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11.
The difference in reactivity of the two modifications of InCl in solid state reactions with SnCl2 is discussed. It is explained on the basis of semi‐empirical and ab initio calculations giving the density of states diagrams of InCl and the energies of possible disproportionation reactions. Their general features are discussed on the basis of a simple bonding picture for open‐packed structures involving inert pair elements. A detailed analysis of the DOS distribution allows to pinpoint the observed redox instability to a specific structural feature of α‐InCl. 相似文献
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Alexander G. Stepanov Sergei S. Arzumanov Horst Ernst Dieter Freude 《Chemical physics letters》2006,420(4-6):574-576
It has been demonstrated that 1H MAS NMR spectroscopy can be used as a tool for in situ monitoring the reaction kinetics of 13C-labeled carbon scrambling in alkane molecules adsorbed on zeolite catalysts at the reaction temperature of 540–570 K. The accuracy of the results and the time resolution are improved compared to 13C MAS NMR spectroscopy. 相似文献
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Sam I. Ahonkhai
Andreas N
llePeter Behr
Horst Heydtmann 《Journal of photochemistry and photobiology. A, Chemistry》1994,80(1-3):389-392Experimental results are presented of a Fourier transform IR product study at 298 K of the reaction system CFO+O2 at oxygen pressures between 3 and 250 mbar. Pulsed photolysis of oxalyl fluoride (CFO)2 or formyl fluoride (CHFO) at 193 nm was used to produce CFO. As stable products we detected bis-fluoroformyl peroxide, carbonyl fluoride and carbon dioxide. The yields of the peroxide and of CF2O were measured as a function of [O2]/[precursor] and are discussed qualitatively. 相似文献
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Horst W. Hamacher Martine Labbé Stefan Nickel Anders J.V. Skriver 《Annals of Operations Research》2002,110(1-4):33-53
Locating a facility is often modeled as either the maxisum or the minisum problem, reflecting whether the facility is undesirable (obnoxious) or desirable. But many facilities are both desirable and undesirable at the same time, e.g., an airport. This can be modeled as a multicriteria network location problem, where some of the sum-objectives are maximized (push effect) and some of the sum-objectives are minimized (pull effect).We present a polynomial time algorithm for this model along with some basic theoretical results, and generalize the results also to incorporate maximin and minimax objectives. In fact, the method works for any piecewise linear objective functions. Finally, we present some computational results. 相似文献
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A. A. van der Horst A. M. van der Kraan J. J. van Loef D. J. Lieftink C. Joosten 《Hyperfine Interactions》1994,91(1):613-618
Mössbauer spectroscopy has been applied to two rattle stones found in the Netherlands, which have been formed under different pedoenvironment conditions in the past. Ultrafine particles of goethite are dominantly present in both core and mantle of these stones. The latter differs in both composition and mean particle size; this is related to the distinct manner of their formation. 相似文献