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91.
92.
Arturo F. Méndez-Sánchez M. Rosario López-González V. Hugo Rolón-Garrido José Pérez-González Lourdes de Vargas 《Rheologica Acta》2003,42(1-2):56-63
The rheological behavior of a cetylpyridinium chloride 100 mmol l–1/sodium salicylate 60 mmol l–1 aqueous solution was studied in this work under homogeneous (cone and plate) and non-homogeneous flow conditions (vane-bob
and capillary rheometers), respectively. Instabilities consistent with non-monotonic flow curves were observed in all cases
and the solution exhibited similar behavior under the different flow conditions. Hysteresis and the sigmoidal flow curve suggested
as characteristic of systems that show constitutive instabilities were observed when running cycles of increasing and decreasing
stress or shear rate, respectively. This information, together with a detailed determination of steady states at shear stresses
close to the onset of the instabilities, allowed one to show unequivocally that "top and bottom jumping" are the mechanisms
to trigger the instabilities in this micellar system. It is shown in addition that there is not a true plateau region in between
the "top and bottom jumping". Finally, the flow behavior beyond the upturn seemed to be unstable and was found accompanied
by an apparent violation of the no-slip boundary condition. 相似文献
93.
In this paper we study the existence and the stability of bounded solutions of the following non-linear system of parabolic equations with homogeneous Dirichlet boundary conditions:
94.
Hugo A. Morales-Técotl Omar Pedraza Luis O. Pimentel 《General Relativity and Gravitation》2007,39(8):1185-1202
Testing extra dimensions at low-energies may lead to interesting effects. In this work a test point charge is taken to move
uniformly in the 3D subspace of a (3 + n)-brane embedded in a (3 + n + 1)-space with n compact and one warped infinite spatial extra dimensions. We found that the electromagnetic potentials of the point charge
match standard Liennard–Wiechert’s at large distances but differ from them close to it. These are finite at the position of
the charge and produce finite self-energies. We also studied a localized Hydrogen atom and take the deviation from the standard
Coulomb potential as a perturbation. This produces a Lamb shift that is compared with known experimental data to set bounds
for the parameter of the model. This work provides details and extends results reported in a previous Letter.
We are pleased to dedicate this work to Professor Octavio Obregón on occasion of his 60th birthday. H. A. Morales-Técotl is
an associate member of the Abdus Salam ICTP, Trieste Italy. 相似文献
95.
Considerable advances in automatic speech recognition have been made in the last decades, thanks specially to the use of hidden Markov models. In the field of speech signal analysis, different techniques have been developed. However, deterioration in the performance of the speech recognizers has been observed when they are trained with clean signal and tested with noisy signals. This is still an open problem in this field. Continuous multiresolution entropy has been shown to be robust to additive noise in applications to different physiological signals. In previous works we have included Shannon and Tsallis entropies, and their corresponding divergences, in different speech analysis and recognition systems. In this paper we present an extension of the continuous multiresolution entropy to different divergences and we propose them as new dimensions for the pre-processing stage of a speech recognition system. This approach takes into account information about changes in the dynamics of speech signal at different scales. The methods proposed here are tested with speech signals corrupted with babble and white noise. Their performance is compared with classical mel cepstral parametrization. The results suggest that these continuous multiresolution entropy related measures provide valuable information to the speech recognition system and that they could be considered to be included as an extra component in the pre-processing stage. 相似文献
96.
97.
Dongre C Dekker R Hoekstra HJ Pollnau M Martinez-Vazquez R Osellame R Cerullo G Ramponi R van Weeghel R Besselink GA van den Vlekkert HH 《Optics letters》2008,33(21):2503-2505
Using femtosecond laser writing, optical waveguides were monolithically integrated into a commercial microfluidic lab-on-a-chip device, with the waveguides intersecting a microfluidic channel. Continuous-wave laser excitation through these optical waveguides confines the excitation window to a width of 12 microm, enabling high-resolution monitoring of the passage of different types of fluorescent analytes when migrating and being separated in the microfluidic channel by microchip capillary electrophoresis. Furthermore, we demonstrate on-chip-integrated waveguide excitation and detection of a biologically relevant species, fluorescently labeled DNA molecules, during microchip capillary electrophoresis. Well-controlled plug formation as required for on-chip integrated capillary electrophoresis separation of DNA molecules, and the combination of waveguide excitation and a low limit of detection, will enable monitoring of extremely small quantities with high spatial resolution. 相似文献
98.
