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991.
A simple High performance liquid chromatographic (HPLC) method for the specific determination of the molecular weight and concentration of hyaluronic acid (HA) in complex mixtures has been developed. Hyaluronate-binding proteins isolated from bovine cartilage labelled by 125I or fluoresceinisothiocyanate were used as specific markers. The specific binding affinities of the markers were compared and were found to have association constants of 1.6 x 10(7) M-1 and 1.2 x 10(7) M-1 respectively. The HA levels and molecular weight distributions can be easily determined in the range 10-500 ng/mL in complex mixtures by the use of markers, molecular sieving HPLC columns and appropriate detectors. It has been demonstrated clearly that the method is useful for the highly specific determination of the parameters in complex biological samples such as serum and synovial fluids and is recommended for clinical applications. 相似文献
992.
Y. -S. Xiong L. Yi K. -L. Yao Z. -G. Li 《Zeitschrift für Physik B Condensed Matter》1994,96(2):261-265
By means of the generalized static replica symmetric spin glass theory, a quantum HeisenbergS=1/2 spin glass model with the infinite-ranged random Dzyaloshinskii-Moriya (DM) interaction and ferromagnetic coupling is investigated. The dependence of entropy, specific heat, susceptibility and the corresponding order parameters on temperature is studied numerically for different ferromagnetic interactions and fixed anisotropy. Two spin glass phases has been found including transverse and mixed spin glass phases. It has been shown that the local susceptibility exhibits double-cusp features for different ferromagnetic coupling (J
0). Phase transition poins are found in the specific heat-temperature plane at various ferromagnetic coupling values. Additionally, the dependence of the spontaneous moment on temperature is calculated. 相似文献
993.
K. Ishikawa H. Nakano H. Masuda C. Kusano Y. Takahashi T. Hamagishi N. Endo 《Fiber and Integrated Optics》1992,11(4):385-394
A 10-Gbit/s optical receiver is developed using low-capacitance HBT IC technology. The HBT allows a cutoff frequency of 45 GHz and a maximum oscillation frequency of 70 GHz. The receiver contains an automatic gain-control amplifier IC with a gain of 16 dB, a bandwidth of 10.7 GHz, and a decision-circuit IC with an ambiguity of 66 mVp-p at a data rate of 10 Gbit/s. The sensitivity of this receiver is -26.5 dBm at a bit error rate of 10-9. Transmission over a 140-km fiber was achieved successfully. 相似文献
994.
A three-phase model of a hybrid chiral quark bag is proposed. In addition to the phases of asymptotically free current quarks
and of totally colorless mesons, the model contains the intermediate phase of massive constituent quarks. A self-consistent
solution with an account for the “Dirac sea” contribution is found in the (1+1)-dimensional case. The dependence of the bag
parameters on the parameters of the theory is investigated analytically and numerically.
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 117, No. 2, pp. 263–299, November, 1998. 相似文献
995.
Studies of breakdown threshold intensity for air at various pressures in the range of 24–760 torr using 0.355, 0.532 and 1.06
μm radiation are reported. We observep
−0.8 scaling ofI
th at 1.06 μm and a weak scaling ofp
−0.4 at 0.532 and 0.355 μm radiation. Strong dependence of breakdown spot size on laser power but weak dependence on air pressure
is observed. 相似文献
996.
M A Alliegro K D Dyer E J Cragoe B M Glaser M C Alliegro 《Journal of chromatography. A》1992,582(1-2):217-223
An assay for amiloride was devised for efficient use with the wide variety of analogues available. Amiloride was extracted from 1-ml plasma samples by elution from a C8 preparative column with 6% acetonitrile-45% methanol-5.4% acetic acid, adjusted to pH 4.0 with trimethylamine. Samples were lyophilized, resuspended in 50% methanol, filtered through 0.22-microns Spin-X cartridges, applied to a reversed-phase C18 column, and eluted in a 0-50% acetonitrile gradient in 0.4% acetic acid, pH 4.5 (1.2 ml/min). Detection by ultraviolet absorbance at 360 nm was linear from 1 to 1000 ng. Versatility of the method was demonstrated with the analogues benzamil, 6-hydro-, 6-iodo-, 5-hexamethylene-, and 5-chlorobenzyl-2',4'-dimethylbenzyl-amiloride. 相似文献
997.
The new olefinic substituted aminodisilanes, which are obtained from the reaction of organometallic reagents with aminochlorodisilanes, are converted into the chlorodisilanes by equilibration reactions or treatment with HCI. The resulting olefinic functionalized disilanes are identified by means of 29Si, 13C, 1H NMR and GC MS measurements. 相似文献
998.
The Sommerfeld diffraction theory is extended to the case of extremely short pulses. It is shown that a simple qualitative
analysis and a quantitative solution of a wide class of diffraction problems are possible for pulses with durations of the
order of the period of the light oscillations and an arbitrary initial distribution of the light field.
Pis’ma Zh. éksp. Teor. Fiz. 66, No. 5, 323–326 (10 September 1997)
Deceased 相似文献
999.
L. A. Chetkina V. E. Zavodnik A. N. Sobolev V. K. Bel'skii B. P. Bespalov A. G. Abolin 《Journal of Structural Chemistry》1991,32(3):442-445
L. Ya. Karpov Physical Chemical Research Institute. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 3, pp. 141–144, May–June, 1991. 相似文献
1000.
The use of a direct liquid introduction type liquid chromatographic-mass spectrometric interface to study highly thermally labile rifamycin antibiotics is described. Using negative ionization, abundant molecular ions were observed, and the spectra, also contained structurally significant fragments. Variation of the high-performance liquid chromatographic parameters did not change the spectra, thus making it easy to change chromatographic conditions. In quantitative studies, a surprising correlation was found, indicating that the mass spectrometric signal was proportional to the square of the sample concentration. 相似文献