塑料闪烁体阵列探测器读出ASIC中峰值保持电路的设计

塑料闪烁体阵列探测器(PSD,简称塑闪阵列探测器)的输出信号经过前置放大器和滤波成形电路后输出准高斯波形,利用峰值保持电路可对准高斯波形信号的峰值进行采样和保持,以便后续的电子学系统对其进行进一步的分析。本工作采用180 nm CMOS工艺设计并实现了一款峰值保持电路ASIC芯片,每通道主要由跨导放大器(OTA)、电流镜和充电电容三部分电路组成。实验室电子学功能和性能测试结果表明：峰值保持电路功能良好;输入动态范围为33～940 mV,非线性误差优于0.8%,下垂速率好于8.6μV/μs,峰值探测延迟时间小于35 ns,芯片单通道静态功耗为825μW,达到设计要求。     

强辐射环境下高能脉冲裂变中子探测方法

在研究通道衰减、探测方法分离和探测器中子/射线本征分辨的基础上,研究了测量高能脉冲裂变中子数目的探测技术。基于电流型Si-PIN探测器,设计了减本底的背靠背探测结构,给出了测量强射线和低能散射中子干扰信号及有效扣除强辐射本底的实现方法,最终实现了高n/n和n/分辨测量和强裂变中子、射线混合场中的高能脉冲裂变中子数目探测,探测系统的信号/辐射本底比可达到10倍以上。     

Synthesis,Structure and Theoretical Research of a New Triaryl Phosphine Complex [HgCl<Subscript>2</Subscript>(PPh<Subscript>2</Subscript>Bz)<Subscript>2</Subscript>] (PPh<Subscript>2</Subscript>Bz = Benzyldiphenylphosphine)

Abstract  The solution-phase reaction of HgCl₂ with benzyldiphenylphosphine (PPh₂Bz) yields a new triaryl phosphine complex [HgCl₂(PPh₂Bz)₂] (1) with the bigger P–Hg–P angle, the longer Hg–Cl bond, and the shorter Hg–P bond. Comparison of the sensitive bond parameters with similar compounds and the theoretical calculation show that the σ-donating abilities of tertiaryl phosphine ligands toward HgCl₂ conforms to the following order: PEt₃ > PPh₂Bz > P(2-thienyl)₃ > dppf > PPh₃. Graphical Abstract  The solution-phase reaction of HgCl₂ with benzyldiphenylphosphine (PPh₂Bz) yields a new triaryl phosphine complex [HgCl₂(PPh₂Bz)₂] (1) with the bigger P–Hg–P angle. Comparison of the sensitive bond parameters with similar compounds shows that the σ-donating abilities of tertiaryl phosphine ligands toward HgCl₂ conforms to the following order: PEt₃ > PPh₂Bz > P(2-thienyl)₃ > dppf > PPh₃.      

Global weak solutions and asymptotics of a singular PDE-ODE Chemotaxis system with discontinuous data

This paper is concerned with the well-posedness and large-time behavior of a two-dimensional PDE-ODE hybrid chemotaxis system describing the initiation of tumor angiogenesis. We first transform the system via a Cole-Hopf type transformation into a parabolic-hyperbolic system and then show that the solution to the transformed system converges to a constant equilibrium state as time tends to infinity. Finally we reverse the Cole-Hopf transformation and obtain the relevant results for the pre-transformed PDE-ODE hybrid system.In contrast to the existing related results, where continuous initial data is imposed, we are able to prove the asymptotic stability for discontinuous initial data with large oscillations. The key ingredient in our proof is the use of the so-called "effective viscous flux", which enables us to obtain the desired energy estimates and regularity. The technique of the "effective viscous flux" turns out to be a very useful tool to study chemotaxis systems with initial data having low regularity and was rarely(if not) used in the literature for chemotaxis models.     

低价钛试剂存在下β -酮砜的还原脱砜

在温和的条件下, 低价钛试剂能容易地还原β -酮砜得到较高产率的相应的酮.     

