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201.
Zhang Xin Ding Yunqian Feng Huanran Gao Huanhuan Ke Xin Zhang Hongtao Li Chenxi Wan Xiangjian Chen Yongsheng 《中国科学:化学(英文版)》2020,63(12):1799-1806
Science China Chemistry - Side chain engineering plays a substantial role for high-performance organic solar cells (OSCs). Herein, a series of non-fullerene acceptor (NFA) molecules with A-D-A... 相似文献
202.
The fatigue lives of materials and structures at different strain levels show heteroscedasticity. In addition, when the number of test specimens is insufficient, the fatigue strength coefficient and fatigue ductility coefficient of the fitting parameters in the total strain life equation may not have definite physical significance. In this work, a maximum likelihood method for estimating probabilistic strain amplitude-fatigue life curves is presented based on the fatigue lives at different strain levels. The proposed method is based on the general basic assumption that the logarithm of fatigue life at an arbitrary strain level is normally distributed. The relationship among the parameters of total strain life equation, monotonic ultimate tensile stress and percentage reduction of area is adopted. The presented approach is finally illustrated by two applications. It is shown that probabilistic strain amplitude-fatigue life curves can be easily estimated based on the maximum likelihood method. The results show that fatigue lives at different strain levels have heteroscedasticity and the values of fatigue strength coefficient and fatigue ductility coefficient obtained by the proposed method are close to those of the true tensile fracture stress and true tensile fracture strain. 相似文献
203.
Science China Mathematics - Let R be an Artin algebra and e be an idempotent of R. Assume that Tor (Re, G) = 0 for any G ∈ Gproj eRe and i sufficiently large. Necessary and sufficient... 相似文献
204.
A novel propisochlor microcapsules suspension (CS) was prepared via in-situ polymerization. The preparation of melamine-formaldehyde resin microcapsules containing propisochlor with different ratios of core-shell material was investigated. The synthesized microcapsules were characterized by Fourier Transform Infrared spectrometer, Scanning Electron Microscope, Ultraviolet spectrometry, Thermogravimetric analyses and particle size analyzer. As the ratio of core/shell was 1, the diameter of the prepared microcapsules was the smallest (3.55?µm), while narrowest size distribution (span: 1.19) and the melamine formaldehyde microcapsules possessed the highest encapsulation efficiency (93.26%). The surface of the microcapsules was smooth and the microcapsules had poor adhesion. These microcapsules had compact microstructures and global shapes, which had a good thermal stability and propisochlor could be preserved better in the poly(melamine-formaldehyde) (PMF) microcapsules. These results indicated that the prepared microcapsule had better performance. Additionally, the propisochlor was easily degraded through microorganisms and had a short half-life. The microcapsule suspension of propisochlor hasn’t been researched yet. Therefore, it is significant to prepare microcapsule suspension. The technology of controlled release has effectively prolonged the persistence of active ingredients. More importantly, there is no use of organic solvents in the preparation of microcapsules suspension, which avoided the pollution of solvents to the ecological environment. 相似文献
205.
Based on recently synthesized two-dimensional graphdiyne, we have constructed several hydrogenated graphdiyne structures and studied their electronic structures and magnetic properties by first-principles calculations. Both direct and indirect band gap semiconductors are found in the nomagnetic hydrogenated configurations. Moreover, half semiconductors are found in the magnetic ground states of some hydrogenated graphdiyne structures we considered, although there is no transition metal element in the materials. 相似文献
206.
采用比较分子场分析(CoMFA)和比较分子相似性指数分析(CoMSIA)方法,研究了香水百合中38种香气成分分子结构与气相色谱保留指数值之间的定量构效关系。用外部测试集验证法和留一交叉验证法对模型的稳健性和预测能力进行了检验,并通过CoMSIA模型和CoMFA模型的分子场三维等势图研究了这些化合物分子中不同化学结构对保留指数值的影响。检验结果表明,所建立的CoMSIA模型和CoMFA模型都具有较好的稳健性和预测能力,且能够合理解释结构对保留指数值的影响,可应用于对香水百合香气成分的色谱保留指数值的预测。与CoMFA模型相比,CoMSIA模型的预测准确度更高,在香水百合香气成分的色谱定量构效关系研究中,显然有更好的应用前景。 相似文献
207.
