A Cation‐Exchange Approach for the Fabrication of Efficient Methylammonium Tin Iodide Perovskite Solar Cells

Tin‐based halide perovskite materials have been successfully employed in lead‐free perovskite solar cells, but the overall power conversion efficiencies (PCEs) have been limited by the high carrier concentration from the facile oxidation of Sn²⁺ to Sn⁴⁺. Now a chemical route is developed for fabrication of high‐quality methylammonium tin iodide perovskite (MASnI₃) films: hydrazinium tin iodide (HASnI₃) perovskite film is first solution‐deposited using presursors hydrazinium iodide (HAI) and tin iodide (SnI₂), and then transformed into MASnI₃ via a cation displacement approach. With the two‐step process, a dense and uniform MASnI₃ film is obtained with large grain sizes and high crystallization. Detrimental oxidation is suppressed by the hydrazine released from the film during the transformation. With the MASnI₃ as light harvester, mesoporous perovskite solar cells were prepared, and a maximum power conversion efficiency (PCE) of 7.13 % is delivered with good reproducibility.     

The Second Spacer Cation Assisted Growth of a 2D Perovskite Film with Oriented Large Grain for Highly Efficient and Stable Solar Cells

The fabrication of high‐quality film with large grains oriented along the direction of film thickness is important for 2D Ruddlesden–Popper perovskite‐based solar cells (PVSCs). High‐quality 2D BA₂MA_n?1Pb_nI_3n+1 (BA⁺=butylammonium, MA⁺=methylammonium, n=5) perovskite films were fabricated with a grain size of over 1 μm and preferential orientation growth by introducing a second spacer cation (SSC⁺) into the precursor solution. Dynamic light scattering showed that SSC⁺ addition can induce aggregation in the precursor solution. The precursor aggregates are favorable for the formation of large crystal grains by inducing nucleation and decreasing the nucleation sites. Applying phenylethylammonium as SSC⁺, the optimized inverted planar PVSCs presented a maximum PCE of 14.09 %, which is the highest value of the 2D BA₂MA_n?1Pb_nI_3n+1 (n=5) PVSCs. The unsealed device shows good moisture stability by maintaining around 90 % of its initially efficiency after 1000 h exposure to air (Hr=25±5 %).     

Isolation,structure elucidation,and antibacterial evaluation of the metabolites produced by the marine-sourced Streptomyces sp. ZZ820

New indole alkaloids streptoprenylindoles A–C (1–3) and diterpenoids 18-acetyl-cyclooctatin (8), 5,18-dedihydroxy-cyclooctatin (9), and 5-dehydroxy-cyclooctatin (10) were isolated from the culture of marine-derived Streptomyces sp. ZZ820, along with known 3-cyanomethyl-6-[3-methyl-2-butenyl]indole (4), N-(2-(1H-indol-3-yl)ethylacetamide (5), 1-acetyl-β-carboline (6), indole-3-methylethanoate (7), cyclooctatin (11), and chromomycin A₃ (12). Their structures were elucidated by a combination of extensive spectroscopic analyses, ECD calculation, and the Mosher's method. Streptoprenylindoles A (1) and B (2) are enantiomers that were separated through the preparation of their Mosher esters. Three new diterpenoids (8–10) showed antibacterial activities against methicillin-resistant Staphylococcus aureus (MRSA) and Escherichia coli with MIC values of 24.11–55.12?μM, while chromomycin A₃ (12) showed potent antibacterial activities against MRSA (MIC: 0.59?μM) and E. coli (MIC 0.04?μM).     

