Experimental investigation into plastic damage of microvoids with interaction

A mechanism of plastic flow localization in ductile matter near microvoids is studied. The voids with the size-scale of micromillimeter exist in sheet specimens under tensile loading, and the plastic strain field around voids is obtained by digital image processing of deformed grids. The size growth of the microvoids, the spacing change of the neighboring voids, and the development of shear bands in the ligament between the voids, are presented by experimental results accompanied with the plastic strain distribution, that gives good interpretation to the process of void growth and coalescence with the flow localization in the ligaments. The project supported by the National Natural Science Foundation of China     

Mixed convection adjacent to inclined flat surfaces embedded in a porous medium

An analysis is performed to study the flow and heat transfer characteristics of laminar mixed convection boundary layer flows from inclined (including horizontal and vertical) surfaces embedded in a saturated porous medium with constant aiding external flows and uniform surface temperature. Both the streamwise and normal components of the buoyancy forces are retained in the momentum equations. Nondimensionalization of the boundary layer equations results in the following three governing parameter: (1)Gr/Re, the ratio of the Grashof number to the Reynolds number; (2)Pe _x =Re _x Pr, the Peclet number; (3) φ, the angle of inclination from the horizontal. The resulting nonsimilar equations are solved by an efficient implicit finite-difference scheme. Numerical results are presented for flows with different values ofGr/Re in the range of 0 to 50, over a wide range of the Peclet numbersPe _x, and various values of φ ranging from 0 to 90 degrees. It is found that the local surface heat transfer rate increases with increasing the local Peclet number. In addition, as the plate is tilted from the horizontal to the vertical orientation, the local Nusselt number increases for a given Peclet number and the effect of the buoyancy force on the surface heat transfer rate increases.     

考虑弹性地基切向抗力的变截面圆弧壳梁分析

本文根据弹性薄壳理论,考虑了弹性地基径向和切向抗力的影响,解决了变截面圆弧壳地基梁的难题,作者所提出的近似解析法和加权余量法、传递矩阵法较有限单元法简便.     

Low Mach number limit of global solutions to 3‐D compressible nematic liquid crystal flows with Dirichlet boundary condition

In this paper, we consider the uniform estimates of strong solutions in the Mach number ? and t ∈ [0,∞) for the compressible nematic liquid crystal flows in a 3‐D bounded domain , provided the initial data are small enough and the density is close to the constant state. Here, we consider the case that the velocity field satisfies the Dirichlet boundary condition. Based on the uniform estimates, we obtain the global convergence of the compressible nematic liquid crystal system to the incompressible nematic liquid crystals system as the Mach number tends to zero.     

Studies on core–shell structural nano-micelles based on star block copolymer of poly(lactide) and poly(2-(dimethylamino)ethyl methacrylate)

Inorganic/polymer hybrid star-shaped block copolymer nano-micelles were synthesized. In the synthetic route, multi-hydroxyl polyhedral oligomeric silsequioxane(POSS-(OH)₃₂) was employed as the starting molecule to initiate ring-opening polymerization of d,l-lactide. 2-(Dimethylamino)ethyl methacrylate was found to polymerize at the end of polylactic acid chains, following mechanism of atom transfer radical polymerization. The well-defined star block copolymer core–shell nano-micelles were finally obtained. The structures of the copolymer and the micelles were characterized extensively. The micelles exhibited a regular spherical shape with an average diameter of 170 nm which was confirmed by transmission electron microscopy and dynamic laser scattering. The sizes of both the core and the shell were controlled by adjusting the feed ratios during the syntheses. The micelles demonstrated pH- and temperature-sensitive behaviors.     

