聚合物流变特性标准物质的研制

介绍聚合物流变特性标准物质的研制过程。聚合物流变特性标准物质主要由聚异丁烯和十六烷组成。研制的该标准物质具有良好的均匀性、稳定性。经对测定数据进行统计处理,确定了该标准物质在不同静态剪切速率下粘度和第一法向应力差的标准值并给出了其相对扩展不确定度。     

LaF3薄片的液相合成和表征

Single-crystalline LaF3 flakes was synthesized through a facile solution-phase approach in aqueous ammonia and ethylenediamine. Applying the thermal treatment at 100 ℃ for 20 h, the LaF3 recrystallized, grew epitaxially and precipitated into flakes in aqueous ammonia or ethylenediamine. The formation of flakes could be attributed to the coordination effect of the solvent.     

Syntheses of Some Organic Fluorescent Dyes for Security Tickers

Five organic fluorescence dyes were synthesized by two- or three-step reactions. These synthetic meth-ods have an advantage of the simple processes, low costs and high yields. The compositions of the five compounds are characterized by IR, ^1H NMR, elemental analyses and fluorescence spectroscopies. The quantum yields of fluorescence were measured.     

Monte Carlo simulation of magnetic nanostructured thin films

Using Monte Carlo simulation, we have compared the magnetic properties between nanostructured thin films and two-dimensional crystalline solids. The dependence of nanostructured properties on the interaction between particles that constitute the nanostructured thin films is also studied. The result shows that the parameters in the interaction potential have an important effect on the properties of nanostructured thin films at the transition temperatures.     

Synchronization of chaotic systems based on adaptive observer design

The synchronizing problem of a chaotic system is investigated based on the observer design. The nonlinear section is assumed to satisfy the Lipschitz condition. Firstly, the normal observer is designed based on the known Lipschitz constant and the results are given in linear matrix inequality (LMI) form. Then a fairly simple adaptive observer is designed with the Lipschitz constant unknown. Simulations on synchronizing the Lorenz system are investigated and the results show the validity and feasibility of our main results.     

Study of the selective catalysis of metalloporphyrins for 2-methyl-butane oxidation with PhIO under mild conditions

Nine ironporphyrins and eight manganeseporphyrins were synthesized, and their selective catalysis for the oxidation of the secondary and tertiary carbon–hydrogen bonds of 2-methyl-butane with PhIO was studied. The proportion of the oxidation product of tertiary carbon–hydrogen bond to the one of secondary carbon–hydrogen bond was 3:1 when ironporphyrins were used as catalysts, and 2.3:1 when manganeseporphyrins were used as catalysts. The research showed that the substituting groups on the porphyrin rings influenced the catalytic selectivity of metalloporphyrins for the oxidation of the secondary and tertiary carbon–hydrogen bonds as well as the reaction yields. The electron-attracting groups on benzene rings of ironporphyrins increased the catalytic selectivity of ironporphyrins for the tertiary carbon–hydrogen bond oxidation and the reaction speeds, and the electron-releasing groups increased the catalytic selectivity for secondary carbon–hydrogen bond oxidation and reduced the reaction speeds. Both electron-attracting and -releasing groups on benzene rings of manganeseporphyrins enhanced the catalytic selectivity of manganeseporphyrins for the secondary carbon–hydrogen bond oxidation.     

非理想二元表面活性剂复配增效理论的进一步研究

在Rubingh与Rosen 提出非理想二元表面活性剂复配增效条件基础上,利用相分离模型和正规溶液理论,导出了体系降低表面张力的能力增效条件βs-βm<0,及最佳摩尔分数α1*、最低表面张力γ*cmc12和γ*cmc处对应的临界胶束浓度cmc*12.通过作三条γ～logc曲线或两条γ～logc曲线加上一个cmc值的方法,对C12NMe3Br～C12SO4Na、 C12NMe3Br～C8SO4N两种复配体系进行验证,计算结果与实验结果相符.     

开关振荡器特性阻抗选取对输出波形影响

开关振荡器是宽带高功率电磁脉冲的重要产生方式之一,以开关激励同轴振荡器为例,采用理论计算和电磁仿真为主要手段,从传输线特性阻抗与开关振荡器储能、传输线特性阻抗与天线阻抗关系及传输线特性阻抗和开关导通阻抗关系三个方面进行了研究。研究结果表明：传输线阻抗越小,振荡器储能越高;天线阻抗与传输线阻抗比值越大,输出信号品质因数越大,频谱上能量越集中,带宽越小,能量效率随比值增大呈现先增大后减小趋势;传输线特性阻抗很小时,开关阻抗对输出振荡信号影响增大,此时随特性阻抗减小,输出信号中心频率降低,品质因数减小,频谱上能量分散,带宽较宽。     

时基反馈控制的Tesla变压器初级电源

LC谐振充电是Tesla变压器常用的初级电容充电技术,但存在对控制时序要求高、易受电磁干扰和不具备故障保护能力等缺陷。针对这个问题,提出了一种时基反馈控制的LC谐振充电电源。该电源与传统LC谐振电源的主要区别在于,采用特殊设计的时基反馈电路取代多路时基控制器,将能量回收开关反向阻断瞬间的电压突变调制为谐振晶闸管触发信号,从而在能量回收结束时刻启动谐振充电,实现各工作回路准确按照预定时序运行。时基反馈电路由高压元件构成,不易受电磁干扰,且在原理上具备负载短路保护能力。该技术已经应用于CKP1000,CKP5000等多台Tesla型超宽谱脉冲源。实验结果表明,在强脉冲辐射环境下,该电源能够1000 Hz重频稳定运行,且能够在Tesla变压器初级短路故障时进行快速自动保护。     

扩展目标光学特性的理论分析与研究

利用双向反射分布函数经验公式推导出激光主动照明条件下的目标反射截面表达式,给出了目标反射截面的一种近似计算方法,基于该方法计算了圆锥体目标反射截面。利用固体激光器和CMOS相机搭建实验系统,实际测量了目标反射截面随入射角度和不同目标体等参数变化时的变化情况,实验系统及数据同提出的方法计算得到的结果基本一致。结果表明,目标形状相同,入射角小于45时,目标反射截面随着无涂层、白色油漆、灰色油漆逐渐变小,大于45时白色油漆涂层目标反射截面最大;在目标表面特性相同的时候,目标反射截面随圆板、圆柱、圆锥渐次减小。