全文获取类型
收费全文 | 29940篇 |
免费 | 4226篇 |
国内免费 | 2710篇 |
专业分类
化学 | 20470篇 |
晶体学 | 284篇 |
力学 | 1948篇 |
综合类 | 276篇 |
数学 | 3281篇 |
物理学 | 10617篇 |
出版年
2024年 | 105篇 |
2023年 | 589篇 |
2022年 | 907篇 |
2021年 | 956篇 |
2020年 | 1112篇 |
2019年 | 1083篇 |
2018年 | 911篇 |
2017年 | 814篇 |
2016年 | 1280篇 |
2015年 | 1269篇 |
2014年 | 1537篇 |
2013年 | 2050篇 |
2012年 | 2631篇 |
2011年 | 2659篇 |
2010年 | 1647篇 |
2009年 | 1632篇 |
2008年 | 1736篇 |
2007年 | 1661篇 |
2006年 | 1490篇 |
2005年 | 1228篇 |
2004年 | 940篇 |
2003年 | 789篇 |
2002年 | 751篇 |
2001年 | 563篇 |
2000年 | 559篇 |
1999年 | 652篇 |
1998年 | 581篇 |
1997年 | 575篇 |
1996年 | 659篇 |
1995年 | 507篇 |
1994年 | 465篇 |
1993年 | 389篇 |
1992年 | 371篇 |
1991年 | 322篇 |
1990年 | 255篇 |
1989年 | 203篇 |
1988年 | 157篇 |
1987年 | 138篇 |
1986年 | 127篇 |
1985年 | 119篇 |
1984年 | 88篇 |
1983年 | 61篇 |
1982年 | 41篇 |
1981年 | 36篇 |
1980年 | 18篇 |
1978年 | 19篇 |
1977年 | 23篇 |
1976年 | 20篇 |
1975年 | 28篇 |
1974年 | 27篇 |
排序方式: 共有10000条查询结果,搜索用时 19 毫秒
801.
Jingen Wang Xihe Huang Changcang Huang Haiyan Song Duoping Yang 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(12):m583-m585
In the title complex, poly[triaquabis(dimethylformamide)di‐μ3‐oxalato‐μ2‐oxalato‐dilanthanum(III)], [La2(C2O4)3(C3H7NO)(H2O)3]n, both La ions are coordinated by nine O atoms, forming slightly distorted tricapped trigonal prisms. The two La ions, the terminal water O atom, and the O and N atoms of the dimethylformamide molecule reside on twofold rotation axes, giving the two La‐centered coordination geometries twofold or pseudo‐twofold symmetries. The two oxalate ligands, one of which rests on a center of inversion at the mid‐point of the C—C bond, adopt different bridging modes, connecting with the La ions to form two types of lanthanide oxalate chains, i.e. anionic {[La(C2O4)2(DMF)(H2O)2]n−}n (DMF is dimethylformamide) and cationic zigzag {[La(C2O4)(H2O)]n+}n, respectively. Each zigzag cationic chain is linked to four adjacent anionic chains via the bridging oxalate anions, and each anionic chain connects with four zigzag cationic chains, constructing a three‐dimensional neutral framework. 相似文献
802.
测定了24例甲亢治疗前后及30例健康对照的头发锌、硒、钒、锂及锗的含量,发现未治疗的甲亢头发锌、硒、钒、锂及锗含量较对照组低,Zn、Se、Li、Ge,P<0.001,V,P<0.01.甲亢经6~12周抗甲亢药物治疗后.头发中5种元素均较治疗前上升(P<0.001),且头发钒和锂含量治疗后已达到对照组水平,V,P>0.2,Li,P>0.1,而头发锌、晒及锗含量治疗后仍低于对照组(P<0 .001).结论:甲亢头发锌、硒、钒、锂及锗含量降低.经6~12周抗甲亢治疗可使头发钒及锂含量恢复正常水平,而其余3种元素则可能需要更长时间的抗甲亢治疗才能恢复至正常水平。 相似文献
803.
beta-Phenylseleno-alpha-tolylsulfonyl-substituted alkenes were synthesized via the three-component conjugate-nucleophilic addition of acetylenic sulfones, phenylselenomagnesium bromide, and carbonyl compounds, such as aldehydes, aliphatic ketones, or alpha,beta-unsaturated enals or enones. The reaction is highly regio- and stereoselective with moderate to good yields. Functionalized allylic alcohols were obtained in the case of aldehydes and aliphatic ketones. In the case of alpha,beta-unsaturated enones, functionalized allylic alcohols or functionalized gamma,delta-unsaturated ketones were obtained, depending on the structures of the ketones. 相似文献
804.