Polarization-dependent coupling in a 1x4 waveguide array in lithium niobate fabricated by femtosecond pulses

We demonstrate a 1×4 waveguide array produced by an IR femtosecond laser in z-cut lithium niobate (LiNbO₃). The polarization dependence of light coupling in this waveguide structure is experimentally investigated. The coupling constants of the waveguide array are obtained by measuring the ratio of output power of each waveguide for extraordinary rays and ordinary rays, and the variation of coupled power in each waveguide as a function of the waveguide length are demonstrated. PACS 42.65.Re; 77.84.Dy; 42.82.Et     

New types of the flexible self-assembled metal-organic coordination polymers constructed by aliphatic dicarboxylates and rigid bidentate nitrogen ligands

The reaction of metal ions, flexible aliphatic dicarboxylates and rigid bidentate linear ligands under mild conditions in water afford four novel metal-organic coordination polymers, [Cd(mu-mal)(mu-pyz)(0.5)(H(2)O)](n) 1 (mal = malonate dianion, pyz = pyrazine), [Cd(2)(mu-suc)(2)(mu-pyz)(H(2)O)(2)](n) 2 (suc = succinate dianion), and ([M(mu-bipy)(H(2)O)4][suc].4H(2)O)(n)(M = Co, 3, M = Zn, 4, bipy = 4,4'-bipyridine). The molecular structures of 1-4 have been established by single-crystal X-ray crystallography. 1 is a 3D network being composed of layers of octahedrally coordinated Cd atoms bridged by malonate anions in syn-anti configurations within the layers and pyz molecules between layers. Unlike that in 1, each Cd atom in 2 displays uncommon pentagonal-bipyramidal geometry to form 2D infinite grid sheets with square grid dimensions of ca. 7.936 x 7.936 [Angstrom]. Both 3 and 4 exhibit 1D linear -M-bipy-M-bipy- chain polymers, and these chains were packed as ...ABCABC... layered structures. The bridging succinate ligands in 2 adopt the syn-anti mode with a torsion angle of 60.8(7) degrees, while the solvated succinate ligands in 3 and 4 adopt the anti-anti mode with a torsion angle of 180.0 degrees. To our knowledge, compound 2 represents the first example of flexible self-assembled succinate-pyrazine mixed bridging ligand coordination network. 3 and 4 are the first two cases of succinate-bipy polymers with non-coordinated succinate. The magnetic behavior for 3 was studied in the temperature range of 5-300 K. The result indicates the occurrence of a weak antiferromagnetic coupling between the cobalt(II) ions.     

PLS–分光光度法同时测定三组分阳离子染料

将偏最小二乘法用于可见分光光度分析,建立一种同时测定阳离子黄X–8GL、阳离子红X–FG、阳离子艳蓝RL三组分混合染料含量的新方法。在380～780 nm范围内,将测定的26组混合溶液的吸光度值作为校正集,另8组混合溶液的吸光度值作为预测集,结合二阶差分法确定最佳主成分数。测得三组分混合体系中校正集的相关系数分别为0.9988,0.9994,0.9964;交互验证均方根误差(RMSECV)分别为0.0754,0.1852,0.2168;预测集的相关系数分别为0.9984,0.9996,0.9981;预测均方根误差(RMSEP)分别为0.1086,0.1877,0.2515。该方法无需样品分离,可为染色过程中多组分染料浓度的在线监测提供技术支撑。     

水溶性Fe3O4磁性纳米催化剂的合成及应用

利用对氨基苯磺酸氟硼酸重氮盐与Fe₃O₄磁性纳米粒子(MNPs)的偶联反应,非常方便地制备出表面含有磺酸基的Fe₃O₄磁性纳米粒子。 透射电子显微镜(TEM) 测试结果表明,粒子的平均粒径在 20 nm左右。 溶解性实验表明,该纳米粒子具有较好的水溶性,但不溶于常用的有机溶剂,因此可利用其磁性回收并循环使用。 将该纳米粒子用于催化羧酸与醇的酯化反应,产物酯的收率为71%~86%。 催化剂在酯化反应中的最优使用量为1.5%(质量分数)。 同时,该催化剂可催化果糖合成5-羟甲基糠醛(HMF),收率为32%。     

从人—地关系谈环境教育

本文从人—地关系引出人类要合理利用自然、改造自然,必须提高人们的环境意识,最有效的方法是在化学教育中渗透环境教育,提高人们的综合素质,才能实现人与自然的协调发展。