全文获取类型
收费全文 | 2048篇 |
免费 | 371篇 |
国内免费 | 352篇 |
专业分类
化学 | 1710篇 |
晶体学 | 53篇 |
力学 | 76篇 |
综合类 | 24篇 |
数学 | 203篇 |
物理学 | 705篇 |
出版年
2024年 | 6篇 |
2023年 | 64篇 |
2022年 | 102篇 |
2021年 | 116篇 |
2020年 | 148篇 |
2019年 | 128篇 |
2018年 | 105篇 |
2017年 | 98篇 |
2016年 | 143篇 |
2015年 | 159篇 |
2014年 | 151篇 |
2013年 | 186篇 |
2012年 | 172篇 |
2011年 | 146篇 |
2010年 | 152篇 |
2009年 | 130篇 |
2008年 | 112篇 |
2007年 | 109篇 |
2006年 | 82篇 |
2005年 | 66篇 |
2004年 | 51篇 |
2003年 | 47篇 |
2002年 | 52篇 |
2001年 | 48篇 |
2000年 | 23篇 |
1999年 | 19篇 |
1998年 | 14篇 |
1997年 | 14篇 |
1996年 | 15篇 |
1995年 | 8篇 |
1994年 | 11篇 |
1993年 | 18篇 |
1992年 | 10篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 9篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 5篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1979年 | 1篇 |
1976年 | 2篇 |
1924年 | 1篇 |
1884年 | 1篇 |
排序方式: 共有2771条查询结果,搜索用时 812 毫秒
61.
62.
Jincheng Li Huan Liu Chaoying Wang Lidong Wu Dan Liu 《Analytical and bioanalytical chemistry》2016,408(24):6537-6544
63.
As an emerging donor building block, naphthodithiophene (NDT) is causing more concerns in the field of organic semiconductors. With the rigid and coplanar molecule structure, NDT will exhibit more application space relying on its own advantage for facilitating the charge carrier transport. In this review article, we have summarized the development progress on the NDT-based donor materials for solution processed organic solar cells. Discussions and comments on those representative NDT type materials about structure and property are also presented. 相似文献
64.
Yanfeng Chu Huan Yu Yunti Zhang Guangyan Zhang Yingying Ma Renxi Zhuo Xulin Jiang 《Journal of polymer science. Part A, Polymer chemistry》2014,52(23):3346-3355
Biodegradable amphiphilic ABC Y‐shaped triblock copolymer (MPBC) containing PEG, PBLA, and PCL segments was synthesized via the combination of enzymatic ring‐opening polymerization (ROP) of epsilon‐caprolactone, ROP of BLA‐N‐carboxyanhydride and click chemistry, where PEG, PBLA, and PCL are poly(ethylene glycol), poly(benzyl‐l ‐aspartate), and polycaprolactone, respectively. Propynylamine was employed as ROP initiator for the preparation of alkynyl‐terminated PBLA and methyloxy‐PEG with hydroxyl and azide groups at the chain‐end was used as enzymatic ROP initiator for synthesis of monoazido‐midfunctionalized block copolymer mPEG‐b‐PCL. The subsequent click reaction led to the formation of Y‐shaped asymmetric heteroarm terpolymer MPBC. The polymer structures were characterized by different analyses. The MPBC terpolymer self‐assembled into micelles and physically encapsulated drug doxorubicin (DOX) to form DOX‐loaded micelles, which showed good stability and slow drug release. In vitro cytotoxicity study indicated that the MPBC micelles were nontoxic and the DOX‐loaded micelles displayed obvious anticancer activity similar to free DOX against HeLa cells. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 3346–3355 相似文献
65.
66.
Wang Fei Cressault Yann Teulet Philippe Li Huan Yang Ke 《Plasma Chemistry and Plasma Processing》2019,39(4):1049-1069
Plasma Chemistry and Plasma Processing - Gas tungsten arc welding (GTAW), a widely used industrial process, is one of the most intense artificial sources of optical radiation. This paper presents a... 相似文献
67.
Using a molecular dynamics simulation technique,we compared several commonly used ion-water models to describe the microscopic structures and dynamics in KSCN aqueous solutions.Results are compared with observations of femtosecond infrared vibrational-energy transfer and anisotropy measurements.The Jorgensen/TIP4P model is found to provide the best reproduction of clustering properties such as percentage of clustered ions,cluster-size distribution,concentration dependence of the water,and ion-rotation time constants. 相似文献
68.
Yushu Liu Chun Gao Qing Li Prof. Dr. Huan Pang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(9):2141-2160
Nickel oxide (NiO) has emerged as one of the most promising transition-metal oxides (TMOs) for electrochemical capacitors, batteries, catalysis, and electrochromic films, owing to its cost-effectiveness, abundance, and well-defined electrochemical properties. Recent studies have identified that mixing NiO with graphene or graphene derivatives results in novel composites with synergistic effects and superior electrochemical performance. This review summarizes the latest advances in composites of NiO with graphene or graphene derivatives. The synthetic strategies, morphologies, and electrochemical performance of these composites are introduced, as well as their electrochemical applications in supercapacitors, batteries, sensors, catalysis, and so forth. Finally, tentative conclusions and assessments regarding the opportunities and challenges for the future development of these composites and other TMOs/graphene or graphene-derived composites are presented. 相似文献
69.
70.
Yingying Ma Guangyan Zhang Lingjuan Li Huan Yu Jia Liu Chaoqun Wang Yanfeng Chu Renxi Zhuo Xulin Jiang 《Journal of polymer science. Part A, Polymer chemistry》2016,54(7):879-888
The pH‐sensitive tertiary amino groups were introduced to synthesize temperature and pH dual‐sensitive degradable polyaspartamide derivatives (phe/DEAE‐g‐PHPA) containing pendant aromatic structures and ionizable tertiary amino groups. The thermo/pH‐responsive behavior of phe/DEAE‐g‐PHPA polymer can be tuned by adjusting the graft copolymer composition. Due to the pH sensitivity of the phe/DEAE‐g‐PHPA‐g‐mPEG polymer with hydrophilic long PEG chain, the micelles and the anticancer drug‐loaded micelles were prepared by a quick pH‐changing method without using toxic organic solvent. The obtained polymeric micelles, paclitaxel‐loaded micelles and doxorubicin‐loaded micelles were stable under physiological conditions. Both the drug‐loaded micelles showed much faster release at pH 5 than at pH 7.4. The doxorubicin‐loaded micelles showed obvious and better anticancer activity against both HepG2 and HeLa cells than free doxorubicin. Thus these nontoxic, dual thermo‐ and pH‐sensitive phe/DEAE‐g‐PHPA‐g‐mPEG micelles may be a promising anticancer drug delivery system. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 879–888 相似文献