxane copolymers are synthesized by the condensation of a dianhydride with an aromatic diamine and an amine telechelic polysiloxane, or by transimidization between an aminopyridine‐terminated oligoimide and an amine end‐capped oligosiloxane. This study investigated another route to obtain perfectly alternating polyimide–polyhybridsiloxane (PI–PHSX) block copolymers. The hydrosilylation, widely studied previously, was performed to elaborate copolymers from an allyl telechelic polyimide and a hydrosilane telechelic polyhybridsiloxane. The use of a telechelic polyhybridsiloxane as a soft segment brought better thermostability and better chemical resistance in comparison with an oligosiloxane based on ? Si(CH3)2? O? units. Using the same allyl telechelic polyimide moiety but varying the size of the hybrid siloxane part, we obtained different PI–PHSX block copolymers, leading to thermoplastic elastomers (TPE). We investigated the effect of the soft‐segment length on the thermal resistance, activation energy of thermal degradation, mechanical behavior, and surface properties of a series three PI–PHSX block copolymers containing 36, 54, and 75 wt % polyimide. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2414–2425, 2001 相似文献
947.
In this work we have investigated viscous flow in a rotating system. The system consists of a horizontally oriented cylindrical drum rotating around the center and a fixed plate as a scraping internal tool. By this plate the inner volume is divided into two separate chambers. No mass transport between the chambers can take place. The drum is completely or partially filled with a highly viscous, optically transparent silicon oil. In the second case the remaining space is filled with air as a passive phase. Depending on the settings in the system, which are the rotational speed of the drum, material properties of the liquid and the volume ratio of the two phases, different flow phenomena can be observed [1, 2]. For the characterization of the flow dimensionless ratios given by the Reynolds number Re, the Froude number Fr, the Capillary number Ca and the volumetric filling degree F are used. The system is investigated applying the experimental method of Particle Image Velocimetry (PIV) as well as suitable models of Computational Fluid Dynamics (CFD). The goal of this investigation is to identify the velocity fields in the liquid phase for a better understanding of the observed phenomena. The results obtained by the different methods are presented and discussed. (© 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
948.
Andre H. St.Amant Fengying Huang Jia Lin Keith Rickert Vaheh Oganesyan Daniel Lemen Shenlan Mao Jay Harper Marcello Marelli Herren Wu Changshou Gao Javier ReaddeAlaniz R. James Christie 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(25):8577-8581
Here, we describe a diene‐containing noncanonical amino acid (ncAA) capable of undergoing fast and selective normal electron‐demand Diels–Alder (DA) reactions following its incorporation into antibodies. A cyclopentadiene derivative of lysine (CpHK) served as the reactive handle for DA transformations and the substrate for genetic incorporation. CpHK incorporated into antibodies with high efficiency and was available for maleimide conjugation or self‐reaction depending on position in the amino acid sequence. CpHK at position K274 reacted with the maleimide drug‐linker AZ1508 at a rate of ≈79 m ?1 s?1 to produce functional antibody–drug conjugates (ADCs) in a one‐step process. Incorporation of CpHK at position S239 resulted in dimerization, which covalently linked antibody heavy chains together. The diene ncAA described here is capable of producing therapeutic protein conjugates with clinically validated and widely available maleimide compounds, while also enabling proximity‐based stapling through a DA dimerization reaction. 相似文献
949.
Carlos Lodeiro Rufina Bastida Alejandro Macías Adolfo Rodríguez Andre Saint‐Maurice 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(6):e255-e256
The X‐ray structure determinations of the two title compounds, namely 7‐methyl‐7,17‐diaza‐3,11‐diazoniabicyclo[11.3.1]heptadeca‐1(17),13,15‐triene dichloride monohydrate, C14H26N42+·2Cl?·H2O, (I), and 7‐methyl‐17‐aza‐3,7,11‐triazoniabicyclo[11.3.1]heptadeca‐1(17),13,15‐triene 2.826‐chloride 0.174‐nitrate, C14H27N43+·2.826Cl?·0.174NO3?, (II), are reported. Protonation occurs at the secondary amine N atoms in (I) and at all three amine N atoms in (II) to which the Cl? ions are linked via N—H?Cl hydrogen bonds. The macrocyclic hole is quite different in both structures, as is observed by comparing particularly the N3?N4 distances [2.976 (4) and 4.175 (4) Å for (I) and (II), respectively]. In (II), a Cl? ion alternates with an NO3? ion in a disordered structure. 相似文献
950.
Claude Taillefumier Christophe Charron Yves Chapleur Andre Aubry 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):1168-1169
The crystal structure of the title compound, C24H28O8, has been determined. The conformation of the furanose ring can be described as 58% ideal envelope OE conformer and 42% ideal twisted OT1 conformer. The 1,3‐dioxane ring adopts a chair conformation with the anhydro‐O atom pointing upwards. Both phenyl rings are quasi‐perpendicular to the mean plane of the furanose ring. The hydrogen bonding is intermolecular and consists of infinite chains parallel to the a axis. 相似文献