Modified Graphite Paste Electrode with Lewatit FO36 Nanoresin/Multi-Walled Carbon Nanotubes for Determination of Quercetin

In the present study, the electrochemical oxidation of quercetin (QUR) was investigated using a graphite paste electrode (GPE) modified with multi-walled carbon nanotube and Lewatit FO36 nanoresin (LFONR-MWCNT/GPE). LFONR-MWCNT/GPE could effectively a sensitive anodic peak at around 0.23 V (vs. SCE) in a 0.10 M phosphate buffer solution. Modified electrode revealed that activated with multiwalled carbon nanotube and LFONR was capable of facilitating electron transfer and increasing surface area. The electrochemical oxidation of QUR was studied using cyclic voltammetry (CV) and linear sweep voltammetry (LSV). Some kinetic parameters for electrochemical oxidation of QUR including total number of electrons (n) and standard heterogeneous rate constant (k_s) were also determined. The calibration graph consisted of two linear segments of 1.8–25.0 μM, and 25.0–570.0 μM with a detection limit of 0.213 μM (based on 3S_b). The applicability of the method to juice of peach, red grape, sour cherry and Gincora tablets analysis was also evaluated.     

Multicomponent synthesis of C-tethered bispyrazol-5-ols using CeO2 nanoparticles as an efficient and green catalyst

Research on Chemical Intermediates - CeO2 nanoparticles have been used as an efficient catalyst for the preparation of C-tethered bispyrazol-5-ols by pseudo five-component reaction of...     

Ion-selective carbon paste electrode based on new tripodal ligand for determination of cadmium (II)

A new chemically modified carbon paste electrode for Cd(II) ions based on 3,5-dinitro-N-(tri-2-pyridyl methyl) benzamide (DNTPMBA) as an ionophore was prepared. The electrode exhibits a Nernstian response for Cd(II) ions over a wide concentration range (2.16 × 10^?7–1.00 × 10^?1 mol L^?1) with a slope of 30 ± 1 mV per decade. It has a response time of about 50 s and can be used for a period of 3 months with good reproducibility. Detection limit obtained in the optimal conditions was 1.82 × 10^?7 mol L^?1. The electrode was successfully used for potentiometric determination of Cd(II) in well water. The pH influence and interference of some cations were also studied.     

Effects of Final State Interactions in Pure Annihilation Decay of B+ → D+K0*

The decay of the B ⁺ meson to the D ⁺ and K ⁰* mesons is a pure annihilation decay. For this reason, in the framework of the quantum chromodynamics factorization (QCDF) approach, this decay has a small amplitude and a small branching ratio. In this research we find that, before the D ⁺ and K ⁰* mesons are produced in the final states, pair mesons such as D _s ⁺* and D _s ⁺ρ⁰ are produced. The intermediate-state mesons via the exchange of K ⁰(K ⁰*) and D ⁺(D ⁺*) go to the D ⁺ and K ⁰* final state mesons. However we calculate the B ₊ → D ⁺ K ⁰* decay in two different frameworks. The first framework is the QCDF method and the second one is final state interaction (FSI). The experimental branching ratio of B ₊ → D ₊ K ⁰* decay is less than 3 × 10^–6, and our results obtained by the QCDF method and FSI are (0.35 ± 0.04) × 10^–6 and (2.94 ± 0.10) × 10^–6, respectively.     

On the b-chromatic number of Kneser graphs

In this note, we prove that for any integer n≥3 the b-chromatic number of the Kneser graph KG(m,n) is greater than or equal to . This gives an affirmative answer to a conjecture of [6].     

Gradient WEB-spline finite element method for solving two-dimensional quasilinear elliptic problems

In this paper, a two-dimensional quasilinear elliptic problem of the form -divF(x,▽u)=g(x)$-\mathit{divF}(\mathbf{x}\text{,}▽u)=g(\mathbf{x})$ is considered. This problem is ill-conditioned and we therefore propose a modified iterative algorithm based on coupling of the Sobolev space gradient method and WEB-spline finite element method. Applying the preconditioned iterative method, which has been already provided by Farago and Karatson (2001) [1] reduces the our considered problem to a sequence of linear Poisson’s problems. Then the WEB-spline finite element method is applied to the approximate solution of these Poisson’s problems. In this sense, a convergence theorem is proved and the advantages of this technique than the gradient finite element method (GFEM) is also described. Finally, the presented method is tested on some examples and compared with GFEM. It is shown that the gradient WEB-spline finite element method gives better test results.     

Convenient,Mild and One‐Pot Synthesis of Double Schiff Bases from Three Component Reaction of Salicylaldehyde,Ammonium Acetate and Aliphatic Aldehydes Accelerated by NEt3 as a Base

A convenient and efficient procedure for one‐pot preparation of double Schiff bases through a three component reaction of salicylaldehyde, ammonium acetate and aliphatic aldehyde was described. In this reaction, N,N′‐bis(salicylidene)‐1,1‐diaminoalkanes was easily obtained in excellent yields and short reaction times under mild reaction condition.