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961.
The molecular species of phosphatidylcholine from freshwater sources (Macrobranchium nipponense and Macrobranchium rosenbergii) and marine sources (Euphausia superba and Penaeus chinesis) were characterized by high-resolution mass spectrometry. The tandem secondary mass spectrometry (MS/MS) fragmentation allowed for the identification of fatty acyl residues of phosphatidylcholine molecular species. (16:0–18:1)Phosphatidylcholine was the main phosphatidylcholine molecular species determined in all shrimp samples, especially in E. superba. Macrobranchium rosenbergii phosphatidylcholine was particularly rich in (16:0–20:5)phosphatidylcholine and (16:0–22:6)phosphatidylcholine. The proportion of the two molecular species was next to the phosphatidylcholine of E. superba. Therefore, M. rosenbergii appears to be a potential freshwater source for the supplementation of polyunsaturated fatty acids, particularly eicosapentaenoic acid (20:5) and docosahexaenoic acid (22:6). This approach may be used as an efficient method for the identification of natural phosphatidylcholine sources from the broad range of plant, animal, and marine origins. 相似文献
962.
A Fluorescent Sensor for Dual‐Channel Discrimination between Phosgene and a Nerve‐Gas Mimic 下载免费PDF全文
Dr. Xin Zhou Yiying Zeng Chen Liyan Prof. Xue Wu Prof. Juyoung Yoon 《Angewandte Chemie (International ed. in English)》2016,55(15):4729-4733
The ability to analyze highly toxic chemical warfare agents (CWAs) and related chemicals in a rapid and precise manner is essential in order to alleviate serious threats to humankind and public security caused by unexpected terrorist attacks and industrial accidents. In this investigation, we designed a o‐phenylenediamine‐pyronin linked dye that is capable of both fluorogenic and colorimetric discrimination between phosgene and the prototypical nerve‐agent mimic, diethyl chlorophosphate (DCP) in the solution or gas phase. Moreover, this dye has been used to construct a portable kit that can be employed for real‐time monitoring of DCP and phosgene in the field, both in a discriminatory manner, and in a simple and safe way. 相似文献
963.
Electrolytic Formation of Crystalline Silicon/Germanium Alloy Nanotubes and Hollow Particles with Enhanced Lithium‐Storage Properties 下载免费PDF全文
Dr. Wei Xiao Jing Zhou Dr. Le Yu Prof. Dihua Wang Prof. Xiong Wen Lou 《Angewandte Chemie (International ed. in English)》2016,55(26):7427-7431
Crystalline silicon(Si)/germanium(Ge) alloy nanotubes and hollow particles are synthesized for the first time through a one‐pot electrolytic process. The morphology of these alloy structures can be easily tailored from nanotubes to hollow particles by varying the overpotential during the electro‐reduction reaction. The continuous solid diffusion governed by the nanoscale Kirkendall effect results in the formation of inner void in the alloy particles. Benefitting from the compositional and structural advantages, these SiGe alloy nanotubes exhibit much enhanced lithium‐storage performance compared with the individual solid Si and Ge nanowires as the anode material for lithium‐ion batteries. 相似文献
964.
965.
Uniform-sized fluorescent molecularly imprinted polymers were prepared by one-step swelling and suspension polymerization, while chlorpyrifos, methacrylic acid, ethylene glycol dimethacrylate, and oil-soluble CdSe/ZnS quantum dots were used as the carrier, template molecule, functional monomer, cross-linker, and fluorophor, respectively. The morphology, adsorption dynamics, binding ability, and selectivity of quantum dot-labeled molecularly imprinted polymers were evaluated. The dosage of quantum dots for labeling the molecularly imprinted polymers was optimized. The results showed that the optimized dose of quantum dots was 200?µL using a concentration of 8.0?µM. The microsphere size was approximately 10?µm with a honeycombed surface. The quantum dot-labeled molecularly imprinted polymers had an even brightness and a high selectivity. In the presence of different concentrations of chlorpyrifos, a decrease in the fluorescence intensity of the quantum dot-labeled molecularly imprinted polymer was clearly identified by flow cytometry. The whole detection process was accomplished within 2?h including pretreatment. This method was used for the determination of chlorpyrifos in tap water samples. 相似文献
966.
Jianxin Chen Dr. Chunyang Yu Dr. Zengqian Shi Songrui Yu Prof. Zhongyuan Lu Wengfeng Jiang Meng Zhang Prof. Wei He Prof. Yongfeng Zhou Prof. Deyue Yan 《Angewandte Chemie (International ed. in English)》2015,54(12):3621-3625
Well‐defined ultrathin nanotubes (30 nm in diameter and of micrometer‐scale length) were generated through the self‐assembly of a novel alternative copolymer synthesized using an epoxy–thiol click‐chemistry reaction. The self‐assembly mechanism was investigated both by experiments and using dissipative particle dynamics (DPD) simulations. The obtained nanotubes can be readily functionalized with carboxy groups, amino groups, peptides, or other groups by simple modular click copolymerization. 相似文献
967.
968.
Zhou Huilian Yan Siming He Yi Xiang Yuxin Li Hongjie Song Ruxia Cheng Xinyu Yan Liping Song Jinxue Shangguan Jianxin 《Journal of Solid State Electrochemistry》2022,26(11):2515-2525
Journal of Solid State Electrochemistry - There are two key factors in the fabrication of superhydrophobic surfaces. One is to have the appropriate micro/nano structure, and the other is to reduce... 相似文献
969.
Journal of Solid State Electrochemistry - As a promising material for many industrial applications, Ti-15 V-3Cr-3Al-3Sn (commonly referred to as Ti-15–3) titanium alloy always... 相似文献
970.
横向磁场激励下铁磁梁式板的混沌运动分析 总被引:9,自引:0,他引:9
在磁体力分布的磁弹性理论模型和磁场准静态假定模式基础上,对于处在周期时变磁场 中的不可移简支铁磁梁式板非线性磁弹性动力特性进行定性与定量分析.首先利用磁场的摄 动技术和结构变形的模态法,导出了关于模态坐标的非线性动力方程;然后利用Melnikov方 法,从理论上给出这一磁弹性动力系统可能出现混沌运动的必要条件及参数范围;最后采用变 步长Runge-Kutta数值积分方法对其磁弹性相互作用的混沌现象进行了定量搜索与模拟,并 利用其轨迹的Poincare截面图与Liapunov指数加以判断.结果表明磁弹性简支梁式板在横 向周期时变磁场中存在混沌吸引子,且在机械阻尼很小时其混沌吸引子表现出稠的特性. 相似文献