Gasanalyse

Ohne Zusammenfassung     

Synthesis of Manganese Oxide Microspheres by Ultrasonic Spray Pyrolysis and Their Application as Supercapacitors

Manganese oxide (MnO₂) microspheres are prepared using an ultrasonic spray pyrolysis (USP) process. A mixed solution of potassium permanganate and hydrochloric acid is nebulized into microsized droplets, which are then carried by air flow through a furnace tube. Each microdroplet serves as one microreactor and produces one microsphere. Upon heating, KMnO₄ is decomposed into MnO₂ microspheres; this synthetic process can easily be scaled up. Characterization of the MnO₂ microspheres by scanning electron microscopy, transmission electron microscopy, powder X‐ray diffraction, Raman spectroscopy, and X‐ray photoelectron spectra is described. Different morphologies of MnO₂ microspheres can be controlled by tuning the precursor concentrations (and ratios) and furnace temperatures. Microspheres synthesized at 150 °C give amorphous MnO₂ while synthesis at 500 °C yields crystalline α‐MnO₂. The electrochemical properties investigated by cyclic voltammetry give specific capacitance as high as 320 F g^?1, demonstrating promising properties as supercapacitors. In addition, these microspheres can be directly sprayed on conductive substrates, such as carbon fiber paper, and may have useful applications as a supercapacitor electrode coating. The supercapacitive properties of MnO₂ microspheres at higher charge and discharge rates can be improved by increasing the surface area coverage or coating them with a thin layer of conductive polymer.     

Simulation of three-phase displacement experiments

Three-phase displacement experiments for a water-benzyl alcohol-decane system are simulated. Literature experimental three-phase relative permeabilities for the system are used to describe the relative permeabilities in the three-phase region for different three-phase relative permeability models. Saturation trajectories and elliptical regions are mapped in the three-phase region. Simulations are performed to model displacement experiments including breakthrough and the formation of multiple shocks. The model can be used to predict the results for other displacements. In an experiment where significant gravity segregation is present, the displacement is more accurately modeled by assuming a uniform initial condition than by using the actual vertical saturation and assuming no cross flow. It is shown how different residual saturation values can be measured in the laboratory depending on the initial saturation conditions in the core. The experimental residual saturations can be significantly different than the ‘theoretical’ or model values.     

Impact of perforation impedance on the transmission loss of reactive and dissipative silencers

The effect of perforation impedance on the acoustic behavior of reactive and dissipative silencers is investigated using experimental and computational approaches. The boundary element method (BEM) is applied for the prediction of transmission loss of silencers with different perforation geometries. The variations are considered in the porosity (8.4 and 25.7%) and hole diameter (0.249 and 0.498 cm) of perforations for both reactive and dissipative silencers, as well as the fiber filling density (100 and 200 kg/m3) for the latter. The acoustic impedance for a number of perforations in contact with air alone and fibrous material has been incorporated into the predictions, which are then compared with the measured transmission loss using an impedance tube setup. The results demonstrate the significance of the accuracy of the perforation impedance in the predictions for both reactive and dissipative silencers.     

Solubility and partial molar volume of carbon dioxide and ethane in crosslinked poly(ethylene oxide) copolymer

Experimental solubility and sorptive dilation data are reported for carbon dioxide and ethane in a crosslinked poly(ethylene oxide) (XLPEO) rubbery copolymer. Five different temperatures (253 ≤ T(K) ≤ 308) were considered, with a maximum gas pressure of 2.09 MPa (20.6 atm). The polymer was prepared by photopolymerization of a solution containing 70 wt % poly(ethylene glycol) methyl ether acrylate (PEGMEA) and 30 wt % poly(ethylene glycol) diacrylate (PEGDA). Sorption isotherms were described by the Flory‐Huggins model. For each gas, the Flory‐Huggins interaction parameter was a decreasing function of temperature and did not show a composition dependence. Dilation and sorption data were combined to calculate the partial molar volume (PMV) of the gases in the polymer, which was an increasing function of temperature. Based on a comparison with literature data for a XLPEO homopolymer prepared from pure PEGDA over the same range of operating conditions, an effect of the network composition on both gas solubility and PMV was found. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 456–468, 2010     

A STUDY OF THE PHOTODYNAMIC EFFICIENCIES OF SOME EYE LENS CONSTITUENTS

We have studied the photochemical quantum yields of singlet oxygen production (using the RNO bleaching method) and superoxide production (using the EPR-spin trapping method and the SOD-inhibitable ferricytochrome c reduction spectral assay) of kynurenine (Ky), N-formylkynurenine (NFK), 3-hydroxykynurenine (3HK), kynurenic acid (KUA), and the flavins, riboflavin (RF) and flavin mononucleotide (FMN). Such a study of the photodynamic efficiencies is important since these compounds appear endogenously in the eye. The singlet oxygen quantum yields of the flavins and KUA are high, while Ky and 3HK generate no detectable amounts of singlet oxygen. The superoxide quantum yields of the sensitizers are low compared to their singlet oxygen, and Ky and 3HK produce no detectable amounts of superoxide. The production of the superoxide radical is enhanced in the presence of electron donor molecules such as EDTA and NADH. These results suggest that the production of oxyradicals in the lens may be modulated by the presence of endogenous electron donor molecules such as the coenzymes NADH and NADPH, which are present in significant amounts in some lenses. They also suggest that Ky and 3HK, which are known to be present in aged lenses, might play a protective rather than a deleterious role in the eye.