DNA Photosensitization by an “Insider”: Photophysics and Triplet Energy Transfer of 5‐Methyl‐2‐pyrimidone Deoxyribonucleoside 下载免费PDF全文
Emmanuelle Bignon Hugo Gattuso Prof. Christophe Morell Dr. Elise Dumont Dr. Antonio Monari 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(32):11509-11516
The main chromophore of (6‐4) photoproducts, namely, 5‐methyl‐2‐pyrimidone (Pyo), is an artificial noncanonical nucleobase. This chromophore has recently been reported as a potential photosensitizer that induces triplet damage in thymine DNA. In this study, we investigate the spectroscopic properties of the Pyo unit embedded in DNA by means of explicit solvent molecular‐dynamics simulations coupled to time‐dependent DFT and quantum‐mechanics/molecular‐mechanics techniques. Triplet‐state transfer from the Pyo to the thymine unit was monitored in B‐DNA by probing the propensity of this photoactive pyrimidine analogue to induce a Dexter‐type triplet photosensitization and subsequent DNA damage. 相似文献
99.
Lydia A. Panther Dr. Daniel P. Guest Dr. Andrew McGown Hugo Emerit Dr. Raysa Khan Tareque Dr. Arathy Jose Mr. Chris M. Dadswell Dr. Simon J. Coles Dr. Graham J. Tizzard Dr. Ramón González-Méndez Dr. Charles A. I. Goodall Prof. Mark C. Bagley Prof. John Spencer Dr. Barnaby W. Greenland 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(49):e202201444
Solvent-free synthesis by using a vibratory ball mill (VBM) offers the chance to access new chemical reactivity, whilst reducing solvent waste and minimising reaction times. Herein, we report the core functionalisation of N,N’-bis(2-ethylhexyl)-2,6-dibromo-1,4,5,8-naphthalenetetracarboxylic acid (Br2-NDI) by using Suzuki, Sonogashira and Buchwald–Hartwig coupling reactions. The products of these reactions are important building blocks in many areas of organic electronics including organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs) and organic photovoltaic cells (OPVCs). The reactions proceed in as little as 1 h, use commercially available palladium sources (frequently Pd(OAc)2) and are tolerant to air and atmospheric moisture. Furthermore, the real-world potential of this green VBM protocol is demonstrated by the double Suzuki coupling of a monobromo(NDI) residue to a bis(thiophene) pinacol ester. The resulting dimeric NDI species has been demonstrated to behave as an electron acceptor in functioning OPVCs. 相似文献
100.
Ultraviolet Absorption Induces Hydrogen‐Atom Transfer in G⋅C Watson–Crick DNA Base Pairs in Solution 下载免费PDF全文
Dr. Katharina Röttger Hugo J. B. Marroux Dr. Michael P. Grubb Philip M. Coulter Hendrik Böhnke Dr. Alexander S. Henderson Dr. M. Carmen Galan Prof. Friedrich Temps Prof. Andrew J. Orr‐Ewing Dr. Gareth M. Roberts 《Angewandte Chemie (International ed. in English)》2015,54(49):14719-14722
Ultrafast deactivation pathways bestow photostability on nucleobases and hence preserve the structural integrity of DNA following absorption of ultraviolet (UV) radiation. One controversial recovery mechanism proposed to account for this photostability involves electron‐driven proton transfer (EDPT) in Watson–Crick base pairs. The first direct observation is reported of the EDPT process after UV excitation of individual guanine–cytosine (G?C) Watson–Crick base pairs by ultrafast time‐resolved UV/visible and mid‐infrared spectroscopy. The formation of an intermediate biradical species (G[?H]?C[+H]) with a lifetime of 2.9 ps was tracked. The majority of these biradicals return to the original G?C Watson–Crick pairs, but up to 10 % of the initially excited molecules instead form a stable photoproduct G*?C* that has undergone double hydrogen‐atom transfer. The observation of these sequential EDPT mechanisms across intermolecular hydrogen bonds confirms an important and long debated pathway for the deactivation of photoexcited base pairs, with possible implications for the UV photochemistry of DNA. 相似文献