全文获取类型
收费全文 | 10004篇 |
免费 | 1896篇 |
国内免费 | 1535篇 |
专业分类
化学 | 7901篇 |
晶体学 | 141篇 |
力学 | 621篇 |
综合类 | 94篇 |
数学 | 1329篇 |
物理学 | 3349篇 |
出版年
2024年 | 18篇 |
2023年 | 153篇 |
2022年 | 259篇 |
2021年 | 324篇 |
2020年 | 370篇 |
2019年 | 431篇 |
2018年 | 351篇 |
2017年 | 310篇 |
2016年 | 518篇 |
2015年 | 591篇 |
2014年 | 604篇 |
2013年 | 755篇 |
2012年 | 892篇 |
2011年 | 894篇 |
2010年 | 717篇 |
2009年 | 680篇 |
2008年 | 714篇 |
2007年 | 581篇 |
2006年 | 519篇 |
2005年 | 486篇 |
2004年 | 440篇 |
2003年 | 401篇 |
2002年 | 510篇 |
2001年 | 422篇 |
2000年 | 265篇 |
1999年 | 221篇 |
1998年 | 188篇 |
1997年 | 132篇 |
1996年 | 119篇 |
1995年 | 108篇 |
1994年 | 84篇 |
1993年 | 67篇 |
1992年 | 55篇 |
1991年 | 57篇 |
1990年 | 36篇 |
1989年 | 27篇 |
1988年 | 21篇 |
1987年 | 16篇 |
1986年 | 10篇 |
1985年 | 8篇 |
1984年 | 14篇 |
1983年 | 11篇 |
1982年 | 4篇 |
1981年 | 12篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1976年 | 3篇 |
1974年 | 5篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
Wen-Jin Yin Xiao-Long Zeng Bo Wen Qing-Xia Ge Ying Xu Gilberto Teobaldi Li-Min Liu 《Frontiers of Physics》2021,16(3):33501
Heterostructure is an effective approach in modulating the physical and chemical behavior of materials. Here, the first-principles calculations were carried out to explore the structural, electronic, and carrier mobility properties of Janus MoSSe/GaN heterostructures. This heterostructure exhibits a superior high carrier mobility of 281.28 cm2·V−1·s−1 for electron carrier and 3951.2 cm2·V−1·s−1 for hole carrier. Particularly, the magnitude of the carrier mobility can be further tuned by Janus structure and stacking modes of the heterostructure. It is revealed that the equivalent mass and elastic moduli strongly affect the carrier mobility of the heterostructure, while the deformation potential contributes to the different carrier mobility for electron and hole of the heterostructure. These results suggest that the Janus MoSSe/GaN heterostructures have many potential applications for the unique carrier mobility. 相似文献
992.
Wenyu Wang Chang Wen Tianyu Liu Changkang Li Haowen Liu Enze Liu Minghou Xu 《Proceedings of the Combustion Institute》2021,38(3):4091-4099
The single or co-combustion experiments of high-Ca pyrolyzed biochar and high-Si coal were carried out on a drop tube furnace (DTF) at 1300 °C under air and oxyfuel (CO2:O2=50:50, oxy50) conditions. The produced PM10 (of an aerodynamic diameter of 10 µm or less) was analyzed to investigate the interactions during co-combustion. Due to the characteristics of the selected samples (low S and Cl), the PM1 emissions including PM0.1 and PM0.1–1 are very low during single combustion, except for the PM0.1–1 emission during the combustion of biochar under oxy50 condition because of the massive partitioning of Mg, Ca and Fe. The interaction during co-combustion was observed to mainly occur in the generation of PM1–10, and also slightly occur in the formation of PM0.1–1 under oxy50 condition. The capture of Mg, Ca, and Fe from biochar by the Si-containing minerals in coal under the oxy50 condition results in a slight decrease in PM0.1–1 during co-combustion. The higher the proportion of coal blended, the more obvious the reduction of elements. As for the formation of PM1–10 during co-combustion, high-melting minerals of biochar would weaken the coalescence of minerals in coal to cause more PM10, while the large mineral grains of coal would capture the minerals in biochar to generate more PM10+. Under the competition of the above two types of interactions, the experimental value of PM1–10 yields was almost consistent with the theoretically calculated value, except for blended ratio of 80:20 (coal: biochar, air) or 50:50 (oxy50) with prior interaction predominating. 相似文献
993.