Inverted Perovskite Solar Cells Based on Small Molecular Hole Transport Material C8‐Dioctylbenzothienobenzothiophene

The small organic molecular Dioctylbenzothienobenzothiophene (C₈‐BTBT) has been explored as hole transport material (HTM) to replace PEDOT:PSS in inverted perovskite solar cells (PVSCs). MAPbI₃ perovskite films depositd onto C₈‐BTBT are smooth and uniform, with negligible residual of PbI₂ and large grain size even larger than 1 μm. Our champion C₈‐BTBT based devices reached a high power conversion efficiency (PCE) of 15.46% with marginal hysteresis, much higher than that of 11.50% achieved using PEDOT:PSS. Besides, devices adopting C₈‐BTBT as substrate show superior stability compared with the PEDOT:PSS based devices when stored under ambient conditions with a relative humidity of (25±5)%.     

Geometric Potential and Dirac Quantization

A fundamental problem regarding the Dirac quantization of a free particle on an () curved hypersurface embedded in N flat space is the impossibility to give the same form of the curvature‐induced quantum potential, the geometric potential as commonly called, as that given by the Schrödinger equation method where the particle moves in a region confined by a thin‐layer sandwiching the surface. This problem is resolved by means of a previously proposed scheme that hypothesizes a simultaneous quantization of positions, momenta, and Hamiltonian, among which the operator‐ordering‐free section is identified and is then found sufficient to lead to the expected form of geometric potential.     

非线性弹性大变形材料梁的抗爆特性

从理论上探讨了非线性弹性大变形材料应用于抗爆结构的可行性,为此,基于等效结构体系的分析原理,将两端固定铰支梁的横向和纵向位移表示为三角级数形式,应用第二类Lagrange方程建立了非线性大变形材料梁的非线性分析方法,并且用ABAQUS有限元软件中的超弹性材料模型验证了所提出的方法的有效性。对典型的爆炸荷载作用下非线性弹性大变形材料梁的抗爆特性进行了分析,讨论了动力放大系数和材料性质及动荷载之间的关系。结果表明:与线弹性小变形材料相比,非线性弹性大变形材料具有优良的抗爆特性,结构的抗爆能力随结构变形的增大而显著提高。     

网络编码在高质量应用层组播中的应用

在面向节点群的混合网状应用层组播模型(Hybrid Mesh Application Multicast Model,HM-ALM)中设计并实现了确定性线性网络编码,探讨了网络编码对提高组播性能的作用.实验表明,网络编码能减少传输延迟和增强系统健壮性.使用网络编码后系统传输延迟减少了约50%;在系统动态变化时,正确接收数据的节点数可以达到最大值,系统能更快恢复稳定.     

直流电弧等离子体法制备纳米粒子实验装置研究

研制了一种实验室用直流电弧等离子体法制备纳米粒子的实验装置,该装置由纳米粒子生成室、阴极、阳极、真空泵和直流电源等组成。其特点是：结构简单、操作方便、成本低。该实验装置可用于制备金属纳米粒子、合金纳米粒子及金属一陶瓷复合纳米粒子。     

Phase correction and resolution improvement of digital holographic image in numerical reconstruction with angular multiplexing

A phase correction method is presented to remove the phase slope of the sub-holograms caused by the multi-direction illumination on object in digital holography. To improve the resolution of the reconstructed holographic images, two sub-holograms are recorded by using angular multiplexing and their phase slope parameter is obtained by theoretical analysis. Introducing a phase correction parameter to this phase slope, the ideal complex reconstructed image can be obtained by superposing the reconstructed object wave fields of the two sub-holograms. Experimental results demonstrate that the resolution of the reconstructed image can be effectively enhanced.     

疏水缔合聚合物在石英砂表面的吸附——疏水基含量和微嵌段长度对吸附的影响

研究了不同分子结构的疏水缔合聚合物和部分水解聚丙烯酰胺在45、55和65 ℃下的静态吸附特征。 实验结果表明,疏水缔合聚合物的疏水基含量和微嵌段长度可以改变聚合物在石英砂表面的最大吸附量,而其中疏水基含量是主要影响因素,等温吸附曲线出现2个平台区。 随着温度的升高, 部分水解聚丙烯酰胺吸附量增大,而缔合聚合物则表现出相反的规律;缔合聚合物通过改变疏水基含量和微嵌段长度来影响其吸附性能。