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51.
Huck WT 《Chemical communications (Cambridge, England)》2005,(33):4143-4148
When organic materials are placed in environments which physically confine the materials at the nanometre scale, interfacial effects and confinement-induced loss of entropy can significantly alter materials' properties such as the glass transition temperature as well as the nanoscale morphology as compared to a "free" system. In block copolymers, nanoconfinement leads to a range of unusual self-organized nanoscale morphologies. In this article, attempts to induce nanoconfinement effects in new polymer systems as well as at interfaces will be highlighted and some possible future implications for organic synthesis and biology will be discussed. 相似文献
52.
Bioanalysis is a fast growing domain with new technological developments in the field of mass spectrometry, separation science, and bioinformatics. The central role of separation prior to detection and evaluation of analytes is indisputable. In fact, since the decipherment of the human genome via multichannel capillary electrophoresis in combination with laser-induced fluorescence [1], the analysis of the proteome, i.e., the type and amount of all proteins expressed at a certain time by the genome in a cell or tissue [2] became of central interest. Therefore, new fast and sensitive capillary liquid chromatographic, electrophoretic, and electrochromatographic separation techniques, suitable for high-throughput analysis of proteins, peptides and nucleic acids, are required. 相似文献
53.
van Delden RA Huck NP Piet JJ Warman JM Meskers SC Dekkers HP Feringa BL 《Journal of the American Chemical Society》2003,125(50):15659-15665
The photochemical control of ground- and excited-state chirality of (M)-cis-(1) and (P)-trans-(2)-2-nitro-7-(dimethylamino)-9-(2',3'-dihydro-1'H-naphtho[2,1-b]-thiopyran-1'-ylidene)-9H-thioxanthene is described. It is shown that while ground state chirality can be controlled photochemically by irradiation with light of different wavelengths, the excited state chirality can be tuned either photochemically in a similar way or by appropriate choice of solvent. In benzene solution, circularly polarized luminescence of the two isomers with opposite ground-state helicity, (M)-cis-1 and (P)-trans-2, revealed corresponding excited states of opposite helicity. On the contrary, in n-hexane solution, circularly polarized luminescence was identical for the two forms indicating identical excited state chirality. Circularly polarized luminescence (CPL), steady-state and time-dependent fluorescence, and time-resolved microwave conductivity (TRMC) measurements in both n-hexane and benzene are reported, which provide an explanation for the remarkable solvent dependence of excited-state chirality. 相似文献
54.
H. Huck 《Analytical and bioanalytical chemistry》1974,270(4):266-273
An analytical fuel cell for the quantitative determination of alcohols is described. As an example of application its use as selective gas-chromatographic detector is demonstrated. The cell contains a symmetrical bipolar Pt/Pt gas diffusion electrode with an acid electrolyte which is surrounded by air on both sides. By this arrangement the reaction was not influenced by air because the rate of chemisorption of ethanol was much greater than that of oxygen. The polarization of the measuring electrode as a criterion of sensitivity was about 3 mV/μg ethanol. 相似文献
55.
56.
The design of novel stationary phases is a permanent demanding challenge in chromatographic separation science to enable analysis with enhanced selectivity, specificity and speed. Therefore, the characterisation of chemical and physical properties is next to calculation of chromatographic parameters essential. Conventionally, chemical parameters including surface coverage are determined by burning combustion or frontal analysis, physical parameters including particle size, pore size, pore volume and surface area are determined by SEM, mercury intrusion porosimetry (MIP) and Brunauer-Emmett-Teller (BET). All these methods are time consuming, invasive and require besides special equipment some special trained laboratory staff. Therefore, we introduced near-infrared spectroscopy (NIRS) as a noninvasive, easy-to-handle technology with wavenumber ranging from 4000 to 10,000 cm(-1) enabling analysis within only a few seconds at higher precision than the conventional methods. Investigated materials comprise porous and nonporous silica gel, carbon-based nanomaterials (fullerenes), polymer beads and monoliths. Different carriers themselves and their kind of derivatisations (RP, normal-phase, ion-exchanger, IMAC (immobilised metal affinity chromatography), affinity) can be determined by applying principal component analysis (PCA) of recorded spectra. Partial least square regression (PLSR) enables the determination of particle size, pore size, pore volume, porosity, total porosity and surface area with one single measurement. For the optimised design of well-defined polymer beads and monoliths, real-time in situ monitoring to control, e. g. particle and pore sizes as well as monomer content during the polymerisation process, can be extremely helpful. In this article, the advantages of this fast, noninvasive high-throughput NIRS methods are summarised, discussed in detail and different applications of the individual characterised materials are shown. 相似文献
57.
Flavonoids were separated utilizing CEC technique. Baseline separation of biologically relevant flavonoids was obtained using a 100 microm ID fused-silica capillary filled with 3 microm Silica-C18 material and an optimized mobile phase comprising of 20 mM Tris-HCl (pH 6.5), ACN and water at a ratio of 10/40/50 v/v/v. Separations were carried out at 25 kV and a column temperature of 25 degrees C. The influence of relevant parameters for the CEC separation, such as buffer concentration, pH, separation voltage, and ACN concentration, was investigated and optimized. Dependencies of the electroendoosmotic flow (EOF) on these parameters and effects on the resolution of the analytes were studied. During analyses the solvents used for dissolving the samples turned out to have significant effects on the separation of flavonoids. The optimized system was then successfully used for the separation of the flavonoids epicatechin, myricetin, quercetin, naringenin, and hesperetin. CEC turned out to be a useful complementary tool for the economic analysis of flavonoids in addition to common HPLC, muHPLC, and CE methodologies. This method can be used for real applications in phytomics. 相似文献
58.
59.
In this review the most important techniques developed to hyphenate CE to MALDI-TOF-MS are summarized. The principles of the different interfaces and ways to solve the hyphenation problem are explained and discussed in detail. The most important applications especially in the proteomic field are reviewed, and the advantages of CE-MALDI-TOF-MS for the analysis of these compounds compared to other techniques such as ESI-MS are exhaustingly discussed from a critical point of view. CE coupled to MALDI-TOF-MS has started to overpass traditionally used CE-coupling techniques, especially CE-ESI-MS, offering the possibility to analyze samples of interest even weeks after CE analysis and using multiplexing systems for high-sample throughput. 相似文献
60.
Yu B Zhou F Liu G Liang Y Huck WT Liu W 《Chemical communications (Cambridge, England)》2006,(22):2356-2358
In this communication we report the first preparation of ionic liquid-modified carbon nanotubes with reversibly switchable solubility between aqueous and organic solvents, induced by anion exchange. 相似文献