全文获取类型
收费全文 | 21759篇 |
免费 | 3648篇 |
国内免费 | 3651篇 |
专业分类
化学 | 17196篇 |
晶体学 | 396篇 |
力学 | 1148篇 |
综合类 | 311篇 |
数学 | 2329篇 |
物理学 | 7678篇 |
出版年
2024年 | 50篇 |
2023年 | 364篇 |
2022年 | 733篇 |
2021年 | 723篇 |
2020年 | 832篇 |
2019年 | 848篇 |
2018年 | 714篇 |
2017年 | 742篇 |
2016年 | 973篇 |
2015年 | 1044篇 |
2014年 | 1315篇 |
2013年 | 1649篇 |
2012年 | 1871篇 |
2011年 | 2030篇 |
2010年 | 1570篇 |
2009年 | 1474篇 |
2008年 | 1662篇 |
2007年 | 1484篇 |
2006年 | 1240篇 |
2005年 | 1166篇 |
2004年 | 873篇 |
2003年 | 760篇 |
2002年 | 830篇 |
2001年 | 719篇 |
2000年 | 569篇 |
1999年 | 434篇 |
1998年 | 344篇 |
1997年 | 267篇 |
1996年 | 284篇 |
1995年 | 212篇 |
1994年 | 231篇 |
1993年 | 150篇 |
1992年 | 160篇 |
1991年 | 142篇 |
1990年 | 103篇 |
1989年 | 99篇 |
1988年 | 61篇 |
1987年 | 50篇 |
1986年 | 50篇 |
1985年 | 44篇 |
1984年 | 25篇 |
1983年 | 28篇 |
1982年 | 23篇 |
1981年 | 11篇 |
1980年 | 11篇 |
1979年 | 10篇 |
1978年 | 13篇 |
1977年 | 9篇 |
1976年 | 12篇 |
1974年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
91.
Xun Fu Danmei Wu Xiaodong Zhou Huaqiang Shi Zhengshui Hu 《Journal of nanoparticle research》2007,9(4):675-681
Hollow spherical molybdenum disulfide has been successfully synthesized via a solvothermal method using Cyanex 301 as sulfur
source and modification agent. The hollow spheres are characterized by transmission electron microscopy, scanning electron
microscopy, X-ray diffraction and Energy-Dispersive X-ray analysis. The influences of reaction conditions are also discussed
while a mechanism is proposed to explain the formation of the peculiar morphology. 相似文献
92.
复制缺陷型人泡沫病毒载体辅助质粒pΔGP的构建及转染小肠癌细胞的研究 总被引:1,自引:1,他引:0
在人泡沫病毒原病毒全长克隆pHRSV13的基础上,缺失突变gag和pol基因,并且用SV40polyA加尾信号替代人泡沫病毒的3′LTR,构建辅助质粒pΔGP.将复制缺陷型人泡沫病毒载体质粒pGPSNI EGFP和辅助质粒pΔGP分别转染和共转染小肠癌HIC细胞系,荧光显微镜检测发现共转染pGPSNI EGFP和pΔGP的HIC细胞能够强烈表达绿色荧光蛋白,转染有复制缺陷型人泡沫病毒载体质粒pGPSNI EGFP的HIC细胞能够表达少量的绿色荧光蛋白,而转染有辅助载体pΔGP的HIC细胞不表达绿色荧光.结果证明复制缺陷型人泡沫病毒载体的构建成功,表明人泡沫病毒env基因3′端的内部启动子IP具有弱启动子的活性,并且bel基因产生的调控蛋白能够反式激活人泡沫病毒内部启动子IP和5′LTR的启动子. 相似文献
93.
94.
Xiao‐Hui Liu Yan‐Guo Li Ying Lin Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1272-1281
The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. 1H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007 相似文献
95.
96.
S.G. Li G. Fu I. Reading S.B. Tor N.H. Loh P. Chaturvedi S.F. Yoon K. Youcef-Toumi 《Applied Physics A: Materials Science & Processing》2007,89(3):721-728
Micro powder injection molding (μPIM) is one of the potential processes for the mass production of metallic microstructures
and micro components. Here, μPIM is the miniaturization of conventional PIM, which involves four processing steps: mixing,
injection molding, debinding and sintering. This paper looks into the feasibility and effectiveness of μPIM as a key mass
production process for the fabrication of metallic micro components. For it to be an effective re-production process, it is
imperative to examine how well parts can be duplicated/fabricated from a master mold. In this work, the dimensional variation
of high-aspect-ratio micro-pillars arrays, in particular the dimensional shrinkage, global warpage, and surface roughness
at each stage of the μPIM process for a range of molding pressures, are quantified and compared in detail. The sensitivity
of the dimensional variation of the microstructures to the packing pressure is reported. The mechanism behind the dimensional
variation is analyzed.
PACS 81.20.Ev; 81.20.Hy; 81.70.Fy; 07.60.Ly; 81.05.-t 相似文献
97.
Writing-induced nano-deformation of slider body becomes a big concern when the mechanical spacing between the head and disk is continuously reduced to achieve higher magnetic recording areal density. Reduced head–disk spacing increases the risk of head/disk contact and causes the thermal instability in head–disk interface (HDI). This paper reports authors’ efforts towards exploration of interface solutions for writing-induced instability in ultra-low head–disk spacing magnetic system. Multi-shallow step structure with optimized rail position is analyzed and a new femto slider with such structure is explored. The results of numerical simulation indicate that the multi-shallow step structure is an effective approach in reducing the flying height change caused by the writing-induced nano-deformation of the slider body. 相似文献
98.
Tsow-Chang Fu 《Applied Surface Science》2006,253(3):1260-1264
Cr1−xAlxC films were deposited on high-speed steel by RF reactive magnetron sputtering. In this study, we aimed to identify the effect of the Al content on the properties of Cr1−xAlxC films. We found that Cr1−xAlxC films exhibited a fine columnar grain microstructure with some special characteristics, such as high hardness of Hv 1426, a low friction coefficient of 0.29, and a large contact angle of 90° for x = 0.18. Furthermore, an increase in Al content resulted in a decrease in film hardness and an increase in contact angle. Moreover, on annealing at 923 K, the mechanical properties of the films improved and a dense protective film of complex Cr2O3 and Al2O3 oxides was formed on the surface for better wear resistance, which will ultimately increase the lifetime of the high-speed steel substrate. 相似文献
99.
100.
通过X射线衍射及磁测量手段研究了Dy2AlFe16-xMnx化合物的结构和磁性.研究结果表明Dy2AlFe16-xMnx化合物具有六角相的Th2Ni17型结构.对x=1,2的样品采用X射线热膨胀测定法在104-647K的温度范围内测量了其热膨胀性质,发现这些化合物在低温下存在热膨胀反常现象,在居里点附近出现负膨胀性质.对自发磁致伸缩的研究结果表明Dy2AlFe16-xMnx化合物中存在着较强的各向异性的自发磁致伸缩,随着Mn含量的增加,其低温下的自发体磁致伸缩减弱.磁测量结果表明Mn的替代导致Dy2AlFe16-xMnx化合物的居里温度及自发磁化强度急剧下降. 相似文献