全文获取类型
收费全文 | 647篇 |
免费 | 32篇 |
国内免费 | 3篇 |
专业分类
化学 | 427篇 |
晶体学 | 2篇 |
力学 | 18篇 |
数学 | 120篇 |
物理学 | 115篇 |
出版年
2023年 | 1篇 |
2022年 | 5篇 |
2021年 | 12篇 |
2020年 | 10篇 |
2019年 | 14篇 |
2018年 | 5篇 |
2017年 | 12篇 |
2016年 | 20篇 |
2015年 | 24篇 |
2014年 | 32篇 |
2013年 | 35篇 |
2012年 | 51篇 |
2011年 | 53篇 |
2010年 | 33篇 |
2009年 | 36篇 |
2008年 | 32篇 |
2007年 | 19篇 |
2006年 | 30篇 |
2005年 | 25篇 |
2004年 | 27篇 |
2003年 | 19篇 |
2002年 | 24篇 |
2001年 | 14篇 |
2000年 | 11篇 |
1999年 | 16篇 |
1998年 | 12篇 |
1997年 | 14篇 |
1996年 | 6篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 10篇 |
1992年 | 7篇 |
1991年 | 2篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1972年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有682条查询结果,搜索用时 15 毫秒
91.
92.
93.
94.
95.
The stability of olive oil-in-water (o/w) emulsion stabilized with sucrose fatty acid ester (SFAE) was evaluated through an accelerated ageing test. The stability of the emulsion in this study was examined by the appearance of any phase separation in the emulsion, mean droplet size and rheological properties over one month. The effect of accelerated ageing at 45 ℃ on the emulsion rheological properties was investigated using an amplitude sweep test, a frequency sweep test and a viscometry test. The rheological properties of the emulsion were examined at the one day, one week and one month of storage time. Among the series of emulsions prepared, the emulsion with 2∶8 of water to oil ratio (by weight) is the most stable one, which did not show any of phase separation. The amplitude sweep result shows that there was no significant change of the critical strain of the emulsion throughout one month of storage time. The dynamic properties as well as the steady flow behavior of the emulsion also show no significant changes for over one month of storage time. The mean droplet size of the emulsion remained stable around 2.5 μm within the period of investigation. 相似文献
96.
97.
Chengchun Hao Ling Hsiao Baoxiang Wang 《Journal of Mathematical Analysis and Applications》2007,328(1):58-83
We study the well-posedness of Cauchy problem for the fourth order nonlinear Schrödinger equations
98.
MA Freitas CL Hendrickson AG Marshall 《Rapid communications in mass spectrometry : RCM》1999,13(15):1639-1642
We present a novel approach for the determination of activation energy for the unimolecular dissociation of a large (>50 atoms) ion, based on measurement of the unimolecular dissociation rate constant as a function of continuous-wave CO(2) laser intensity. Following a short ( approximately 1 s) induction period, CO(2) laser irradiation produces an essentially blackbody internal energy distribution, whose 'temperature' varies inversely with laser intensity. The only currently available method for measuring such activation energies is blackbody infrared radiative dissociation (BIRD). Compared with BIRD, FRAGMENT: (a) eliminates the need to heat the surrounding ion trap and vacuum chamber to each of several temperatures (each requiring hours for temperature equilibration); (b) offers a three-fold wider range of effective blackbody temperature; and (c) extends the range of applications to include initially cold ions (e.g., gas-phase H/D exchange). Our FRAGMENT-determined activation energy for dissociation of protonated bradykinin, 1.2 +/- 0.1 eV, agrees within experimental error to the value, 1.3 +/- 0.1 eV, previously reported by Williams et al. from BIRD experiments. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
99.
100.
Sheng-Huei Hsiao Chou-Huan Yu 《Journal of polymer science. Part A, Polymer chemistry》1998,36(11):1847-1854
Two flexible dicarboxylic acid monomers, 4,4′-[isopropylidenebis(1,4-phenylene)dioxy]dibenzoic acid ( 1 ) and 4,4′-[hexafluoroisopropylidenebis(1,4-phenylene)-dioxy]dibenzoic acid ( 3 ), were synthesized from readily available compounds in two steps in high yields. High molecular-weight polyhydrazides and poly(amide-hydra-zide)s were directly prepared from dicarboxylic acids 1 and 3 with terephthalic dihydrazide ( 5 ), isophthalic dihydrazide ( 6 ), and p-aminobenzhydrazide ( 7 ) by the phosphorylation reaction by means of diphenyl phosphite (DPP) and pyridine in N-methyl-2-pyrrolidone (NMP)/LiCl, or prepared from the diacyl chlorides of 1 and 3 with the hydrazide monomers 5–7 by the low-temperature solution polycondensation in NMP/LiCl. Less favorable results were obtained when using triphenyl phosphite (TPP) instead of DPP in the direct polycondensation reactions. Except for those derived from terephthalic dihydrazide, the resulting polyhydrazides and poly(amide-hydrazide)s could be cast into colorless, flexible, and tough films with good tensile strengths. All the hydrazide polymers and copolymers are amorphous in nature and are readily soluble in various polar solvents such as NMP and dimethyl sulfoxide (DMSO). Their Tgs were recorded in the range of 162–198°C and could be thermally cyclodehydrated into the corresponding polyoxadiazoles and poly(amide-oxadiazole)s approximately in the region of 300–380°C, as evidenced by the DSC thermograms. The oxadiazole polymers and copolymers showed a dramatically decreased solubility and higher Tg when compared to their respective hydrazide prepolymers. They exhibited Tgs of 190–216°C and were stable up to 450°C in air or nitrogen. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1847–1854, 1998 相似文献