Studies on syntheses and dynamic swelling of pH-sensitive macroporous poly(N-isopropylacrylamide-co-acrylic acid) hydrogels

A series of macroporous poly(N-isopropylacrylamide-co-acrylic acid) (PNIPAm-AA) hydrogels with different composition were synthesized by free-radical copolymerization in the presence of silica particles as a pore generating agent. The equilibrium swelling ratio, half swelling time and dynamic swelling kinetics of the copolymers previously soaked in different acidic buffer solutions were investigated at pH 7 at 25°C. Experimental results revealed that the swelling rate of the macroporous hydrogels was greatly increased compared to conventional hydrogels due to existence of the macroporous structures. It was found that the swelling history of previously putting in acidic solutions copolymers had strong influence on their dynamic swelling kinetics especially for the samples ranging in composition between 30 and 70 mol % of NIPAAm, whereas the swelling history had little influence on the equilibrium swelling ratio of copolymers. The swelling pattern exhibits sigmoid swelling curves. This is explained by an autocatalytic mechanism. The hydrogen bonding dissociation plays an important role in the dynamic swelling behavior.     

Determination of vertilmicin sulfate and its related substances by HPLC-ELSD and HPLC-MS2

A new and simple high-performance liquid chromatography (HPLC)-evaporative light scattering detection (ELSD) method for the determination of vertilmicin sulfate and its related substances is developed. The column is an Agilent SB-C(18) (250 x 4.6 mm, 5 microm). The mobile phase is 0.05 mol/L trifluoroacetic acid-methanol (85:15). Good separation of vertilmicin from the main related substances is achieved. The standard curve is rectilinear in the range of 270-1350 microg/mL (r = 0.9998). The average recovery is 99.8%. The limit of detection is 10 microg/mL. The HPLC-mass spectrometry-mass spectrometry (MS(2)) method is used to characterize the structures of vertilmicin sulfate and its related substances. In positive mode, vertilmicin sulfate and its related substances are elucidated by use of electrospray ion trap MS in the multi-stage MS full scan mode. The possible structure of an unknown impurity in vertilmicin is deduced based on the HPLC-MS(2) data.     

Photodissociation and photoisomerization of alpha-fluorotoluene and 4-fluorotoluene in a molecular beam

The photodissociation of jet-cooled alpha-fluorotoluene and 4-fluorotoluene at 193 and 248 nm was studied using vacuum ultraviolet (vuv) photoionization/multimass ion imaging techniques as well as electron impact ionization/photofragment translational spectroscopy. Four dissociation channels were observed for alpha-fluorotoluene at both 193 and 248 nm, including two major channels C6H5CH2F-->C6H5CH2 (or C7H7)+F and C6H5CH2F-->C6H5CH (or C7H6)+HF and two minor channels C6H5CH2F-->C6H5CHF+H and C6H5CH2F-->C6H5+CH2F. The vuv wavelength dependence of the C7H7 fragment photoionization spectra indicates that at least part of the F atom elimination channel results from the isomerization of alpha-fluorotoluene to a seven-membered ring prior to dissociation. Dissociation channels of 4-fluorotoluene at 193 nm include two major channels C6H4FCH3-->C6H4FCH2+H and C6H4FCH3-->C6H4F+CH3 and two minor channels C6H4FCH3-->C6H5CH2 (or C7H7)+F and C6H4FCH3-->C6H5CH (or C7H6)+HF. The dissociation rates for alpha-fluorotoluene at 193 and 248 nm are 3.3 x 10(7) and 5.6 x 10(5) s(-1), respectively. The dissociation rate for 4-fluorotoluene at 193 nm is 1.0 x 10(6) s(-1). An ab initio calculation demonstrates that the barrier height for isomerization from alpha-fluorotoluene to a seven-membered ring isomer is much lower than that from 4-fluorotoluene to a seven-membered ring isomer. The experimental observed differences of dissociation rates and relative branching ratios between alpha-fluorotoluene and 4-fluorotoluene may be explained by the differences in the six-membered ring to seven-membered ring isomerization barrier heights, F atom elimination threshold, and HF elimination threshold between alpha-fluorotoluene and 4-fluorotoluene.