基于X射线脉冲星导航的地面模拟系统研究

为进行X射线脉冲星导航的关键技术研究,搭建了基于X射线脉冲星导航的地面模拟系统.地面模拟系统由模拟X射线脉冲源、基于微通道板的高灵敏X射线光子探测器、电荷灵敏前放和主放电路、时间测量单元、X射线脉冲轮廓构造及X射线脉冲到达时间测量系统组成.该模拟系统可在地面模拟X射线脉冲星导航的星源的强度、周期及脉冲轮廓,实现对X射线脉冲星单光子到达时间的记录,构造X射线脉冲星脉冲轮廓,计算X射线脉冲到达时间.描述了基于X射线脉冲星导航的地面模拟系统的组成和工作原理,报道了基于X射线脉冲星导航的地面模拟系统的初步结果. 关键词： X射线脉冲星导航 微通道板光子探测器 脉冲轮廓     

C波段具有平坦近零色散光子晶体光纤的一种改进设计方法

光子晶体光纤的最内层空气孔在拉制过程中容易发生形变,从而严重影响色散. 基于多极法,模拟了当最内层空气孔为不易发生形变的较小值时,第二、三层空气孔对色散的影响,结果表明这种简单的色散控制方法也可以实现零色散点的快速平移,且保持色散平坦. 以此为基础,设计了应用于C波段具有近零平坦色散的光子晶体光纤,色散系数为-0.24-0.33 ps/(km·nm). 模拟表明,从第五层开始增加空气孔的层数对已设计光纤的色散影响很小,可以通过增加空气孔的层数得到理想的限制损耗. 这一方法亦适用于S,L波段具有类似性质PCF的设计. 关键词： 光子晶体光纤 色散系数 多极法 限制损耗     

优化重聚脉冲提高梯度场核磁共振信号强度

缩短射频脉冲宽度, 有助于解决脉冲电力消耗大、样品吸收率高、信噪比低等极端条件核磁共振探测的关键问题. 本文首先分析射频脉冲角度对核磁共振自旋回波信号强度的影响机理, 基于Bloch方程推导了回波信号幅度与扳转角、重聚角的关系. 在特制核磁共振分析仪上采用变脉冲角度技术, 分别在均匀磁场和梯度磁场条件下实现对扳转角和重聚角与回波信号强度关系的数值模拟和实验测量. 结果表明, 梯度场中, 扳转角为90°、重聚角为140°的射频脉冲组合获得最大首波信号强度, 比180°脉冲对应的回波幅值提高13%, 能耗降低至78%. 选用该重聚角(140°) 优化设计饱和恢复脉冲序列探测流体的纵向弛豫时间T₁特性, 准确获得 T₁分布.该结果对于低电力供应、且对信噪比有较高要求的核磁共振测量, 如随钻核磁共振测井和在线核磁共振快速检测等, 具有重要意义. 关键词： 核磁共振 信号强度 重聚脉冲角度 Bloch方程     

联苯甲酰桥联β-环糊精吸附U(VI)的动力学和热力学

β-环糊精与对甲苯磺酰氯在低温碱性溶液中反应合成6-对甲苯磺酰酯-β-环糊精,并利用红外光谱和核磁共振氢谱对其进行表征;联苯甲酰与6-对甲苯磺酰酯-β-环糊精以摩尔比为1: 2反应合成一种新型的联苯甲酰桥联β-环糊精(BB β-CD)材料,并采用紫外可见分光光度法对其合成机理以及BB β-CD和联苯甲酰对U(VI)的吸附行为进行研究;同时采用扫描电镜对材料吸附U(VI)前后的外貌形态进行表征。通过间歇吸附法考察pH、反应时间、温度以及干扰离子等因素对吸附过程的影响。结果表明,相比联苯甲酰,BB β-CD能更有效地吸附U(VI),在pH=4.5,反应时间为60 min条件下,最大吸附量为12.16 mg·g^-1,吸附率高达91.2%。动力学和热力学拟合结果表明,吸附过程更符合准二级动力学速率方程,Langmuir等温吸附模型比Freundlich等温吸附模型更适合模拟吸附过程,且吸附是自发吸热的过程。     

江淮持续性暴雨前期热带印度洋海温影响初析

热带印度洋是最强最稳定的江淮持续性暴雨中期海温信号区.在此基础上,利用28年气候逐候资料,根据该信号区海温与后期OLR（Outgoing Longwave Radiation）场和环流场的相关分析以及典型持续性暴雨过程的合成分析,初步探究了其对江淮持续性暴雨形成的中期影响机制.研究结果表明,前期信号区海温异常可通过以下3种途径对江淮持续性暴雨过程的发生产生影响.过程发生前5候至前4候热带印度洋偏高的海温及其引起的热带对流异常,导致热带偏北印度洋至热带西太平洋上异常的准纬向环流形成,削弱印度洋上的Walker环流和西南季风,有利于西太平洋副高偏强.偏高的海温有利于过程发生前4候北大西洋急流出口区右侧脊发展,还可影响此异常波动的东传,对欧亚波列的发展作出重要贡献.过程发生前3～2候,该波列东传所伴随的环流调整导致南亚高压加强、中国东部槽发展、西太平洋副高加强.另外偏高的海温还有利于过程发生前2～1候110～140°E经向异常环流的形成,该异常环流削弱热带季风经圈环流,使南海-西太平洋热带辐合带偏南,有利于副高西伸.     

