大体积进样技术在环境分析中的应用

在毛细管气相色谱法(CGC)中,采用大体积进样技术(LVI),即使用能够容纳大体积样品的进样装置以及增加可控时间的溶剂蒸汽放空装置,可以满足环境样品中超痕量组分的分析要求,简化样品浓缩步骤以及实现液相色谱(LC)与CGC的在线联用。针对分析物的性质、毛细管柱的规格和分析的目的已发展了多种LVI。本文总结了几种常见的LVI,包括柱头进样(OCI)和程序升温进样(PTV),以及近年来发展的一些新技术,如在柱同时溶剂浓缩进样、样品直接引入进样/复杂基质进样和同时溶剂冷凝无分流进样,阐述了各种进样技术的基本原理及其与样品提取、LC纯化在线联用的方法在环境分析应用中的一些最新研究进展。     

Coupled heat and mass transfer in the entrance region of a circular tube with fully-developed parabolic flow and external convective heating

Coupled heat and mass transfer in the entrance region of a circular tube with fully-developed parabolic flow and external heating is analyzed. The closed form solutions of temperature and concentration distributions, local Nusselt numbers based on the total external heat transfer and convective heat transfer inside the tube, as well as the Sherwood number were obtained. The effects of Biot and Lewis number on heat and mass transfer were investigated.     

Simulation of random packing of spherical particles with different size distributions

A numerical model for a loose packing process of spherical particles is presented. The simulation model starts with randomly choosing a sphere according to a pregenerated continuous particle-size distribution, and then dropping the sphere into a dimension-specified box, and obtaining its final position by using dropping and rolling rules which are derived from a similar physical process of spheres dropping in the gravitational field to minimize its gravity potential. Effects of three different particle-size distributions on the packing structure were investigated. Analysis on the physical background of the powder-based manufacturing process is additionally applied to produce optimal packing parameters of bimodal and Gaussian distributions to improve the quality of the fabricated parts. The results showed that higher packing density can be obtained using bimodal size distribution with a particle-size ratio from 1.5 to 2.0 and the mixture composition around n ₂:n ₁=6:4. For particle size with a Gaussian distribution, the particle radii should be limited in a narrow range around 0.67 to 1.5.     

应变测量的光栅法

本文提出一种新的应变测量方法。用模压全息光栅作为应变传感器，测量光栅衍射点空间位置的变化量，直接获得应变或应力分量。全息光栅的模压制作，可以大幅度地降低成本。视频技术与微机技术的运用可以自动地获得应变和应力的数值。     

非单特征值的广义分歧定理

讨论了抽象算子方程F(λ,u)=0的局部分歧问题,其中F:R×X→Y是一个C~2微分映射,λ是参数,X,Y为Banach空间.利用Lyapunov-Schmidt约化过程及偏导算子F_u(λ~*,O)的有界线性广义逆,在dim N(F_u(λ~*,0))≥codim R(F_u(λ~*,O))=1的条件下,证明了一个广义跨越式分歧定理.当参数空间的维数等于值域余维数时,应用同样的方法又得到了多参数方程的抽象分歧定理.     

11种吸附剂上二噁英的热吸附/脱附性能评价

筛选在低温下高效捕集并在一定的高温下可以快速完全脱附二噁英的吸附/脱附材料是二噁英在线热捕集的关键.该研究以1,2,3,4-四氯代二苯并-对-二噁英(1,2,3,4-TCDD)和1,2,3,8,9-五氯代二苯并呋喃(1,2,3,8,9-PCDF)为二噁英模型物,以电子捕获检测器(ECD)作为检测器,利用填充柱气相色谱系...     

Recent Advances in the One‐Step Synthesis of Distally Fluorinated Ketones

Fluorinated ketones are intriguing compounds in synthetic chemistry and life science‐related fields. The development of efficient methodologies to obtain these compounds is of significant importance and has therefore attracted considerable attention. This Minireview highlights recent progress made in the synthesis of fluorine‐containing ketones, with an emphasis on those methods in which the construction of carbonyl groups is synergetic with distal (β‐, γ‐, δ‐, etc.) incorporation of fluorine atoms or fluorinated groups.     

实时光电混合联合变换相关器单元的实验研究

本文根据联合变换相关的原理，提出了一种实时光电混合联合变换相关器，它采用一个液晶光阀作为输入器件，用另一个液晶光阀记录和显示联合功率谱，所给出的实验结果证实了该系统设计及性能分析的正确性。     

两维空间光调制器及其在实时图象处理中的应用

本文系统的报道了我们研制成功的几种两维空间光调制器,包括液晶光阀(LCLV),Si-LCLV,CRT-LCLV,和光折空间光调制器(PR-SLM)。最后给出利用它们在实时图象处理中的应用成果。     

Optical Fiber Dispersion Compensation by Chirped Fiber Bragg Grating

１ＩｎｔｒｏｄｕｃｔｉｏｎＵｓｉｎｇｄｉｓｐｅｒｓｉｏｎｃｏｍｐｅｎｓａｔｉｎｇｔｅｃｈｎｉｑｕｅｓｔｏｕｐｇｒａｄｅｔｈｅｅｘｉｓｔｉｎｇｎｏｎｄｉｓｐｅｒｓｉｏｎｓｈｉｆｔｅｄｆｉｂｅｒ（ＮＤＳＦ）ｔｅｌｅｃｏｍｍｕｎｉｃａｔｉｏｎｓｙｓｔｅｍｉ...