全文获取类型
收费全文 | 63735篇 |
免费 | 14328篇 |
国内免费 | 6465篇 |
专业分类
化学 | 62270篇 |
晶体学 | 766篇 |
力学 | 2040篇 |
综合类 | 405篇 |
数学 | 5383篇 |
物理学 | 13664篇 |
出版年
2024年 | 94篇 |
2023年 | 525篇 |
2022年 | 1090篇 |
2021年 | 1211篇 |
2020年 | 2238篇 |
2019年 | 3610篇 |
2018年 | 1965篇 |
2017年 | 1700篇 |
2016年 | 4625篇 |
2015年 | 4902篇 |
2014年 | 5090篇 |
2013年 | 6291篇 |
2012年 | 5601篇 |
2011年 | 4976篇 |
2010年 | 4805篇 |
2009年 | 4736篇 |
2008年 | 4448篇 |
2007年 | 3678篇 |
2006年 | 3180篇 |
2005年 | 3059篇 |
2004年 | 2638篇 |
2003年 | 2260篇 |
2002年 | 2966篇 |
2001年 | 2219篇 |
2000年 | 2005篇 |
1999年 | 957篇 |
1998年 | 583篇 |
1997年 | 464篇 |
1996年 | 377篇 |
1995年 | 389篇 |
1994年 | 351篇 |
1993年 | 255篇 |
1992年 | 210篇 |
1991年 | 191篇 |
1990年 | 199篇 |
1989年 | 117篇 |
1988年 | 114篇 |
1987年 | 66篇 |
1986年 | 80篇 |
1985年 | 58篇 |
1984年 | 44篇 |
1983年 | 44篇 |
1982年 | 23篇 |
1981年 | 15篇 |
1980年 | 17篇 |
1979年 | 8篇 |
1978年 | 6篇 |
1975年 | 6篇 |
1957年 | 5篇 |
1936年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 11 毫秒
31.
Yin Pengpeng Liu Chang Wang Ying Guan Lei Chen Xian Xiong Xuejia Jin Hongzhe 《Russian Journal of General Chemistry》2021,91(5):897-903
Russian Journal of General Chemistry - A dinuclear Tb complex, Tb2(H2L)3(phen)2 (1), and two similar N-donor coordination complexes, Fe(phen)3·HL (2), Fe(bipy)3·HL·5H2O (3) (Na2H2L =... 相似文献
32.
Yongjie Zhou Yuqi Mei Tian Luo Wenxue Chen Qiuping Zhong Haiming Chen Weijun Chen 《Molecules (Basel, Switzerland)》2021,26(9)
The contribution of rheological properties and viscoelasticity of the interfacial adsorbed layer to the emulsification mechanism of enzymatic modified sugar beet pectin (SBP) was studied. The component content of each enzymatic modified pectin was lower than that of untreated SBP. Protein and ferulic acid decreased from 5.52% and 1.08% to 0.54% and 0.13%, respectively, resulting in a decrease in thermal stability, apparent viscosity, and molecular weight (Mw). The dynamic interfacial rheological properties showed that the interfacial pressure and modulus (E) decreased significantly with the decrease of functional groups (especially proteins), which also led to the bimodal distribution of particle size. These results indicated that the superior emulsification property of SBP is mainly determined by proteins, followed by ferulic acid, and the existence of other functional groups also promotes the emulsification property of SBP. 相似文献
33.
34.
Sun Yuan Luo Shunlong Lei Xiangyun 《International Journal of Theoretical Physics》2021,60(9):3211-3224
International Journal of Theoretical Physics - Gram matrices arise naturally in the consideration of pair-wise overlap of a family of vectors or quantum pure states, and play an important role in... 相似文献
35.
36.
37.
Sergio Ayala‐Mar Javier Donoso‐Quezada Roberto C. Gallo‐Villanueva Victor H. Perez‐Gonzalez Jos Gonzlez‐Valdez 《Electrophoresis》2019,40(23-24):3036-3049
Exosomes are nanovesicles secreted by most cellular types that carry important biochemical compounds throughout the body with different purposes, playing a preponderant role in cellular communication. Because of their structure, physicochemical properties and stability, recent studies are focusing in their use as nanocarriers for different therapeutic compounds for the treatment of different diseases ranging from cancer to Parkinson's disease. However, current bioseparation protocols and methodologies are selected based on the final exosome application or intended use and present both advantages and disadvantages when compared among them. In this context, this review aims to present the most important technologies available for exosome isolation while discussing their advantages and disadvantages and the possibilities of being combined with other strategies. This is critical since the development of novel exosome‐based therapeutic strategies will be constrained to the effectiveness and yield of the selected downstream purification methodologies for which a thorough understanding of the available technological resources is needed. 相似文献
38.
Luo Dajuan Liu Bingqian Gao Rong Su Lixia Su Yonghuan 《Journal of Solid State Electrochemistry》2022,26(3):749-759
Journal of Solid State Electrochemistry - Cortisol, a steroid hormone, has been confirmed as a kind of biomarker that reflects the stress response of psychobiology and related adverse health... 相似文献
39.
Over the past two decades, advanced materials with hollow interiors have received significant attention in materials research owing to their great application potential across a vast number of technological fields. Though with great difficulty, multi-shelled hollow metal–organic frameworks (MSHMs) have also been successfully synthesized in recent years. Herein, a rational shell-by-shell soft-templating protocol has been devised to fabricate highly uniform multi-shelled hollow cobalt-imidazole-based MOF (ZIF-67). For the first time, it has become possible to endow mesoporosity to this new type of functional material (i.e., mesoporous MOFs). When used as carrier materials in catalytic reactions, in principle, these mesoporous MSHMs with high surface area not only improve the dispersity of metal nanoparticles (NPs), but also efficiently facilitate the mass diffusion of the reactions, resulting in enhanced catalyst activity. Moreover, the obtained MSHMs/M nanocomposites serve as base-metal bifunctional catalysts for one-pot oxidation-Knoevenagel condensation cascade reaction, in which the MSHMs itself serves as a pristine active catalyst in addition to its role of catalyst support. The results demonstrate that excellent multifunctional catalysts can be achieved via preparing intrinsically microporous bulk MOFs into extrinsically mesoporous MSHMs which possess many structural merits that conventional bulk MOFs do not have. 相似文献
40.
Triazines are widely used in agriculture around the world as selective pre‐ and post‐emergence herbicides for the control of broad leaf and grassy weeds. With high toxicity and persistence, triazines can contaminate the environment and crops, so the development of rapid and sensitive methods for the determination of different triazines is necessary. Capillary electrophoresis comprises a group of techniques used to separate chemical mixtures. Analytical separation is based on different electrophoretic mobilities. This review focuses on the analysis of triazine herbicides with different modes of capillary electrophoresis, including capillary zone electrophoresis, micellar electrokinetic capillary electrophoresis, capillary electrochromatography and nonaqueous capillary electrophoresis. Determinations of triazines in various matrices such as surface water, groundwater, vegetables, soil and grains are emphasized. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献