两个正交子能级的V型三能级系统的粒子数振荡特性

研究了线偏振脉冲光场激发下,半导体量子点中两个正交子能级上的粒子数振荡特性.利用旋转波近似方法给出了共振激发和无衰减时粒子数运动方程的解析解.引入了该系统的等效跃迁偶极矩和等效脉冲面积，并给出了其关系表达式.理论分析表明，该体系中的子能级上粒子数振荡的振幅和频率都可以通过改变激发场的偏振角和系统的初态条件进行调控. 关键词： Rabi振荡 旋转波近似 三能级系统     

Synchronization of different chaotic systems via active radial basis functions sliding mode controller

This paper presents a new method to synchronize different chaotic systems with disturbances via an active radial basis function （RBF） sliding controller. This method incorporates the advantages of active control, neural network and sliding mode control. The main part of the controller is given based on the output of the RBF neural networks and the weights of these single layer networks are tuned on-line based on the sliding mode reaching law. Only several radial basis functions are required for this controller which takes the sliding mode variable as the only input. The proposed controller can make the synchronization error converge to zero quickly and can overcome external disturbances. Analysis of the stability for the controller is carried out based on the Lyapunov stability theorem. Finally, five examples are given to illustrate the robustness and effectiveness of the proposed synchronization control strategy.     

Investigating cyclic sotolon,maple furanone and their dimers in solution using optical rotation,electronic circular dichroism and vibrational circular dichroism

The experimental optical rotation (OR), electronic circular dichroism (ECD) and vibrational circular dichroism (VCD) spectra of (R)-3-hydroxy-4,5-dimethylfuran-2(5H)-one (sotolon, 1) and (R)-5-ethyl-3-hydroxy-4-methylfuran-2(5H)-one (maple furanone, 2) taken in chloroform were compared to their spectra calculated with time-dependent density functional theory (TDDFT). Sotolon was shown to exist as a dimer in chloroform while maple furanone remains a monomer. Transition state barriers for the enol/keto tautomerization of sotolon were calculated and found to be high. The VCD method offers promise to ultimately distinguish between the presence of monomers or dimers.     

聚合型硼氢化物(BH3)n(n=1-3)的几何结构与光谱的研究

采用不同方法B3P86,B3LYP,MP2和LSDA,结合Dunning的相关一致基组cc-PVTZ,对聚合型硼氢化物(BH₃)_n(n=1-3)分子的可能几何构型进行优化计算,得出最稳定构型的几何参数、电子结构、振动频率和光谱等性质参数,并给出了最稳定结构的总能量(E_T),结合能(E_BT),平均结合能(E_av),电离势(E_IP),能隙(E_g),费米能级(E_F)等.结果表明:采用密度泛函DFT中的方法B3P86计算的能量最低,结构参数更接近文献值;三种硼氢化物分子基态都为1重态,电子态分别为¹A',¹A和¹A; BH₃分子的最稳定几何构型为平面三角形结构;B₂H₆为对称性乙烯式D_2h立体结构,H-B之间生成氢桥式三中心双电子键;B₃H₉为C_3ν立体结构,也生成氢桥式三中心双电子键,但三个氢桥三中心双电子键彼此隔离.最后分析了三种氢化物的红外和拉曼光谱、平均结合能、电离势、能隙和费米能级等特性,说明(BH₃)_n(n=1-3)三分子中B₂H₆最稳定,H-B桥键键长比端键更长,最强峰红外光谱强度最大. 关键词： 聚合型硼氢化物 几何构型 光谱     

混合交通流时间序列的去趋势波动分析

应用去趋势波动分析法研究交通流时间序列的复杂性,探讨了混合交通流时间序列演变行为的标度指数.根据标度指数的变化特征,进而揭示交通流时间序列所具有的长程相关性和短程相关性.通过分析发现,存在一密度ρ,当ρ₁<ρ<ρ₂时,交通流时间序列具有长程相关性;而当ρ<ρ₁或ρ>ρ₂时,交通流时间序列具有短程相关性,即密度的变化影响着标度指数的变化.另外分析了在不同慢车比率条件下时间序列的标度指数,发现慢车比率的变化 关键词： 混合交通流 去趋势波动分析 时间序列 长程相关     