This study investigates the cellulose–lignin interactions during fast pyrolysis at 100–350 °C for better understanding fundamental pyrolysis mechanism of lignocellulosic biomass. The results show that co-pyrolysis of cellulose and lignin (with a mass ratio of 1:1) at temperatures < 300 °C leads to a char yield lower than the calculated char yield based on the addition of individual cellulose and lignin pyrolysis. The difference between the experimental and calculated char yields increases with temperature, from ~2% 150 °C to ~6% at 250 °C. Such differences in char yields provide direct evidences on the existence of cellulose–lignin interactions during co-pyrolysis of cellulose and lignin. At temperatures below 300 °C, the reductions in both lignin functional groups and sugar structures within the char indicate that co-pyrolysis of cellulose and lignin enhances the release of volatiles from both cellulose and lignin. Such an observation could be attributed to two possible reasons: (1) the stabilization of lignin-derived reactive species by cellulose-derived reaction intermediates as hydrogen donors, and (2) the thermal ejection of cellulose-derived species due to micro-explosion of liquid intermediates from lignin. In contrast, at temperatures ≥ 300 °C, co-pyrolysis of cellulose and lignin increases char yields, i.e., with the difference between the experimental and calculated char yields increasing from ~1% at 300 °C to ~8% at 350 °C. The results indicate that the cellulose-derived volatiles are difficult to diffuse through the lignin-derived liquid intermediates into the vapor phase, leading to increased char formation from co-pyrolysis of cellulose and lignin as temperature increases. Such an observation is further supported by the increased retention of cellulose functional groups in the char from co-pyrolysis of cellulose and lignin. 相似文献
994.
作为马约拉纳费米子的“凝聚态版本”,马约拉纳零能模是当前凝聚态物理领域的研究热点.马约拉纳零能模满足非阿贝尔统计,可以构建受拓扑保护的量子比特.这种由空间上分离的马约拉纳零能模构建的拓扑量子比特不易受局域噪声的干扰,具有长的退相干时间,在容错量子计算中具有重要的应用前景.半导体/超导体纳米线是研究马约拉纳零能模和拓扑量子计算的理想实验平台.本文综述了高质量半导体纳米线外延生长、半导体/超导体异质结制备以及相应的马约拉纳零能模研究方面的进展,并对半导体/超导体纳米线在量子计算中的应用前景进行了展望. 相似文献
995.
Tetraoctyloxy-substituted naphthalenophanedienes were synthesized from tetraoctyloxy-substituted dithia[3.3]naphthalenophanes via sequential benzyne Stevens rearrangement, oxidation, and pyrolysis reactions. Surprisingly, only the pseudo-geminal isomer of tetraoctyloxy-substituted dithia[3.3]naphthalenophane was obtained after cyclization of the corresponding starting materials. The structures of the pseudo-geminal isomers of tetraoctyloxy-substituted dithia[3.3]naphthalenophane and tetraoctyloxy-substituted naphthalenophanediene were fully determined by nuclear magnetic resonance spectroscopy, high resolution mass spectrometry, and X-ray crystallography. The pseudo-geminal and pseudo-meta diastereomers of tetraoctyloxy-substituted naphthalenophanedienes were isolated by multiple fractional recrystallization from hexane at 5 °C. The solid state structure of the pseudo-geminal isomer of tetraoctyloxy-substituted naphthalenophanediene revealed strongly distorted naphthyl rings with high levels of ring strain. 相似文献
996.
