全文获取类型
收费全文 | 317篇 |
免费 | 10篇 |
国内免费 | 1篇 |
专业分类
化学 | 199篇 |
晶体学 | 1篇 |
力学 | 5篇 |
数学 | 54篇 |
物理学 | 69篇 |
出版年
2023年 | 2篇 |
2022年 | 14篇 |
2021年 | 2篇 |
2020年 | 4篇 |
2019年 | 8篇 |
2018年 | 5篇 |
2017年 | 5篇 |
2016年 | 16篇 |
2015年 | 7篇 |
2014年 | 17篇 |
2013年 | 21篇 |
2012年 | 17篇 |
2011年 | 14篇 |
2010年 | 19篇 |
2009年 | 14篇 |
2008年 | 28篇 |
2007年 | 25篇 |
2006年 | 15篇 |
2005年 | 14篇 |
2004年 | 14篇 |
2003年 | 11篇 |
2002年 | 15篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有328条查询结果,搜索用时 12 毫秒
61.
62.
63.
64.
We study discrete vector solitons and vortices in two-dimensional photonic lattices with Kerr nonlinearity and demonstrate novel types of stable, incoherently coupled dipoles and vortex-soliton complexes that can be excited by Gaussian beams. We also discuss what we believe to be novel scenarios of the charge-flipping instability of incoherently coupled discrete vortices. 相似文献
65.
Burke AJ Davies SG Garner AC McCarthy TD Roberts PM Smith AD Rodriguez-Solla H Vickers RJ 《Organic & biomolecular chemistry》2004,2(9):1387-1394
Conjugate addition of lithium (S)-N-benzyl-N-alpha-methylbenzylamide to a range of alpha, beta-unsaturated Weinreb amides proceeds with high levels of diastereoselectivity (>95% de). The beta-amino Weinreb amide products may be transformed into beta-amino ketones via reactions with Grignard reagents, while treatment with DIBAL-H furnishes beta-amino aldehydes. Trapping of the aldehyde via Wadsworth-Emmons reaction and subsequent manipulation offers an efficient route to homochiral delta-amino acid derivatives and 2-substituted piperidines. The application of this methodology for the synthesis of (S)-coniine is demonstrated. 相似文献
66.
67.
Humberto Andre Potes-Lesoinne Fernando Ramirez-Alvarez Victor H. Perez-Gonzalez Sergio O. Martinez-Chapa Roberto Carlos Gallo-Villanueva 《Electrophoresis》2022,43(1-2):249-262
The survival of living beings, including humanity, depends on a continuous supply of clean water. However, due to the development of industry, agriculture, and population growth, an increasing number of wastewaters is discarded, and the negative effects of such actions are clear. The first step in solving this situation is the collection and monitoring of pollutants in water bodies to subsequently facilitate their treatment. Nonetheless, traditional sensing techniques are typically laboratory-based, leading to potential diminishment in analysis quality. In this paper, the most recent developments in micro- and nano-electrochemical devices for pollutant detection in wastewater are reviewed. The devices reviewed are based on a variety of electrodes and the sensing of three different categories of pollutants: nutrients and phenolic compounds, heavy metals, and organic matter. From these electrodes, Cu, Co, and Bi showed promise as versatile materials to detect a grand variety of contaminants. Also, the most commonly used material is glassy carbon, present in the detection of all reviewed analytes. 相似文献
68.
69.
Jorge Ivn Castro Manuel N. Chaur Carlos Humberto Valencia Llano Mayra Eliana Valencia Zapata Jos Herminsul Mina Hernandez Carlos David Grande-Tovar 《Molecules (Basel, Switzerland)》2021,26(16)
In recent decades, the number of patients requiring biocompatible and resistant implants that differ from conventional alternatives dramatically increased. Among the most promising are the nanocomposites of biopolymers and nanomaterials, which pretend to combine the biocompatibility of biopolymers with the resistance of nanomaterials. However, few studies have focused on the in vivo study of the biocompatibility of these materials. The electrospinning process is a technique that produces continuous fibers through the action of an electric field imposed on a polymer solution. However, to date, there are no reports of chitosan (CS) and polyvinyl alcohol (PVA) electrospinning with carbon nano-onions (CNO) for in vivo implantations, which could generate a resistant and biocompatible material. In this work, we describe the synthesis by the electrospinning method of four different nanofibrous membranes of chitosan (CS)/(PVA)/oxidized carbon nano-onions (ox-CNO) and the subdermal implantations after 90 days in Wistar rats. The results of the morphology studies demonstrated that the electrospun nanofibers were continuous with narrow diameters (between 102.1 nm ± 12.9 nm and 147.8 nm ± 29.4 nm). The CS amount added was critical for the diameters used and the successful electrospinning procedure, while the ox-CNO amount did not affect the process. The crystallinity index was increased with the ox-CNO introduction (from 0.85% to 12.5%), demonstrating the reinforcing effect of the nanomaterial. Thermal degradation analysis also exhibited reinforcement effects according to the DSC and TGA analysis, with the higher ox-CNO content. The biocompatibility of the nanofibers was comparable with the porcine collagen, as evidenced by the subdermal implantations in biological models. In summary, all the nanofibers were reabsorbed without a severe immune response, indicating the usefulness of the electrospun nanocomposites in biomedical applications. 相似文献
70.
Emildo Marcano Emilio Squitieri Juan Murgich Humberto Soscún 《Journal of Molecular Structure》2009,911(1-3):81-87
Hatree–Fock calculations at ab initio and semiempirical levels were carried out for the averaged polarizability α and second hyperpolarizability γ of two pairs of quadrupolar isomers with different donor and acceptor groups. These properties were correlated with the antibonding/bonding π occupation number (π*/π ratio). It was found that isomers with extended π systems had low π*/π ratios and high α and γ values, while low α and γ values were obtained for isomers with large π*/π ratios and no extended π system. The PM3 and PM6 α values were found to be in excellent agreement with the HF/6-31+G(d,p) ones. The PM3 values for γ were significantly larger than those calculated by HF/6-31+G(d,p), with an average PM3/HF ratio of 1.43. The PM6 results were noticeably better with a ratio of 0.85. The calculation of α and γ at MP2/6-31+G(d,p) level for representative isomers showed that the contribution of the electron correlation to their values was small and that the HF/6-31+G(d,p) method provides reliable values at much lower computational cost. 相似文献