全文获取类型
收费全文 | 346篇 |
免费 | 36篇 |
国内免费 | 37篇 |
专业分类
化学 | 262篇 |
晶体学 | 1篇 |
力学 | 7篇 |
数学 | 64篇 |
物理学 | 85篇 |
出版年
2023年 | 21篇 |
2022年 | 37篇 |
2021年 | 38篇 |
2020年 | 45篇 |
2019年 | 37篇 |
2018年 | 30篇 |
2017年 | 27篇 |
2016年 | 20篇 |
2015年 | 18篇 |
2014年 | 10篇 |
2013年 | 17篇 |
2012年 | 12篇 |
2011年 | 11篇 |
2010年 | 8篇 |
2009年 | 11篇 |
2008年 | 11篇 |
2007年 | 12篇 |
2006年 | 12篇 |
2005年 | 4篇 |
2004年 | 7篇 |
2003年 | 5篇 |
2002年 | 3篇 |
2001年 | 7篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有419条查询结果,搜索用时 15 毫秒
31.
Chukwuemeka Okolie Yasmeen F. Belhseine Yimeng Lyu Dr. Matthew M. Yung Dr. Mark H. Engelhard Dr. Libor Kovarik Dr. Eli Stavitski Dr. Carsten Sievers 《Angewandte Chemie (International ed. in English)》2017,56(44):13876-13881
The conversion of methane into alcohols under moderate reaction conditions is a promising technology for converting stranded methane reserves into liquids that can be transported in pipelines and upgraded to value‐added chemicals. We demonstrate that a catalyst consisting of small nickel oxide clusters supported on ceria–zirconia (NiO/CZ) can convert methane to methanol and ethanol in a single, steady‐state process at 723 K using O2 as an abundantly available oxidant. The presence of steam is required to obtain alcohols rather than CO2 as the product of catalytic combustion. The unusual activity of this catalyst is attributed to the synergy between the small Lewis acidic NiO clusters and the redox‐active CZ support, which also stabilizes the small NiO clusters. 相似文献
32.
A series of new half-metallocene complexes of titanium containing siloxy ligands and a new bimetallic titanocene complex (compound 1) with a crystallographically determined structure have been prepared. When activated with methylaluminoxane (MAO), they showed high activities toward polymerization of styrene with high syndiotacticity. Origin of the high activity and syndiotacticity found in this work was investigated systematically by comparison with polymerization results using other known complexes. 相似文献
33.
Tsao L. Dou Kh. Sun' G. Lyu Yu. Koroteev A. M. Krasnov G. B. 《Russian Journal of Organic Chemistry》2003,39(3):384-391
The reactivity of melezitose hydroxy groups was studied by tritylation in pyridine with subsequent acetylation. After partial detritylation of the products, acetyl group transfer from position 4 to 6 was observed. The structure of the prepared melezitose derivatives was established on the basis of their IR, 1H, 13C, and 1H-1H COSY NMR, and mass spectra (fast atom bombardment), as well as from the results of model calculations performed with the aid of SGI Indigo Molecule-Pattern-Work-Station software package (Biosym) where the potential energy function was approximated with the CVFF potential. The reactivity of primary hydroxy groups in melezitose was found to decrease in the following order: 6' > 6 6' > 1'. 相似文献
34.
35.
Criteria for the near and far electromagnetic fields of ultrawideband radiation are considered based on a numerical simulation.
To estimate the field boundaries for ultrawideband radiation, it is proposed to use the condition of the maximum (near field)
and minimum (far field) differences between the time dependences of the electromagnetic field components. The approach proposed
has been approved for an axially symmetric radiator excited by voltage pulses of varied waveform and duration.
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 46–50, September, 2008. 相似文献
36.
