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71.
Pan J Wu X Wang L Liu G Lu GQ Cheng HM 《Chemical communications (Cambridge, England)》2011,47(29):8361-8363
Single crystalline anatase TiO(2) rods with dominant reactive {010} facets are directly synthesized by hydrothermally treating Cs(0.68)Ti(1.83)O(4)/H(0.68)Ti(1.83)O(4) particles. The nanosized rods show a comparable conversion efficiency in dye-sensitized solar cells (DSSCs), and a superior photocatalytic conversion of CO(2) into methane to the benchmark P25 TiO(2) nanocrystals. 相似文献
72.
Crystal facet engineering of semiconductors has become an important strategy for fine-tuning the physicochemical properties and thus optimizing the reactivity and selectivity of photocatalysts. In this review, we present the basic strategies for crystal facet engineering of photocatalysts and describe the recent advances in synthesizing faceted photocatalysts, in particular TiO(2) crystals. The unique properties of faceted photocatalysts are discussed in relation to anisotropic corrosion, interaction dependence of adsorbates, photocatalytic selectivity, photo-reduction and oxidation sites, and photocatalytic reaction order. Ideas for future research on crystal facet engineering for improving the performance of photocatalysts are also proposed. 相似文献
73.
Ata Allah Taleizadeh Hui-Ming Wee Seyed Gholamreza Jalali-Naini 《Applied Mathematical Modelling》2013
We develop an economic production quantity (EPQ) model with random defective items and failure in repair. The existence of only one machine results with limited production capacity and shortages. The aim of this research is to derive the optimal cycle length, the optimal production quantity and the optimal back ordered quantity for each product so as to minimize the total expected cost (holding, shortage, production, setup, defective items and repair costs). The convexity of the model is derived and the objective function is proved convex. Two numerical examples illustrate the practical usage of the proposed method. 相似文献
74.
研究了超高压中温协同处理对砀山梨汁中多酚氧化酶活性的影响,实验压力为0.1~500 MPa,温度为20~60 ℃。此外,考察了不同pH值(3~7)和保压时间(2~34 min)超高压处理对酶活性的影响。实验结果分析表明:在处理温度为50 ℃、保压时间为10 min和梨汁pH值为5的条件下,200~300 MPa处理梨汁时多酚氧化酶被激活,活性表现最高;500 MPa时酶的活性下降到75.3%。协同温度为30 ℃处理梨汁时,酶的活性反而增大;30 ℃以后,酶活性随温度升高而迅速降低;有效协同高压处理的温度为40 ℃。随着保压时间的延长,梨汁中过氧化物酶的活性减小;18 min以前下降速度较快些,之后下降速度变缓。pH在5~6之间,酶的残留活性最大;pH值为6时,梨汁中多酚氧化酶最为耐压。 相似文献
75.
Nan-Ru Ma Cheng-Jian Lin Jian-Song Wang Lei Yang Dong-Xi Wang Lei Zheng Shi-Wei Xu Li-Jie Sun Hui-Ming Jia Jun-Bing Ma Peng Ma Shi-Lun Jin Zhen Bai Yan-Yun Yang Xin-Xing Xu Gao-Long Zhang Feng Yang Jian-Jun He Huan-Qiao Zhang Zu-Hua Liu 《中国物理C(英文版)》2016,40(11):116004-116004
The breakup reactions of weakly-bound nuclei at energies around the Coulomb barrier and the corresponding coupling effect on the other reaction channels are hot topics nowadays. To overcome the difficulty in identifying both heavier and lighter fragments simultaneously, a new kind of ionization-chamber based detector telescope has been designed and manufactured. It consists of a PCB ionization chamber and three different thickness silicon detectors installed inside the chamber, which form a multilayer ΔE-ER telescope. The working conditions were surveyed by using an α source. An in-beam test experiment shows that the detector has good particle identification for heavy particles like 17F and 16O as well as light particles like protons and alpha particles. The measured quasi-elastic scattering angular distribution and the related discussions for 17F+208Pb are presented. 相似文献
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采用不同沉积电压制备TiO2光阳极,研究电压对薄膜沉积速率、厚度和形貌的影响。通过台阶仪、光学照片、扫描电子显微镜(SEM)、电化学交流阻抗谱、开路电压衰减曲线对光阳极和电池进行系统表征,并测试了染料敏化太阳能电池器件的电流密度-电压(J-V)曲线,计算其光电转换效率。结果表明,提高沉积电压时,光阳极薄膜的沉积速率加快,膜厚也增加,但是电压过高时,薄膜会有裂缝和覆盖不全的问题,这会对电池的效率造成负面影响。综合考虑低沉积电压条件下薄膜均匀无裂缝和高沉积电压条件下沉积速率快的优点,采用先30 V电压、后60 V电压的电泳沉积方式来制备光阳极,结果呈现协同效果,既降低了制备时间又得到高质量的薄膜,在无其他修饰的情况下,电池的光电转换效率可以达到7.29%。 相似文献
79.
Elastic scattering angular distributions of the 14^N+16^O system and the angular distributions of transfer reaction 16^O(14^N,13^C)17^F at ELab=76.2 MeV and 57 MeV have been measured and calculated by means of the exact finiterange distorted-wave Born approximation with the PTOLEMY code. The optical potential parameters for the weakly bound nuclear system 17^F+13^C have been deduced and applied to analyse the elastic scattering angular distributions of the similar systems 17^F+12^C and 17^F+14^N which are taken from literature. The result shows that the transfer reaction with stable projectile and target combination can be used as an alternative method to extract the optical potential parameters for the weakly bound nuclear system. 相似文献
80.
A laser diode end-pumped 10 at.% doped Yb:YAG microchip crystal intracavity frequency doubled all solid-stated green laser is reported in this paper. Using one plano-concave resonator, with the pump power of 1.2 W, 44.2 mW TEM00 continuous wave (CW) laser at 525 nm was obtained, the optical conversion efficiency was about 3.7%. When a Cr:YAG crystal with initial transmission of 95.5% inserted in the resonator, the maximum output power of 6.4 mW, pulse duration width of 49.1 ns, pulse repetition rate of 2.45 kHz, and peak power of 53.1 W at 515 nm were achieved when the pump power was 1.2 W. The wavelength changed from 525 nm to 515 nm and the threshold was only 725 mW. 相似文献