Application of dynamic speckle method using in sedimentation process of silver chloride

The generation process of silver chloride was studied using dynamic speckle methods including speckle size measurement and speckle contrast measurement. The quantity and size changes of the sedimentation particles in the illuminating region were investigated and analyzed.     

Novel asymmetric synthesis of oseltamivir phosphate (Tamiflu) from (−)-shikimic acid via cyclic sulfite intermediates

A novel asymmetric synthesis of oseltamivir phosphate 1 from the naturally abundant (?)-shikimic acid via 3,4-cyclic sulfite intermediate 3 (Scheme 1) is described. Target compound 1 was obtained in 39% overall yield from this nine-step synthesis, and the characteristic step of the synthesis is the regio- and stereospecific nucleophilic substitution with sodium azide at the allylic (C-3) position of 3,4-cyclic sulfite 3. Since the yield of the direct-aziridine-formation from the unprotected dihydroxyl azide 4 was not satisfactory, two improved preparations of the established compound 7 via protected 3,4-cyclic sulfites 10 and 13 (Scheme 2) have been developed. In these two improved preparations, compound 7 was obtained from 3,4-cyclic sulfite 3 in 7-steps in 64% or 62% overall yield, respectively.     

等离子体气动激励机理数值研究

基于介质阻挡与准直流电弧放电的物理过程, 分析了它们的气动激励机理, 建立了各自的气动激励模型, 并分别研究了它们对低速和超声速流动的激励效果. 结果显示: 介质挡板放电等离子体气动激励机理是改变了连续流体中的三种力, 即由牛顿内摩擦引起的剪切应力、由电动力学引起的体积力及由压力突变引起的冲击力, 其中基于电动力学的体积力效应占主导地位; 临近空间环境中体积力的作用效果更强, 诱导速度更大; 超声速来流下准直流电弧放电气动激励机理主要是等离子体的热阻塞效应, 本文所建立的爆炸丝传热模型可以用于仿真其控制激波的过程; 热电弧对于超声速来流而言就像一个具有一定斜坡角度的虚拟突起, 可用于高超声速飞行器前体激波的控制.     

Capillary liquid chromatography fraction collection and postcolumn reaction using segmented flow microfluidics

A challenge for capillary LC (cLC) is fraction collection and the manipulation of fractions from microscale columns. An emerging approach is the use of segmented flow or droplet technology to perform such tasks. In this work, a fraction collection and postcolumn reaction system based on segmented flow was developed for the gradient cLC of proteins. In the system, column effluent and immiscible oil are pumped into separate arms of a tee resulting in regular fractions of effluent segmented by oil. Fractions were generated at 1 Hz corresponding to 5 nL volumes. The fraction collection rate was high enough to generate over 30 fractions per peak and preserve chromatographic resolution achieved for a five‐protein test mixture. The resulting fractions could be stored and subsequently derivatized for fluorescence detection by pumping them into a second tee where naphthalene dicarboxyaldehyde, a fluorogenic reagent, was pumped into a second arm and added to each fraction. Proteins were derivatized within the droplets enabling postcolumn fluorescence detection of the proteins. The experiments demonstrate that fraction collection from cLC by segmented flow can be extended to proteins. Further, they illustrate a potential workflow for protein analysis based on postcolumn derivatization for fluorescence detection.     

双Lloyd镜数字全息显微测量术

提出了一种双Lloyd镜数字全息显微测量技术.其基本思想是将Lloyd镜的共光束自干涉特性与双波长光学相位解包裹方法相结合,使用两个Lloyd镜调节参考光与物光夹角以形成共光束自干涉,从而获得一张双波长复合全息图,再通过角谱法再现得到每个波长对应的包裹相位,利用两波长的相位差求得解包裹后的相位图和三维高度分布图.采用532和632 nm两波长记录全息图,通过数值再现重构被测物体的振幅和相位信息.与标定值相比,实验值的误差小于5%,证明了该方法的有效性.     

多输入多输出量子密钥分发信道容量研究

量子安全通信是一个量子密钥分发过程,目前采用的通信技术严重制约了量子密钥分发的比特率.将多输入多输出（MIMO）技术应用于量子密钥分发系统,可提高量子密钥分发的比特率,促进量子安全通信向高速大容量发展.文中首先构造出MIMO量子密钥分发信道中多光子纠缠态Wigner算符矩阵.并在此基础上,推导出多光子双模压缩纠缠态Wigner算符矩阵和MIMO量子密钥分发信道容量.为开发稳健的MIMO量子安全通信空时处理算法和优化设计高性能MIMO量子密钥分发系统提供理论支撑和技术基础. 关键词： 多输入多输出 双模压缩态 多光子纠缠态 信道容量     

Mg/B多层膜退火法中不同制备条件对MgB2超导薄膜性质的影响

用Mg/B多层膜退火的方法制备了一系列MgB₂超导薄膜,研究了退火温度、退火时间和薄膜厚度对于MgB₂薄膜性质的影响.厚度为250 nm的Mg/B多层膜经400 ℃低温退火后已经生成超导相,此厚度薄膜750 ℃下退火20—30 min实现最佳超导转变温度（T_c）.前驱膜分层厚度相同时,随着薄膜厚度减小MgB₂薄膜T_c明显降低,而且较薄的膜T_{c关键词： 2}超导薄膜')" href="#">MgB₂超导薄膜 电子束蒸发 超导成相     

有效抑制光子晶体加载矩形谐振腔中模式竞争的方法

研究了光子晶体加载矩形谐振腔,针对传统光子晶体加载无法完全抑制模式竞争的问题,提出了特性阻抗和介质加载方法进行改进,完全实现了谐振腔的高次模式的单模工作,为抑制高次模式工作的谐振腔中模式竞争的问题提供了一种新方法.在此基础之上,采用解析方法以及高频仿真软件HFSS,设计了一个采用TM₅₃₀高次模式工作的传统光子晶体加载的谐振腔,进一步采用了该新方法对其进行改进,并深入分析了采用这种方法抑制模式竞争的物理原因.计算结果表明,新方法能有效抑制模式竞争,实现谐振腔的高次工作模式的单模工作. 关键词： 光子晶体 谐振腔 模式竞争 特性阻抗