Sang Hee Han Sang Kyu Kim Kyoungsook Park So Yeon Yi Hong-Kun Lyu Bong Hyun Chung 《Analytica chimica acta》2010,665(1):79-348
We assessed the abilities of wild p53 and mutant p53 proteins to interact with the consensus DNA-binding sequence using a MOSFET biosensor. This is the first report in which mutant p53 has been detected on the basis of DNA-protein interaction using a FET-type biosensor. In an effort to evaluate the performance of this protocol, we constructed the core domain of wild p53 and mutant p53 (R248W), which is DNA-binding-defective. After the immobilization of the cognate DNA to the sensing layer, wild p53 and mutant p53 were applied to the DNA-coated gate surface, and subsequently analyzed using a semiconductor analyzer. As a consequence, a significant up-shift in drain current was noted in response to wild p53, but not mutant p53, thereby indicating that sequence-specific DNA-protein interactions could be successfully monitored using a field-effect-based biosensor. These data also corresponded to the results obtained using surface plasmon resonance (SPR) measurements. Taken together, our results show that a FET-type biosensor might be promising for the monitoring of mutant p53 on the basis of its DNA-binding activity, providing us with very valuable insights into the monitoring for diseases, particularly those associated with DNA-protein binding events. 相似文献
37.
Kang-Pil Kim Daeic Chang Sang Kyoo Lim Soo-Keun Lee Hong-Kun Lyu Dae-Kue Hwang 《Current Applied Physics》2011,11(6):1311-1314
In this study, UV photodetectors based on a network of aluminium-doped zinc oxide (AZO) nanowires were manufactured at a low cost; for this purpose, a fast and simple fabrication process that involved dropping nanowires dispersion solution was employed instead of the conventional e-beam lithography process that is used to manufacture single nanowire–based UV photodetectors. It was demonstrated that nanowire network–based UV photodetectors provide a much faster UV photoresponse than conventional single nanowire–based UV photodetectors. The fast UV photoresponse of the fabricated UV photodetector can be attributed to the fact that the potential barriers formed in the nanowire network junctions effectively block the flow of electrons during the process of photocurrent decay. Furthermore, the UV photoresponse under illumination by a 254 nm UV source was studied as a function of the annealing temperature of the AZO nanowires network at a bias of 5 V. The fabricated UV photodetector showed the fastest response of 2 s to UV illumination in air when the sample was annealed in air for 1 h at 300 °C. 相似文献
38.
Hong-Kun Zhang 《应用数学学报(英文版)》2011,27(3):381-392
Bunimovich billiards are ergodic and mixing. However, if the billiard table contains very large arcs on its boundary then if there exist trajectories experience infinitely many collisions in the vicinity of periodic trajectories on the large arc. The hyperbolicity is nonuniform and the mixing rate is very slow. The corresponding dynamics are intermittent between regular and chaotic, which makes them particularly interesting in physical studies. The study of mixing rates in intermittent chaotic systems is mo... 相似文献
39.
The reactivity of melezitose hydroxyls is studied during tritylation in pyridine. Some novel derivatives of melezitose are prepared. An acetyl is transferred from the 4- to the 6-position after detritylation of 3 and 4. The structures of the products are proved by elemental analysis;
1
H,
13
C, and
1
H-
1
H COSY NMR spectra;IR spectra; and fast-atom bombardment mass spectrometry. 相似文献
40.
Tienhsiung Ku Peiyu Lu Chenhsiung Chan Tsusheng Wang Szuming Lai Pingchiang Lyu Naiwan Hsiao 《Computational Biology and Chemistry》2009,33(6):445-450
Proteins of both hyperthermophilic and mesophilic microorganisms generally constitute from the same 20 amino acids; however, the extent of thermal tolerance of any given protein is an inherent property of its amino acid sequence. The present study is the first to report a rapid method for predicting Tm (melting temperature), the temperature at which 50% of the protein is unfolded, directly from protein sequences (the Tm Index program is available at http://tm.life.nthu.edu.tw/). We examined 75 complete microbial genomes using the Tm Index, and the analysis clearly differentiated hyperthermophilic from mesophilic microorganisms on this global genomic basis. These results are consistent with the previous hypothesis that hyperthermophiles express a greater number of high Tm proteins compared with mesophiles. The Tm Index will be valuable for modifying existing proteins (enzymes, protein drugs and vaccines) or designing novel proteins having a desired melting temperature. 相似文献