全文获取类型
收费全文 | 58篇 |
免费 | 1篇 |
专业分类
化学 | 11篇 |
数学 | 3篇 |
物理学 | 45篇 |
出版年
2021年 | 4篇 |
2018年 | 2篇 |
2015年 | 2篇 |
2013年 | 1篇 |
2010年 | 1篇 |
2009年 | 2篇 |
2007年 | 2篇 |
2006年 | 1篇 |
2005年 | 1篇 |
2004年 | 2篇 |
2002年 | 1篇 |
2001年 | 6篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有59条查询结果,搜索用时 15 毫秒
31.
Sushanta Kumar Parida Sudhir Kumar Hota Raushan Kumar Dr. Sandip Murarka 《化学:亚洲杂志》2021,16(8):879-889
Synthetic methods enabling late-stage modification of heterocycles hold tremendous importance in the pharmaceutical and agrochemical industry and drug discovery. Accordingly, efficient, functional group tolerant and selective late-stage alkylation of valuable molecular entities is of enormous significance and well-acknowledged in medicinal chemistry. Radical alkylation of heteroarenes employing carboxylic acids as the alkyl radical precursor represents one of the most direct ways of C−H functionalizations of heterocycles. Recently, the field has undergone a revolutionary development especially with regard to the generation of alkyl radicals under much milder conditions. In this regard N-(acyloxy)phthalimides (NHPI esters) have emerged as a suitable precursor of a diverse set of alkyl radicals allowing formal C−H alkylation of not only N-heteroarenes but a diverse set of non-aromatic heterocycles under visible light photocatalysis or electrochemical conditions. This review delineates all these discoveries and provides readers a comprehensive overview of this rapidly expanding field. 相似文献
32.
Bobeldijk I Bouwhuis M Ireland DG de Jager CW Jans E de Jonge N Kasdorp WJ Konijn J Lapikás L van Leeuwe JJ van der Meer RL Nooren GJ Passchier E Schroevers M van der Steenhoven G Steijger JJ Theunissen JA van Uden MA de Vries H de Vries R de Witt Huberts PK Blok HP van den Brink HB Dodge GE Harakeh MN Hesselink WH Kalantar-Nayestanaki N Pellegrino A Spaltro CM Templon JA Hicks RS Kelly JJ Marchand C 《Physical review letters》1994,73(20):2684-2687
33.
Milton SV Gluskin E Biedron SG Dejus RJ Den Hartog PK Galayda JN Kim K Lewellen JW Moog ER Sajaev V Sereno NS Travish G Vinokurov NA Arnold ND Benson C Berg W Biggs JA Borland M Carwardine JA Chae Y Decker G Deriy BN Erdmann MJ Friedsam H Gold C Grelick AE 《Physical review letters》2000,85(5):988-991
Experimental evidence for self-amplified spontaneous emission (SASE) at 530 nm is reported. The measurements were made at the low-energy undulator test line facility at the Advanced Photon Source, Argonne National Laboratory. The experimental setup and details of the experimental results are presented, as well as preliminary analysis. This experiment extends to shorter wavelengths the operational knowledge of a linac-based SASE free-electron laser and explicitly shows the predicted exponential growth in intensity of the optical pulse as a function of length along the undulator. 相似文献
34.
A Multifunctional Subphthalocyanine Nanosphere for Targeting,Labeling, and Killing of Antibiotic‐Resistant Bacteria 下载免费PDF全文
Indranil Roy Dr. Dinesh Shetty Dr. Raghunandan Hota Dr. Kangkyun Baek Jeesu Kim Prof. Dr. Chulhong Kim Sandro Kappert Prof. Dr. Kimoon Kim 《Angewandte Chemie (International ed. in English)》2015,54(50):15152-15155
Developing a material that can combat antibiotic‐resistant bacteria, a major global health threat, is an urgent requirement. To tackle this challenge, we synthesized a multifunctional subphthalocyanine (SubPc) polymer nanosphere that has the ability to target, label, and photoinactivate antibiotic‐resistant bacteria in a single treatment with more than 99 % efficiency, even with a dose as low as 4.2 J cm?2 and a loading concentration of 10 nM . The positively charged nanosphere shell composed of covalently linked SubPc units can increase the local concentration of photosensitizers at therapeutic sites. The nanosphere shows superior performance compared to corresponding monomers presumably because of their enhanced water dispersibility, higher efficiency of singlet‐oxygen generation, and phototoxicity. In addition, this material is useful in fluorescence labeling of living cells and shows promise in photoacoustic imaging of bacteria in vivo. 相似文献
35.
Development of bacteriorhodopsin (bR) analogues employing chromophore substitution technique for the purpose of characterizing the binding site of bR and generating bR analogues with novel opto-electronic properties for applications as photoactive element in nanotechnical devices are described. Additionally, the photophysical and photochemical properties of variously substituted diarylpolyenes as models of photobiologically relevant linear polyenes are discussed. The role of charge separated dipolar excited states in the photoprocesses of linear polyenes is highlighted. 相似文献
36.
Infrared-to-visible wave-length conversion in the Yb3+−Er3+ doped phosphors system has been described by a simple three level model based on two ions mechanism. The excitation in the
range of 900–1000 nm of an IR-photon is first absorbed by Yb3+ ion as a sensitizer attributed to the resonant energy transition in Er3+ ion from 4
I
3/2 → 4
S
15/2 and 1
F
9/2 → 4
I
15/2, respectively for green and red emission. The essential energy transfer processes in this system i.e. upconversion from 4
I
11/2 and 1
I
13/2, cross-relaxation from 4
S
3/2 and 1
F
9/2 are taken into account. The limitations of the rate-equation approach are examined with a focus on the underlying dynamics
of this rare-earth system. 相似文献
37.
The absorption spectrum of D-TCNQ (D is potassium, barium, calcium and perylene) has been studied between 3100 Å and 24000 Å and from 10 K to room temperature. In the metal compounds, the locally excited ultraviolet and visible bands sharpened considerably at lower temperatures revealing vibronic structure, while the charge transfer bands in the infrared remained relatively broad and temperature independent. In these compounds the TCNQ's stack on top of each other. We have also observed the monomer spectrum in Ba(TCNQ)2, indicating incomplete charge transfer. In the perylene- TCNQ compounds, we have observed at lower temperatures vibronic structure in the locally excited ultraviolet bands but not in the charge transfer intrared bands. We have also observed the monomer spectrum in the perylene-TCNQ compounds. 相似文献
38.
M K Malik R V Raghavan P Chaddah PK Mishra G Ravi Kumar BA Dasannacharya 《Pramana》1987,29(1):L111-L112
We report critical current measurements on sintered Y0.35Ba0.65CuOy. The sample, in the perovskite phase, shows zero resistance at 87 K. The critical current transition is seen, in zero field
and at 77 K, at a current densityJ
c of 50 A/cm2. 相似文献
39.
40.