Aerodynamic measurements of patients with parkinson''s disease

Patients with Parkinson's disease commonly complain of voice dysfunction. Most of these complaints can be attributed to the known muscular control disorders that occur with Parkinson's disease. However, the manifestations of Parkinson's disease muscular dysfunction on parameters of phonation such as airflow, laryngeal resistance, and subglottal pressure necessary to sustain phonation have not been reported. The purpose of this study was to examine the aerodynamic characteristics of flow, laryngeal resistance, and phonation pressure threshold in a heterogeneous population of patients with Parkinson's disease who had varying voice complaints and to compare the data to similar studies for human subjects who have no voice complaints. The studies used a noninvasive method of detecting flow and acoustic signal from the lips, oral cavity and nose during phonation and used an external flow interruption technique to estimate subglottal pressure and phonation threshold pressure. About one third of the patients could not produce phonation at regular and loud intensities that were comfortable for normal subjects. The mean subglottal pressure (SGP) of patients with Parkinson disease who could produce 3 levels of intensity comparable to normal subjects was significantly higher than the mean SG-Ps for normal subjects for the same intensities of vocal production. The mean flow rates measured from patients with Parkinson's disease at the same 3 intensities of phonation was not significantly greater than in normal subjects. This indicated that the mean laryngeal resistance calculated for patients with Parkinson's disease was notably and significantly greater than mean laryngeal resistance calculated for normal subjects at the same intensity levels. The mean vocal efficiency (VE) for normal subjects was not significantly different than the mean VE for patients with Parkinson's disease, because greater pressure was used to generate similar flow and acoustic energy. These findings correlate with the perception of patients with Parkinson's disease that they are working harder to produce phonation. The observation of notably greater laryngeal resistance and phonation threshold pressure in patients with Parkinson's disease suggests that further studies of the glottic aperture in patients with Parkinson' disease may be useful for understanding how this common motor disorder disturbs phonation.     

聚丙烯酰胺树脂的制备及其对2,4-二氯苯氧乙酸的吸附性能研究

以氯甲基化交联聚苯乙烯树脂(CMCPS)为载体和大分子引发剂,溴化亚铜/2,2’-联吡啶为催化剂体系,采用了表面引发原子转移自由基聚合技术(SI-ATRP),将丙烯酰胺接枝到CMCPS树脂表面,制得了新型聚丙烯酰胺树脂(PAM-CMCPS),并且用元素分析、扫描电镜和红外光谱对其进行了表征。考察了此树脂对2,4-二氯苯氧乙酸的吸附性能、动力学和热力学参数。结果表明,此树脂对2,4-二氯苯氧乙酸的吸附量随溶液初始浓度和温度的升高而增加,当初始浓度为8 mmol/L时吸附效果最佳,树脂的静态饱和吸附容量为111.0 mg/g,Langmuir和Freundlich方程都呈现良好的拟合度。热力学平衡方程计算得ΔG<0,ΔH=268.2 k J/mol,ΔS>0,表明此吸附过程是一个自发、吸热、熵增加的过程。动力学研究表明,准二级动力学方程能较好拟合动力学实验结果,该过程符合准二级动力学模型。此PAM-CMCPS树脂应用于柑橘样品中2,4-二氯苯氧乙酸的吸附,取得了较满意的结果。     

Simultaneous qualitation and quantification of thirteen bioactive compounds in Flos lonicerae by high-performance liquid chromatography with diode array detector and mass spectrometry

A high-performance liquid chromatography (HPLC) with diode array detector (DAD) and electrospray ionization mass spectrometry (ESI-MS) was established for the simultaneous determination of thirteen bioactive compounds in Flos Lonicerae. The optimal chromatographic conditions were obtained on a C(18) column (250x4.6 mm, 5.0 microm) with the column temperature at 30 degrees C. The mobile phase was composed of (A) acetic acid aqueous (0.4%, v/v) and (B) acetonitrile using a gradient elution, the flow rate was 1 ml/min. Detection wavelengths were set at 240 nm for iridoids (loganin, sweroside, secoxyloganin and centauroside), 330 nm for phenolic acids (chlorogenic acid, caffeic acid, 4,5-di-O-caffeoyl quinic acid and 3,4-di-O-caffeoyl quinic acid) and 360 nm for flavonoids (rutin, hyperoside, quercetin-3-O-glucoside, luteolin-7-O-glucoside and lonicerin). The identities of the peaks were accomplished by comparing retention times, UV and mass data with reference compounds under the same conditions. All calibration curves showed good linear regression (r(2)>0.9983) within test ranges. The developed method provided satisfactory precision and accuracy with overall intra-day and inter-day variations of 0.78--1.85% and 1.13--2.36%, respectively, and the overall recoveries of 91.3--104.2% for the thirteen compounds analyzed. The verified method was successfully applied to quantitative determination of the three types of bioactive compounds in ten commercial Flos Lonicerae samples from different markets in China. The analytical results demonstrated that the contents of the thirteen analytes were relatively variant.     

New expressions for the surface roughness length and displacement height in the atmospheric boundary layer

An alternative model for the prediction of surface roughness length is developed. In the model a new factor is introduced to compensate for the effects of wake diffusion and interactions between the wake and roughness obstacles. The experiments are carried out by the use of the hot wire anemometry in the simulated atmospheric boundary layer in a wind tunnel. Based on the experimental data, a new expression for the zero-plane displacement height is proposed for the square arrays of roughness elements, which highlights the influence of free-stream speed on the roughness length. It appears that the displacement height increases with the wind speed while the surface roughness length decreases with Reynolds number increasing. It is shown that the calculation results based on the new expressions are in reasonable agreement with the experimental data.