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101.
102.
Jun Hua YU Xue Song WANG Bao Wen ZHANG* Yi CAO Technical Institute of Physics Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2002,13(10)
Porphyrin derivatives attract much more interest in photodynamic therapy (PDT). Their importance as therapeutic drugs and targeting agents has been widely recognized1, and many of the efforts have been put towards crafting new porphyrin-based molecular entities to achieve enhanced tumor localization, better tissue penetration and increased singlet oxygen quantum yield2. The states of porphyrins in tissue models such as micelles, lipid bilayers are extensively investigated focusing more or l… 相似文献
103.
104.
对称正交反对称矩阵反问题解存在的条件 总被引:25,自引:1,他引:24
戴华 《高等学校计算数学学报》2002,24(2):169-178
矩阵反问题和矩阵特征值反问题在科学和工程技术中具有广泛的应用,有关它们的研究已取得了许多进展[1,2].[3]和[4]分别研究了反对称矩阵反问题和双反对称矩阵特征值反问题等.本文研究一类更广泛的对称正交反对称矩阵反问题.用Rn×m(Cn×m)表示n×m实(复)矩阵的全体,ASRn×n表示n阶反对称矩阵的全体,ABSRn×n表示n阶双反对称矩阵的全体,ORn×n表示n阶正交矩阵的全体.A+表示矩阵A的Moore-Penrose广义逆.In表示n阶单位矩阵.ei表示n阶单位矩阵的第i列,Sn=[en,en-1, 相似文献
105.
对形如Nt×Nl型准二维无序系统,只考虑格点之间的最近邻跳跃积分,采用特殊的格点编号方案,在单电子近似下,系统的哈密顿量可表示为简明对称矩阵,借助豪斯荷尔德变换将其约化为对称三对角矩阵,再利用负本征值理论及传输矩阵等方法,对系统态密度、局域长度及电导等电子结构特性进行数值计算. 重点研究了准一维四平行链和五平行链无序系统, 将结果与一维单链、准一维双链及三链系统进行对比,发现随维度的增加,系统的能带有所展宽,能态密度分布发生很大的变化,其峰值数量呈偶数规律增加. 并且在能带中心处存在有局域长度大于系统大小的扩展态,处于这些态下的系统具有较大电导. 从单链到多链,相当于扩大了系统的关联范围,使系统出现了类似非对角长程关联的行为.
关键词:
准二维无序系统
态密度
局域长度
电导 相似文献
106.
以8-羟基喹啉为配体的金属配合物是一种性能优良的有机电致发光材料,其中有关8-羟基喹啉铝(Alq3)研究已有大量报道,8-羟基喹啉锌(Znq2)研究还有待发展。介绍了两种以Znq2为基体的新型有机电致发光材料Znq2(H2O)2和(Znq2)4的合成方法。用IR、XRD、TG、DTA和荧光测试方法进行表征与分析表明:Znq2(H2O)2和(Znq2)4的玻璃化温度(Tg)分别为104.2℃和204.9℃;在161℃下Znq2(H2O)2脱去水分子成为Znq2,在361℃高温下四聚体(Znq2)4裂解为单体Znq2;Znq2(H2O)2和(Znq2)4具有很好的发光性能,在光致发光谱中λmax分别是505,550nm。 相似文献
107.
108.
Wang Jingxiu Zhang Jun Deng Yuanyong Li Jingqun Tian Lirong Yang Xiulan 《中国科学A辑(英文版)》2002,45(1):57-64
Based on the studies on the source regions of a group of coronal mass ejections, we have identified two types of large-scale magnetic structures, and suggested that they are intrinsic components of solar magnetism, their destabilization, expansion, and eruption into the interplanetary space are the basic physical processes which lead to the coronal mass ejections. These two types of large-scale structures are giant magnetic loops connecting the two active belts on the opposite hemispheres of the Sun, and the giant filaments (filament channels) and their related magnetic structures. The latter often appear as two parallel rows of sunspots and plage fields, which align side by side in the full disk daily and synoptic magnetograms. The magnetic neutral lines of these large-scale structures are usually longer than 50 heliographic degrees. We name this type of structure “super A configuration”. Sometimes, they are shown as very long filaments and related large-scale magnetic fields. As these magnetic structures are of very large scale, they extend to a great altitude into the corona, they are not easily recognized in magnetic field observations which are usually aimed at solar flare studies. To identify these large-scale structures becomes a key to understanding and predicting coronal mass ejections. 相似文献
109.
Guantie Deng 《Bulletin des Sciences Mathématiques》2007,131(1):53
In this paper, using a modified Poisson kernel in an upper half-space, we prove that a harmonic function u(z) in a upper half space with its positive part u+(x)=max{u(x),0} satisfying a slowly growing condition can be represented by its integral in the boundary of the upper half space, the integral representation is unique up to the addition of a harmonic polynomial, vanishing in the boundary of the upper half space and that its negative part u−(x)=max{−u(x),0} can be dominated by a similar slowly growing condition, this improves some classical result about harmonic functions in the upper half space. 相似文献
110.
Films of polytetrafluoroethylene (PTFE) were exposed to sodium naphthalenide (Na/naphtha) etchant so as to defluorinate the surface for obtaining hydroxyl functionality. Surface-initiators were immobilized on the PTFE films by esterification of 4,4′-azobis(4-cyanopentanoic acid) (ACP) and the hydroxyl groups covalently linked to the surface. Grafting of polymer brushes on the PTFE films was carried out by the surface-initiated free radical polymerization. Homopolymers brushes of methyl methacrylate (MMA) were prepared by free radical polymerization from the azo-functionalized PTFE surface. The chemical composition and topography of the graft-functionalized PTFE surfaces were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance (ATR) FT-IR spectroscopy and atomic force microscopy (AFM). Water contact angles on PTFE films were reduced by surface grafting of MMA. 相似文献