原位插层聚合制备聚丁二烯/蒙脱土纳米复合材料及其结构与性能研究

采用负离子引发原位插层聚合法制备了聚丁二烯(PB)/有机蒙脱土(OMMT)纳米复合材料(NC).对OMMT纯化方法、OMMT种类和溶剂等因素对聚合反应的影响进行了研究.不同方法纯化的OMMT消耗的BuLi量相差一倍;采用OMMT-DK1制备的NC具有较宽的分子量分布,而采用OMMT-DK1B和OMMT-DK4制备的NC则具有较窄的分子量分布;OMMT在环己烷中不溶解,在甲苯和二甲苯等溶剂中可形成均匀溶液.采用XRD、TEM和H-NMR等仪器对PB/OMMT NC的插层结构、化学结构和形态进行了分析;采用DSC、TGA和DMA等仪器对PB/OMMT NC的Tg、热学性能和动态力学性能进行了研究,结果表明,采用负离子原位插层聚合可得到剥离型PB/OMMT纳米复合材料;与OMMT插层复合明显改变了PB的微观结构组成,在OMMT含量为6.2wt%时,1,2-结构含量增加了近一倍,Tg和Tdc分别增加了10 K和16 K;E′、E″均明显提高,而tanδ下降.     

High photorefractive sensitivity and fast response time of near‐stoichiometric and MgO doped LiNbO3:Fe crystals

Congruent LiNbO₃:Fe and LiNbO₃:Mg,Fe crystals were grown by Czochralski method, and vapor transport equilibration technique was employed to improve the [Li]/[Nb] ratios of these crystals. The influence of stoichiometry and MgO dopant on the photorefractive sensitivity and response time of LiNbO₃:Fe crystals was investigated. Both stoichiometry and MgO dopant can effectively reduce the amount of intrinsic defects, but MgO can also decrease the concentration of Fe²⁺ ions in Li‐sites. Near‐stoichiometric and MgO doped LiNbO₃:Fe crystal has high photorefractive sensitivity and fast response time. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

一些三价稀土离子在碘氧化镧中的发光

本文报导了碘氧化镧的合成和一些稀土离子在其中的发光.碘氧化镧是一具有低声子能量的基质,发光光谱表明一些稀土离子如Er3+等的较高激发态的辐射跃迁可以被观察到.碘氧化镧在240nm处有一较强吸收,并能把能量传递给其它稀土发光中心,这是基质敏化的一个较好例子.而Eu3+在这基质中发光很弱,对此作了简单讨论.     

Added mass matrix estimation of beams partially immersed in water using measured dynamic responses

An added mass matrix estimation method for beams partially immersed in water is proposed that employs dynamic responses, which are measured when the structure is in water and in air. Discrepancies such as mass and stiffness matrices between the finite element model (FEM) and real structure could be separated from the added mass of water by a series of correction factors, which means that the mass and stiffness of the FEM and the added mass of water could be estimated simultaneously. Compared with traditional methods, the estimated added mass correction factors of our approach will not be limited to be constant when FEM or the environment of the structure changed, meaning that the proposed method could reflect the influence of changes such as water depth, current, and so on. The greatest improvement is that the proposed method could estimate added mass of water without involving any water-related assumptions because all water influences are reflected in measured dynamic responses of the structure in water. A five degrees-of-freedom (dofs) mass-spring system is used to study the performance of the proposed scheme. The numerical results indicate that mass, stiffness, and added mass correction factors could be estimated accurately when noise-free measurements are used. Even when the first two modes are measured under the 5 percent corruption level, the added mass could be estimated properly. A steel cantilever beam with a rectangular section in a water tank at Ocean University of China was also employed to study the added mass influence on modal parameter identification and to investigate the performance of the proposed method. The experimental results demonstrated that the first two modal frequencies and mode shapes of the updated model match well with the measured values by combining the estimated added mass in the initial FEM.