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91.
Qiuhua Nie Tiefeng Xu Xiang shen Xudong Zhang 《Journal of Physics and Chemistry of Solids》2006,67(11):2345-2350
The absorption and upconversion fluorescence spectra of a series of Er3+/Yb3+-codoped natrium-germanium-bismuth glasses have been studied. The transition probabilities, excited state lifetimes, and the branching ratios have been predicted for Er3+ based on the Judd-Ofelt theory. At room temperature, an upconversion efficiency of 6.1×10−2 has been obtained for the green emission from the glass with 0.5 wt% Er2O3 and 3.0 wt% Yb2O3 pumped by 980 nm radiation with an intensity of 270 W/cm2. And the “standardized” efficiency for green upconversion light is higher than that reported in lead-germanate, lead-tellurite-germanate, and silicate glasses. The results indicate that the Er3+/Yb3+-codoped natrium-germanium-bismuth oxide glass may be a potential material for developing upconversion optic devices. 相似文献
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The pure Cr2O3 coated Li4Ti5O12 microspheres were prepared by a facile and cheap solutionbased method with basic chromium(III) nitrate solution (pH=11.9). And their Li-storage properties were investigated as anode materials for lithium rechargeable batteries. The pure Cr2O3 works as an adhesive interface to strengthen the connections between Li4Ti5O12 particles, providing more electric conduction channels, and reduce the inter-particle resistance. Moreover, LixCr2O3, formed by the lithiation of Cr2O3, can further stabilize Li7Ti5O12 with high electric conductivity on the surface of particles. While in the acid chromium solution (pH=3.2) modification, besides Cr2O3, Li2CrO4 and TiO2 phases were also found in the final product. Li2CrO4 is toxic and the presence of TiO2 is not welcome to improve the electrochemical performance of Li4Ti5O12 microspheres. The reversible capacity of 1% Cr2O3-coated sample with the basic chromium solution modification was 180 mAh/g at 0.1 C, and 134 mAh/g at 10 C. Moreover, it was even as high as 127 mAh/g at 5 C after 600 cycles. At-20℃, its reversible specific capacity was still as high as 118 mAh/g. 相似文献
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The doping effect of Cu on the self-assembly film of melamine on an Au(111) surface has been investigated with scanning tunneling microscopy (STM). The evaporated Cu adatoms occupy the positions underneath the amino groups and change the hydrogen bonding pattern between the melamine molecules. Accordingly, the self-assembly structure has changed stepwise from a well-defined honeycomb into a track-like and then a triangular structure depending on the amount of Cu adatoms. The interaction between Cu adatom and melamine is moderate thus the Cu adatoms can be released upon mild heating to around 100℃. These findings are different from previous observations of either the coordination assembly or the physically trapped metal adatoms. 相似文献
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副品红共振光散射法测定脱氧核糖核酸 总被引:3,自引:0,他引:3
本文基于脱氧核糖核酸 (DNA)对有机染料副品红的共振光散射的增强效应 ,拟定了一种测定DNA的共振光散射法。在pH =0 5~ 1 5范围内 ,有机染料副品红于 35 5nm处的共振光散射强度被DNA强烈增强 ,且增强程度与DNA浓度呈线性关系 ,线性范围为 0 10~ 15 μg·mL- 1 ,检出限可达 36ng·mL- 1 。该方法简便、快速、具有较高的灵敏度和准确度 ,且线性范围较宽。将该方法用于混合样品中DNA的测定 ,结果令人满意。 相似文献
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