讨论了一类在轴向载荷作用下,有限长粘弹性梁的非线性振动问题,用Galerkin方法证明了问题的整体强解和整体经典解的存在性. 相似文献
208.
Wenjuan Li Wenmin Guo Hongling Zhang Huanhuan Xu Liang Chen Junshan Zeng Bin Liu Zhibing Ding 《Entropy (Basel, Switzerland)》2022,24(4)
FeCoCrNi and FeCoNiCrMo0.2 high-entropy alloy powders were prepared by gas atomization. Two kinds of coatings were prepared on the surface of 304 stainless steel by laser cladding technology. The effect of Mo element on the microstructure of laser cladding FeCoCrNi coating and its corrosion behavior in 3.5 wt.% NaCl solution was investigated. Both FeCoCrNi and FeCoCrNiMo0.2 powders exhibit a single-phase FCC structure. Due to the remelting and multiple heat treatments during the preparation of the laser cladding coating, a small amount of σ and μ phases appeared in the FeCoCrNiMo0.2 coating. The microstructures of the two coatings from the bonding area to the top layer are planar, columnar and equiaxed grains, respectively. The addition of the Mo element causes the dendrite size in the middle region of the FeCoCrNiMo0.2 coating increases significantly and exhibits obvious orientation characteristics. FeCoCrNiMo0.2 coating has high corrosion potential (−0.01 VSHE) and low current density (0.94 × 10−7 A/cm2) in 3.5 wt.% NaCl solution, showing excellent corrosion resistance. The passivation film formed on corroded the FeCoCrNiMo0.2 coating contains high content of oxides of Cr and Mo. The addition of the Mo element enhances the compactness and pitting resistance of the passivation film. 相似文献
209.
Hui Li Huanhuan Li Wu Wang Ye Tao Shuang Wang Qingqing Yang Yunbo Jiang Chao Zheng Wei Huang Runfeng Chen 《Angewandte Chemie (International ed. in English)》2020,59(12):4756-4762
Purely organic materials showing room temperature phosphorescence (RTP) and ultralong RTP (OURTP) have recently attracted much attention. However, it is challenging to integrate circularly polarized luminescence (CPL) into RTP/OURTP. Here, we show a strategy to realize CPL‐active OURTP (CP‐OURTP) by binding an achiral phosphor group directly to the chiral center of an ester chain. Engineering of this flexible chiral chain enables efficient chirality transfer to carbazole aggregates, resulting in strong CP‐OURTP with a lifetime of over 0.6 s and dissymmetry factor of 2.3×10?3 after the conformation regulation upon photo‐activation. The realized CP‐OURTP is thus stable at room temperature but can be deactivated quickly at 50 °C to CP‐RTP with high CPL stability during the photo‐activation/thermal‐deactivation cycles. Based on this extraordinary photo/thermal‐responsive and highly reversible CP‐OURTP/RTP, a CPL‐featured lifetime‐encrypted combinational logic device has been successfully established. 相似文献
210.
利益冲突是影响供应链绩效的重要原因,如何消除供应链冲突、设置合理的协调机制对供应链稳定和可持续发展具有重要的意义.考虑到供应商努力水平和风险规避行为是影响供应链绩效的重要因素,利用博弈论和"均值-方差法",构建一种基于供应商努力水平的主体效用模型,设计了基于增值利润共享的供应链协调机制.结果表明,所设计的机制能够有效地保障供应链主体在利润不受损情形下调动成员合作的积极性与能动性,实现零售商与供应商长期合作和供应链的可持续发展. 相似文献