To understand the substitution effects of 3-aminomethyl-pyridine on the reaction equilibrium, the interactions between a series of 3-aminomethyl-pyridine derivatives and peroxovanadium(V) complex [OV(O2)2(D2O)]?/[OV(O2)2(HOD)]? in solution were explored by the combined use of multinuclear (1H, 13C, and 51V) magnetic resonance spectroscopy together with HSQC in 0.15 M NaCl ionic medium for mimicking the physiological conditions. Some direct NMR data are given for the first time. The relative reactivity among the 3-aminomethyl-pyridine derivative ligands are N-(pyridin-3-ylmethyl)acetamide (1) ≈ N-(pyridin-3-ylmethyl)propionamide (2) > N-(pyridin-3-ylmethyl)pivalamide (3) > t-butyl(pyridin-3-ylmethyl)carbamate (4). The competitive coordination results in the formation of a series of new six-coordinate peroxovanadium species [OV(O2)2L]? (L = 1–4). The results of density functional calculations indicated that the solvation effects play an important role in these reactions, providing a reasonable explanation on the relative reactivity of the 3-aminomethyl-pyridine derivatives. 相似文献
997.
Dr. Yongjin Fang Dr. Xin-Yao Yu Prof. Xiong Wen Lou 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(21):5895-5899
Layered metal oxides have attracted increasing attention as cathode materials for sodium-ion batteries (SIBs). However, the application of such cathode materials is still hindered by their poor rate capability and cycling stability. Here, a facile self-templated strategy is developed to synthesize uniform P2-Na0.7CoO2 microspheres. Due to the unique microsphere structure, the contact area of the active material with electrolyte is minimized. As expected, the P2-Na0.7CoO2 microspheres exhibit enhanced electrochemical performance for sodium storage in terms of high reversible capacity (125 mAh g−1 at 5 mA g−1), superior rate capability and long cycle life (86 % capacity retention over 300 cycles). Importantly, the synthesis method can be easily extended to synthesize other layered metal oxide (P2-Na0.7MnO2 and O3-NaFeO2) microspheres. 相似文献
998.
Quantum reaction dynamics of C(1D) + HD → CH(CD) + D(H) on the ground state potential energy surface
下载免费PDF全文
![点击此处可从《International journal of quantum chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
We present accurate quantum dynamic calculations of the reaction C(1D) + HD on the latest version of the potential energy surface [Zhang et al., J. Chem. Phys. 140, 234301 (2014)]. Using a Chebyshev real wave packet method with full Coriolis coupling, we obtain the initial state‐specified ( ) reaction probabilities, integral cross sections, and rate constants. The resulting probabilities display oscillatory structures due to numerous long‐lived resonances supported by the deep potential well. The calculated rate constants and CD/CH product branching ratio at room temperature are in reasonably good agreement with the experimental measurements. 相似文献
999.
通过简单的一锅两步法制备了三氟金属(铝,钛,锆)接枝介孔SBA-15 (AlTf/S,TiTf/S,ZrTf/S)固体酸材料,并通过XRD,N2吸附,TGA,FTIR,原位吡啶FTIR和元素分析对这些材料进行了详细的表征.其中,ZrTf/S能够高效催化环氧化物温和条件下被胺或醇开环生成对应β-氨基醇或β-烷氧基醇,并且催化剂能循环利用.ZrTf/S相较于AlTf/S和TiTf/S酸性最强,因而催化活性也最高. 相似文献
1000.
液晶润滑添加剂的减摩作用机理研究 总被引:3,自引:0,他引:3
液晶润滑添加剂具有优良的减摩性能,但在已有的文献报道中涉及其减摩机理的研究内容却还很少。因此,利用向列型液晶材料已氧基苯甲酸和正辛基苯甲酸作为HU-20汽轮机油的添加剂,在给定的压力、速度和温度条件下于Falex试验机上进行了液晶的减摩性能试验研究,并且用X射线衍射、俄歇电子能谱和扫描电子显微镜等技术,对溶解于矿物油中的液晶结构、磨损表层的元素组成及其表面形貌作了观察、分析与研究,在此基础上又对液 相似文献