全文获取类型
收费全文 | 3210篇 |
免费 | 134篇 |
国内免费 | 32篇 |
专业分类
化学 | 2271篇 |
晶体学 | 36篇 |
力学 | 119篇 |
综合类 | 1篇 |
数学 | 392篇 |
物理学 | 557篇 |
出版年
2024年 | 7篇 |
2023年 | 19篇 |
2022年 | 99篇 |
2021年 | 126篇 |
2020年 | 87篇 |
2019年 | 101篇 |
2018年 | 94篇 |
2017年 | 81篇 |
2016年 | 146篇 |
2015年 | 97篇 |
2014年 | 121篇 |
2013年 | 319篇 |
2012年 | 209篇 |
2011年 | 213篇 |
2010年 | 133篇 |
2009年 | 123篇 |
2008年 | 125篇 |
2007年 | 121篇 |
2006年 | 102篇 |
2005年 | 87篇 |
2004年 | 98篇 |
2003年 | 76篇 |
2002年 | 90篇 |
2001年 | 49篇 |
2000年 | 59篇 |
1999年 | 21篇 |
1998年 | 37篇 |
1997年 | 21篇 |
1996年 | 36篇 |
1995年 | 26篇 |
1994年 | 40篇 |
1993年 | 21篇 |
1992年 | 25篇 |
1991年 | 27篇 |
1990年 | 18篇 |
1989年 | 26篇 |
1988年 | 17篇 |
1987年 | 18篇 |
1986年 | 11篇 |
1985年 | 28篇 |
1984年 | 25篇 |
1983年 | 25篇 |
1982年 | 24篇 |
1981年 | 23篇 |
1980年 | 16篇 |
1979年 | 14篇 |
1978年 | 7篇 |
1977年 | 13篇 |
1976年 | 7篇 |
1975年 | 13篇 |
排序方式: 共有3376条查询结果,搜索用时 156 毫秒
1.
Saqib Kamal Arif I. Inamdar Kuan-Ru Chiou Batjargal Sainbileg Muhammad Usman Jenq-Wei Chen Tzuoo-Tsair Luo Michitoshi Hayashi Chen-Hsiung Hung Wen-Feng Liaw Kuang-Lieh Lu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(30):e202103905
The dielectric properties of coordination polymers has been a topic of recent interest, but the role of different functional groups on the dielectric properties of these polymers has not yet been fully addressed. Herein, the effects of electron-donating (R=NH2) and electron-withdrawing (R=NO2) groups on the dielectric behavior of such materials were investigated for two thermally stable and guest-free Zn-based coordination polymers, [Zn(L1)(L2)]n ( 1 ) and [Zn(L1)(L3)]n ( 2 ) [L1=2-(2-pyridyl) benzimidazole (Pbim), L2=5-aminoisophthalate (Aip), and L3=5-nitroisophthalate (Nip)]. The results of dielectric studies of 1 revealed that it possesses a high dielectric constant (κ=65.5 at 1 kHz), while compound 2 displayed an even higher dielectric constant (κ=110.3 at 1 kHz). The electron donating and withdrawing effects of the NH2 and NO2 substituents induce changes in the polarity of the polymers, which is due to the inductive effect from the aryl ring for both NO2 and NH2. Theoretical results from density functional theory (DFT) calculations, which also support the experimental findings, show that both compounds have a distinct electronic behavior with diverse wide bandgaps. The significance of the current work is to provide information about the structure-dielectric property relationships. So, this study promises to pave the way for further research on the effects of different functional groups on coordination polymers on their dielectric properties. 相似文献
2.
Development and Validation of LC-ESI-MS/MS Method for the Determination of Alfuzosin in Human Plasma
Moustapha E. Moustapha El Gamal Rania M. Kamal Mehnaz 《Journal of Analytical Chemistry》2021,76(11):1327-1335
Journal of Analytical Chemistry - A new liquid chromatography-electrospray ionization tandem mass spectrometry (LC-ESI-MS/MS) method has been developed and validated for alfuzosin quantification in... 相似文献
3.
Various antimonate compounds are well known as important inorganic ion exchangers, since they resist radiation and chemical degradation and also exhibit selectivities towards different cations. Ceric, silicon, titanium and ferric antimonates were prepared as inorganic ion exchangers. Characterization of these materials has been described using different techniques, including thermal analysis, surface area measurements, X-ray diffraction and IR-spectroscopy. In batch distribution experiments the influence of HNO3 molarity and Mo concentration for Mo sorption on different matrices is described in terms of their retention capacities and distribution coefficients.The selectivities of these exchangers towards molybdenum are in the order: CeSb > SiSb > FeSb > TiSb. 相似文献
4.
