Empirical correlation study of dryout heat transfer at high pressure using high order neural network and feed forward neural network

A hybrid high order neural network (HHONN) and a feed forward neural network (FNN) are developed and applied to find an optimized empirical correlation for prediction of dryout (DO) heat transfer. The values predicted by the HHONN and FNN models are compared with each other and also with the previous values of empirical correlation. HONN successfully provides an efficient open-box model of nonlinear input–output mapping which provides easier understanding of data mining. By removing the hidden layers, HONN structures become simpler than FNNs and initialization of learning parameters (weights) will not be catastrophic. The RMS results show that the HHONN model has superior fitting specification for prediction of DO heat transfer problem compared to the other prediction methods.     

Reaction of benzoyl chlorides with Huisgen's zwitterion: synthesis of functionalized 2,5-dihydro-1H-pyrroles and tetrasubstituted furans

The 1:1 intermediate generated by the addition of alkyl(aryl) isocyanides to dimethyl acetylenedicarboxylate is trapped by benzoyl chloride to yield functionalized 2,5-dihydro-1H-pyrroles. The presence of electron-withdrawing groups at the para position of benzoyl chloride leads to tetrasubstituted furans. The structures of these products were confirmed by single-crystal X-ray diffraction studies.     

Green and mild laccase-catalyzed aerobic oxidative coupling of benzenediol derivatives with various sodium benzenesulfinates

The oxidative coupling reaction between hydroquinone or catechols and various sodium benzenesulfinates was investigated using the laccase from Trametes versicolor, in the presence of O₂ in a phosphate buffer solution at room temperature to afford sulfonyl benzenediols in 75–95% yield.     

甲烷氧化偶联锂/氧化镁催化剂和纳米催化剂

采用初湿浸渍和溶胶凝胶法分别制备了Li/MgO催化剂和Li/MgO纳米催化剂. 比较两种Li/MgO催化剂对于甲烷氧化偶联反应的催化性能. 采用X射线衍射、BET吸附和透射电镜进行了表征.在973-1073 K和总压力为101 kPa下对催化剂进行了测试. 实验结果表明,Li/MgO纳米催化剂比普通催化剂对于甲烷氧化偶联反应表现为更高的甲烷转换率,较高选择性和较高的的主要产品(乙烷和乙烯)的产率.     

激光辐照下复合材料树脂基热分解3维温度场模型

 采用控制体积法,从质量和能量守恒角度,推导了激光辐照下复合材料树脂基热分解时温度变化的基本方程。用多步模型描述树脂的热分解反应。提出了热分解气体的1维运动假设,这使得可以在3维情况下考虑热分解气体对流传输的影响,且在不引入力学量的前提下实现3维温度场模型的封闭。考虑到树脂基复合材料的各向异性,对部分分解材料的导热率计算公式进行了推导,并重新推导了部分分解材料对激光的吸收系数计算公式。在一定的简化下,推导的能量守恒方程与文献结果一致。     

The role of matching thickness on the wideband electromagnetic wave suppresser using single layer doped barium ferrite

The effect of Mg²⁺, Co²⁺and Ti⁴⁺ substitution on microwave absorption has been studied for BaMg_0.5Co_0.5Ti_1.0Fe₁₀O₁₉ ferrite-acrylic resin composite in frequency range from 13 to 20 GHz. X-ray diffraction (XRD), scanning electron microscopy (SEM), vector network analysis and vibrating sample magnetometry (VSM) were employed to analyze structure, electromagnetic and microwave absorption properties of prepared ferrite. The obtained results of reflectivity demonstrate that by varying matching thickness along with weight percentage of ferrite to acrylic resin, the bandwidth coupled with reflection loss values of prepared composites can be easily tuned. Based on microwave measurement on reflectivity, it is found that BaMg_0.5Co_0.5Ti_1.0Fe₁₀O₁₉ is a good candidate for wideband electromagnetic compatibility and other practical applications at high frequency.