LiMnC2O4(Ac) precursor in which Li+ and Mn2+ were amalgamated in one molecule was prepared by solid-state reaction at room-temperature using manganese acetate, lithium hydroxide and oxalic acid as raw materials. By thermo-decomposition of LiMnC2O4(Ac) at various temperatures, a series of Li1+y[Mn2−xLix]16dO4 spinels were prepared with Li2MnO3 as impurities. The structure and phase transition of these spinels were investigated by XRD, TG/DTA, average oxidation state of Mn and cyclic voltammeric techniques. Results revealed that the Li-Mn-O spinels with high Li/Mn ratio were unstable at high temperature, and the phase transition was associated with the transfer of Li+ from octahedral 16c sites to 16d sites. With the sintering temperature increasing from 450 to 850 °C, the phase structure varied from lithiated-spinel Li2Mn2O4 to Li4Mn5O12-like to LiMn2O4-like and finally to rock-salt LiMnO2-like. A way of determining x with average oxidation state of Mn and the content of Li2MnO3 was also demonstrated. 相似文献
805.
806.
Seong-Je?Huang Jin-Kook?Lee Chang-Sik?HaEmail author 《Colloid and polymer science》2004,282(6):575-582
The object of this work was to prepare high-density polyethylene (HDPE)/ethylene–propylene–diene terpolymer (EPDM)/conductive carbon black (CB) composites by dynamic curing and to characterize the positive-temperature-coefficient (PTC) performances of the composites.EPDM and dicumyl peroxide were preblended in a research mill. The roll-milled strands were blended with HDPE and CB in a Haake mixer. The sheet resistivity and morphology of the HDPE/EPDM/CB composites with or without the dynamic curing process were investigated. It was concluded that the dynamically cured blends exhibit better PTC performance than the simple blends without dynamic curing. The effects of shear intensity and dicumyl peroxide content during the dynamic curing process were discussed for the PTC characteristics of the HDPE/EPDM/CB composites. 相似文献
807.
氟代乙烯阳离子的理论研究 总被引:1,自引:0,他引:1
用B3LYP和MP2方法及6-31G(d, p)、6-31+G(d, p)、6-311G(d, p)和6-311+G(d, p) 基组,对六种氟代乙烯阳离子做了理论研究,优化了它们的基电子态的结构,计算了对应分子的垂直电离势(VIP)和绝热电离势(AIP).结果表明,与具有非平面结构的乙烯阳离子不同,六种氟代乙烯阳离子都只具有平面结构;与分子结构相比,离子结构的C-C键增长, C-F键缩短, CCF键角变小. 自然布居分析计算表明,这些离子的正电荷主要分布在与F原子相连的C原子和各H原子上. B3LYP/6-311+G(d, p) 级别上计算的各分子的VIP和AIP值和实验值符合得很好. 使用含弥散基函数的基集可以明显提高这类分子的电离势的计算精度. 相似文献
808.
纳米Y2O3/钴基合金激光熔覆层的组织 总被引:6,自引:0,他引:6
利用5 kW CO2激光器,在Ni基高温合金表面,熔覆纳米稀土氧化物(Y2O3)/钴基合金复合材料,制备了涂层.利用光学显微镜、扫描电镜及透射电镜分析了熔覆层的组织结构.结果表明: 熔覆层的主要相组成为γ-Co,ε-Co,Cr23C6和Y2O3;加入纳米Y2O3,凝固组织由细长的柱状树枝晶转变为较短的树枝晶;纳米Y2O3含量增大至1%时整个断面获得等轴晶组织;纳米Y2O3作为异质形核的核心,细化了组织;纳米Y2O3在熔覆层中分布不均匀,促进了γ-Co向ε-Co的转变;熔覆层的亚结构为堆跺层错.对熔覆层等轴组织形成机制进行了分析. 相似文献
809.
ZHANG Xingwen HU Lijiang HUANG Yudong SUN Dezhi & SUN Yi . Department of Applied Chemistry Harbin Institute of Technology HUANG Yudong Harbin China . Department of Environmental Engineering Harbin Institute of Technology Harbin China . Department of Experimental Mechanics Harbin Institute of Technology Harbin China 《中国科学B辑(英文版)》2004,47(5):388-395
Silsesquioxanes (SSO) or polyhedral oligomericsilsesquioxanes (POSS) are generally prepared frommolecular precursors using the hydrolytic condensa-tion of trialkoxysilane, RSi(OR')3. They are organic/inorganic hybrid nanostructural blocks with theircomplete general formula Tn(T = RSiO1.5, n = 1,2, …), and the incomplete generic formula is Tn-(OH)x(OR')y[x, y = 0, 1, 2, …, T= RSiO1.5 ?(x+y)/2n][1,2].Each VSSO, possessing a certain structural formulaand molecular weight, may h… 相似文献
810.
合成了硫氰酸合希土酸四丁基季铵盐配合物,测定了它们的远红外光谱及部分配合物的中红外光谱,结果表明,配合物中的NCS-是以氮原子与Ln3+配位。用X射线单晶衍射法测定了[(n-C4H9)4N]3Nd(NCS)6晶体的结构,结果表明,该晶体属单斜晶系,Cc空间群,晶胞参数为:a=25.188(8)Å,b=13.320(6)Å,c=25.322(8)Å,β=121.30(2)°,晶胞体积V=7258.9Å3,每一晶胞中有四个配合物分子,中心离子Nd3+与六个来自NCS-的氮原子配位,这六个氮位于配位正八面体的六个顶角上,构成配阴离子Nd(NCS)63-,它与三个[(n-C4H9)4N]+以静电引力结合成中心分子,所以晶体为离子型晶体。 相似文献