全文获取类型
收费全文 | 32417篇 |
免费 | 5369篇 |
国内免费 | 3715篇 |
专业分类
化学 | 23433篇 |
晶体学 | 341篇 |
力学 | 2289篇 |
综合类 | 199篇 |
数学 | 3666篇 |
物理学 | 11573篇 |
出版年
2024年 | 73篇 |
2023年 | 640篇 |
2022年 | 1080篇 |
2021年 | 1057篇 |
2020年 | 1225篇 |
2019年 | 1201篇 |
2018年 | 1015篇 |
2017年 | 1000篇 |
2016年 | 1543篇 |
2015年 | 1434篇 |
2014年 | 1797篇 |
2013年 | 2226篇 |
2012年 | 2921篇 |
2011年 | 2948篇 |
2010年 | 2015篇 |
2009年 | 1822篇 |
2008年 | 2133篇 |
2007年 | 1899篇 |
2006年 | 1810篇 |
2005年 | 1532篇 |
2004年 | 1121篇 |
2003年 | 963篇 |
2002年 | 945篇 |
2001年 | 802篇 |
2000年 | 642篇 |
1999年 | 685篇 |
1998年 | 556篇 |
1997年 | 506篇 |
1996年 | 556篇 |
1995年 | 492篇 |
1994年 | 386篇 |
1993年 | 307篇 |
1992年 | 317篇 |
1991年 | 318篇 |
1990年 | 252篇 |
1989年 | 221篇 |
1988年 | 165篇 |
1987年 | 136篇 |
1986年 | 130篇 |
1985年 | 100篇 |
1984年 | 83篇 |
1983年 | 69篇 |
1982年 | 46篇 |
1981年 | 47篇 |
1980年 | 38篇 |
1978年 | 26篇 |
1977年 | 25篇 |
1976年 | 23篇 |
1974年 | 20篇 |
1973年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
以CF4和C6H6的混合气体作为气源,在微波电子回旋共振化学气相沉积(ECRCVD)装置中制备了氟化非晶碳薄膜(aC:F),并在N2气氛中作了退火处理以考察其热稳定性.通过傅里叶变换红外吸收谱和紫外可见光谱获得了薄膜中CC双键的相对含量和光学带隙,发现膜中CC键含量与光学带隙之间存在着密切的关联,在高微波功率下沉积的氟化非晶碳膜具有低的光学带隙和较好的热稳定性.
关键词:
氟化非晶碳膜
光学带隙
退火温度
热稳定性 相似文献
62.
63.
64.
S. J. Cheng W. Sheng P. Hawrylak S. Raymond S. Studenikin A. Sachrajda Z. Wasilewski A. Babinski M. Potemski G. Ortner M. Bayer 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):211
We present results of calculations and experiments on electron–hole complexes in InGaAs/GaAs self-assembled quantum dots in high magnetic field (B). Due to hidden symmetries, the chemical potential of an N-exciton system at special B fields becomes insensitive to the exciton number as well as the magnetic field. This results in plateau regions of high intensity in measured magneto-PL spectrum. Theoretical calculations using exact diagonalization techniques successfully explain the measured magneto-photoluminescence spectrum with B fields up to 28 T. 相似文献
65.
66.
根据Co P非晶态合金结构的短程有序和结构中可能存在P -P相互作用的实验事实 ,选择了单磷原子簇模型ConP(n =1~ 5 )和双磷原子簇模型ConP2 (n =1~ 4 ) ,用密度泛函理论方法对其进行计算 .结果表明 ,在单磷Co2 P( 2 ) 、Co3 P( 1) 及Co4P( 2 ) 模型体系中 ,Co原子供给P原子电子 ,与电负性规则一致 ,同时Co和P之间具较强化学作用 ,可以形成稳定的原子簇 ;而在双磷和单磷原子簇Co5P( 1) 模型体系中 ,形成的原子簇不稳定 ,采用单磷Co2 P( 2 ) 、Co3 P( 1) 及Co4P( 2 ) 模型能较好地反映Co P非晶态合金的结构特点 . 相似文献
67.
Weidong Gao Meiqiong Zhan Shuhai Fan Janda Shao Zheng-Xiu Fan 《Applied Surface Science》2005,250(1-4):195-202
The laser-induced damage (LID) behavior of narrow-band interference filters was investigated with a Nd:YAG laser at 1064 nm under single-pulse mode and free-running mode. The absorption measurement of such coatings was performed with surface thermal lensing (STL) technique. The damage morphologies under the two different laser modes were also studied in detail. It was found that all the filters exhibited a pass-band-center-dependent absorption and laser-induced damage threshold (LIDT) behavior, but the damage morphologies were diverse. The explanation was given with the analysis of the electric field distribution and the operational behavior of the irradiation laser. 相似文献
68.
Hong-Wen Gao 《Journal of Analytical Chemistry》2003,58(4):328-332
The reactions between Cu(II) and picramine CA (PCA) and Al(III) and PCA were both sensitive at pH 7. The competition coordination between Cu and the Al–PCA complex was applied to the selective determination of Cu (CCSD) by the spectral correction technique. Results have shown that the complexes formed at pH 7 are Al2(PCA) and Cu(PCA)3, their cumulative stability constants are 4.43 × 105 and 2.08 × 1015, respectively, and their real molar absorptivities are 5.78 × 103 at 650 nm and 3.19 × 104at 530 nm. At the analysis of the samples, the relative standard deviation (RSD) was 5.0% and the recovery rate of Cu was between 94 and 108%. 相似文献
69.
Deposition of Hydrogen-Free Silicon Nitride Thin Films by Microwave ECR plasma Enhanced Magnetron Sputtering at Room Temperature
下载免费PDF全文
![点击此处可从《中国物理快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Hydrogen-free silicon nitride (SiNx) films were deposited at room temperature by microwave electron cyclotron resonance (MW-ECR) plasma enhanced unbalance magnetron sputtering system. Both Fourier-transform infrared spectroscopy and x-ray photoelectron spectroscopy are used to study the bonding type and the change of bonding structures of the silicon nitride films. The results indicate that the chemical structure and composition of SiNx films deposited by this technique depend strongly on the N2 flow rates, the stoichiometric SiNx film, which has the highest hardness of 22.9 GPa, could be obtained at lower N2 flow rate of 4 sccm. 相似文献
70.
Ching‐Yuan Cheng Kuan‐Jiuh Lin 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(8):m363-m365
In the title compound, catena‐poly[lithium‐μ3‐ethylenediphosphonato], [Li(C2H7O6P2)]n, the supramolecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethylenediphosphonate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand. 相似文献