Mohammed Ali Faya Ibrahim 《Czechoslovak Mathematical Journal》2004,54(2):303-313
It was shown in [7] that any right reversible, cancellative ordered semigroup can be embedded into an ordered group and as a consequence, it was shown that a commutative ordered semigroup can be embedded into an ordered group if and only if it is cancellative. In this paper we introduce the concept of L-maher and R-maher semigroups and use a technique similar to that used in [7] to show that any left reversible cancellative ordered L or R-maher semigroup can be embedded into an ordered group. 相似文献
5.
O. Perru F. Ibrahim O. Bajeat C. Bourgeois F. Clapier E. Cottereau C. Donzaud M. Ducourtieux S. Galès D. Guillemaud-Mueller C. Lau H. Lefort F. Le Blanc A. C. Mueller J. Obert N. Pauwels J. C. Potier F. Pougheon J. Proust B. Roussière J. Sauvage O. Sorlin D. Verney 《Physics of Atomic Nuclei》2003,66(8):1421-1427
The PARRNe facility has been used to produce neutron-rich isotopes 83,84Gaby the ISOL method. Their decay has been studied, and β-γ coincidence and γ-γ coincidence data were collected as a function of time. The first two excited levels in 83Ge and the first excited level in 84Ge have been measured for the first time. 相似文献
6.
Ibrahim Erol 《Journal of polymer science. Part A, Polymer chemistry》2004,42(13):3157-3169
A new type of methacrylate monomer, [2‐oxo‐2‐(4‐acetyl) phenyl amino] ethylene methacrylate (APEMA), was synthesized. The oxime, 2,4‐dinitrophenylhydrazone, and thiosemicarbazone derivatives of poly{[2‐oxo‐2‐(4‐acetyl) phenyl amino] ethylene methacrylate} [poly(APEMA)] were prepared with hydroxylamine hydrochloride, 2,4‐dinitrophenylhydrazine, and thiosemicarbazone hydrochloride, respectively. The radical homopolymerization of APEMA was performed at 65 °C in a 1,4‐dioxane solution with benzoyl peroxide as an initiator. The monomer and its homopolymer were characterized with Fourier transform infrared and NMR techniques. The thermal stabilities of poly(APEMA) and its derivatives were investigated with thermogravimetric analysis and differential scanning calorimetry. The ultraviolet stability of the polymers were compared. The solubility and inherent viscosity of the polymers were also determined. The number‐average and weight‐average molecular weights and polydispersity index of the polymers were determined with gel permeation chromatography. The antibacterial and antifungal effects of the monomer and the polymer and its derivatives were also investigated on various bacteria and fungi. The activation energies of the thermal degradation of the polymers were calculated with the Ozawa method. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3157–3169, 2004 相似文献
7.
Numerical schemes for systems with multiple spatio-temporal scales are investigated. The multiscale schemes use asymptotic results for this type of systems which guarantee the existence of an effective dynamics for some suitably defined modes varying slowly on the largest scales. The multiscale schemes are analyzed in general, then illustrated on a specific example of a moderately large deterministic system displaying chaotic behavior due to Lorenz. Issues like consistency, accuracy, and efficiency are discussed in detail. The role of possible hidden slow variables as well as additional effects arising on the diffusive time-scale are also investigated. As a byproduct we obtain a rather complete characterization of the effective dynamics in Lorenz model. 相似文献
8.
A. A. M. Kamal 《Acta Mathematica Hungarica》1992,59(3-4):355-363
9.
Mostafa Kamal Hassan 《Transition Metal Chemistry》1991,16(6):618-621
Summary Mixed ligand complexes of general formula [UO2L1L2-(H2O)n], where L1 iso-hydroxy-,o-mercapto- oro-aminobenzoic acid and L2 is glycine, L-alanine, or L-valine, have been prepared and characterized. The uranium atom in these complexes is 6- or 8-coordinate. Both acid ligands are bidentate, bonding through the ionized –COO–– group and either O, N or S atoms. 相似文献
10.
We give several equivalent characterisations of left (and hence, by duality, also of right) supported algebras. These characterisations are in terms of properties of the left and the right parts of the module category, or in terms of the classes L0 and R0 which consist respectively of the predecessors of the projective modules, and of the successors of the injective modules. 相似文献