受扰统一混沌系统基于RBF网络的主动滑模控制

针对受外扰影响的统一混沌系统,提出一种基于径向基函数(RBF)神经网络的主动滑模自适应控制方法.将被控系统分解为受控子系统和自由子系统,利用主动控制思想,建立受控子系统在目标点处的状态误差的可控标准型,设计出一个结构简单的基于滑模趋近率在线参数整定的RBF函数神经网络控制器,并且基于Lyapunov稳定性理论分析了系统的稳定性.仿真结果表明该控制器对系统参数突变和外部干扰具有鲁棒性,同时抑制了抖振. 关键词： 统一混沌系统 主动控制 滑模控制 RBF网络     

脉冲激发三能级体系半导体量子点的单光子发射效率

研究了脉冲激发下单个半导体量子点中单光子发射的统计特性.在旋转波近似条件下，由系统粒子数演化主方程并结合量子回归理论推导了二阶相关函数的运动方程，利用此方程讨论了二阶相关函数随输入脉冲面积的关系.在窄脉冲宽度的脉冲激发下，单光子的发射概率p和效率η都随着强度的增强而产生振荡.研究表明，采用窄脉冲宽度，当输入脉冲面积在π附近时可以得到较高的单光子发射效率. 关键词： 半导体量子点 单光子发射 三能级系统     

基于(火积)耗散率最小的T-Y形肋片构形优化

基于构形理论,以导热和对流换热总(火积)耗散率最小为优化目标,对T-Y形肋片进行构形优化,得到同时考虑导热和对流换热(火积)耗散性能的T-Y形肋片最优构形。结果表明:存在最佳单元级直肋和中部空腔高度和长度比使得T-Y形肋片无量纲当量热阻取得二次最小值。增大肋片高度和长度比和肋片占比有助于提高T-Y形肋片整体传热性能。T-Y形肋片与T形肋片相比,T-Y形肋片二次最小无量纲当量热阻降低32.33%,此时T-Y形肋片温度梯度场更均匀,整体传热性能得到明显提高。     

新型多杂臂超支化聚缩水甘油的简易合成及自组装行为

一种新型的两亲性多杂臂超支化聚缩水甘油(HPG-h-arm)可以通过简单的三部反应制备: 先利用阴离子开环聚合制备HPG核, 再利用1,3-二环己基碳化二亚胺(DCC)缩合反应一步同时将疏水性的棕榈酸(PA)链和活性溴接枝到HPG上面, 最后利用原子转移自由基聚合反应(ATRP)将亲水性的聚(N,N-二甲氨基甲基丙烯酸乙酯) (PDMAEMA)链接枝到HPG表面. 红外光谱(FTIR), 核磁共振(1H-NMR)和凝胶渗透色谱仪(GPC)证实了HPG-h-arm被成功制备. 利用动态光散射仪(DLS), 透射电子显微镜(TEM)和原子力显微镜(AFM)研究了HPG-h-arm在不同溶剂中的自组装行为和形貌. 结果表明HPG-h-arm在不同的溶剂中可以自组装得到不同尺寸的球状胶束.     

Graphene oxide noncovalent photosensitizer and its anticancer activity in vitro

Graphene oxide (GO) was investigated as a potential drug-delivery system due to its special properties and biocompatibility. Thus far, little has been done to use GO as a photosensitive drug-delivery system and to explore its anticancer activity in vitro in photodynamic therapy applications. Here, a novel GO-hypocrellin A (GO-HA) hybrid was prepared by a simple noncovalent method and its photodynamic activity was studied for the first time. The results showed that an efficient loading amount of HA on GO was as high as 1.0 mg mg(-1) and the stability of the hybrid was superior to that of the free hypocrellin A in aqueous solution. Furthermore, GO-HA can be excited by irradiation with light of appropriate wavelength to generate singlet oxygen, and in vitro experiments illustrated that GO-HA was efficiently taken up by tumor cells, and that light irradiation of such impregnated cells resulted in significant cell death. Thus, these properties of GO-HA could possibly make it especially promising for use in clinical photodynamic therapy.