低密度聚乙烯光引发交联机理——Ⅱ.BNB自旋捕捉ESR研究

在光引发剂二苯甲酮(BP)存在下,紫外光辐照低密度聚乙烯(LDPE)所形成的自由基中间体已被自旋捕捉剂2,4,6-三特丁基亚硝基苯(BNB)所捕捉,其自旋加合物自由基已为电子自旋共振(ESR)所特征。现已检测和鉴定到二种自旋加合物:一种是叔碳自由基;另一种是仲碳自由基。它们分别是由BP的激发三重态从LDPE链的支化点和亚甲基团上夺氢所形成的自由基中间体同自旋捕捉剂BNB反应生成的。上述的证据表明:LDPE的光引发交联点主要发生在叔碳和仲碳原子上,且H-型交联点占主导地位。     

Molecular deposition film of porphyrin and phthalocyanine bearing oppositely charged substituents

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Scheduling Parts in a Combined Production-transportation Work Cell

This paper is concerned with a combined production-transportation scheduling problem. The problem comprises a simple, two-machine, automated manufacturing cell, which either stands alone or is a subunit of a complete flexible manufacturing system. The cell consists of two machines in series with a dedicated part-handling device such as a crane or robotic arm for transferring parts from the first machine to the second. The loading of a new piece on the first machine and the ejection of a finished piece from the second machine are performed by dedicated automated mechanisms. The introduction of parts into the system is done n at a time, whereby the parts are reshuffled into a sequence that minimizes completion time. All processing and transfer times are considered deterministic—a reasonable assumption for a cell comprising a robotic transfer device and two CNC machining units. What complicates the problem is the assumption of a non-negligible time for the transfer device to return (empty) from the second machine to the first. The operation is a generalization of a two-machine flowshop problem, and is formulated as a specially structured, asymmetric travelling salesman problem. An approximate polynomial time 0(n log n) algorithm is proffered. The procedure incorporates a lower bound using the Gilmore–Gomory algorithm for the no-wait, two-machine flowshop problem.     

Characterization theorem of generalized polynomial of best approximation having bounded coefficients

Let the set of generalized polynomials having bounded coefficients beK={p= _jg_j. _{j j j},j=1, 2, ...,n}, whereg ₁,g ₂, ...,g _n are linearly independent continuous functions defined on the interval [a, b], _j, _j are extended real numbers satisfying _j<+, _j>-, and _{j j}. Assume thatf is a continuous function defined on a compact setX [a, b]. This paper gives the characterization theorem forp being the best uniform approximation tof fromK, and points out that the characterization theorem can be applied in calculating the approximate solution of best approximation tof fromK.     

On the Role of Mixed Strategies in Elementary Decision Analysis and Related Decision-Support-System Treatments

We first demonstrate that mixed strategies are relevant in decision analysis for a maximin decision-maker quite apart from any game-theory considerations. This rectifies the apparent misconception that results from MS/OR textbooks which discuss mixed strategies only in the game-theory setting. Next we show an example of an implementable mixed strategy, by which we mean a mixed decision strategy which does not require randomization for its implementation. This application is to portfolio construction.     

Optimal Discrete Approximations for Continuous Outcomes with Applications in Decision and Risk Analysis

In decision and risk analysis, it is common to use discrete probability distributions to approximate uncertain events with continuous outcomes. This paper discusses how these approximations may be selected. A class of approximations based on a modification to Taguchi's work on tolerance analysis is shown to be optimal under assumptions of independent uncertainties with normally distributed outcomes. The approximation procedure is shown to be robust in many other situations and is extremely easy to use in practice. We also show how the approximation may be integrated into the process of subjective probability estimation by a ‘subject-matter expert’.     

Optimal Inventory Policies with Service-Level Constraints

In a practical situation it is often difficult to determine the value of the shortage costs for use in in ventory-control systems. However, in cost-minimization problems including service-level constraints, shortage costs are implicitly prevailing. With the purpose of exploring these relations, a continuous review (Q, r) stock-control system is considered, where the order points and lot sizes are computed simultaneously. Instead of explicitly expressing the shortage cost in the objective function, it is taken into consideration through a service-level constraint. The shadow price of this constraint can in some sense be interpreted as the shortage cost corresponding to the requested service level. By changing the value of the service level, interesting relations between shortage costs and service levels can be viewed for different sets of other inventory parameters. In order to investigate the sensitivity for probabilistic variations in the input data, two different probability distributions are used to describe the lead-time demand.