全文获取类型
收费全文 | 17981篇 |
免费 | 2438篇 |
国内免费 | 2874篇 |
专业分类
化学 | 14210篇 |
晶体学 | 282篇 |
力学 | 755篇 |
综合类 | 264篇 |
数学 | 1967篇 |
物理学 | 5815篇 |
出版年
2024年 | 32篇 |
2023年 | 170篇 |
2022年 | 414篇 |
2021年 | 450篇 |
2020年 | 483篇 |
2019年 | 543篇 |
2018年 | 454篇 |
2017年 | 416篇 |
2016年 | 708篇 |
2015年 | 773篇 |
2014年 | 928篇 |
2013年 | 1311篇 |
2012年 | 1468篇 |
2011年 | 1512篇 |
2010年 | 1161篇 |
2009年 | 1125篇 |
2008年 | 1384篇 |
2007年 | 1272篇 |
2006年 | 1160篇 |
2005年 | 971篇 |
2004年 | 914篇 |
2003年 | 826篇 |
2002年 | 925篇 |
2001年 | 740篇 |
2000年 | 570篇 |
1999年 | 441篇 |
1998年 | 277篇 |
1997年 | 284篇 |
1996年 | 235篇 |
1995年 | 209篇 |
1994年 | 185篇 |
1993年 | 174篇 |
1992年 | 159篇 |
1991年 | 113篇 |
1990年 | 104篇 |
1989年 | 87篇 |
1988年 | 50篇 |
1987年 | 52篇 |
1986年 | 41篇 |
1985年 | 36篇 |
1984年 | 26篇 |
1983年 | 18篇 |
1982年 | 12篇 |
1981年 | 14篇 |
1980年 | 10篇 |
1978年 | 11篇 |
1977年 | 7篇 |
1976年 | 8篇 |
1974年 | 5篇 |
1973年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
Kuan‐Wei Lee Hong‐Cheu Lin 《Journal of polymer science. Part A, Polymer chemistry》2007,45(20):4564-4572
A series of new liquid crystalline homopolymers, copolymers, and block copolymers were polymerized from styrene‐macroinitiator ( SMi ) and methacrylates with pendent 4,4′‐bis(biphenyl)fluorene ( M1 ) and biphenyl‐4‐ylfluorene ( M2 ) groups through atom transfer radical polymerization (ATRP). The number‐average molecular weights (Mn) of polymers P1 ‐ P4 were 10,007, 14,852, 6,275, and 10,463 g mol?1 with polydispersity indices values of 1.21, 1.15, 1.31, and 1.22, respectively. All polymers exhibit the nematic phase. The thermal, mesogenic, and photoluminescent properties of all polymers were investigated. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4564–4572, 2007 相似文献
92.
93.
讨论了W12[a,b]能否扩大为含有有间断点函数的再生核空间的问题.结论是:若再生核空间W W12[a,b]含有有间断点的函数,则间断点必固定、间断点个数必有限且非端点a,b.进一步,我们构造了函数含有n个间断点的再生核空间并给出其再生核表达式. 相似文献
94.
无机纳米粒子作为生物探针在生物分析中的研究进展 总被引:3,自引:0,他引:3
介绍了无机纳米粒子在生物分析领域的研究进展分别从生物分子与纳米粒子的耦联方式、检测生物分子的纳米金探针、核酸或蛋白质修饰的其它纳米探针以及生物纳米技术的应用前景4个方面对该领域的发展进行了概述。 相似文献
95.
数量级在物理实验中的应用 总被引:2,自引:0,他引:2
介绍了数量级在物理实验设计、实验失败原因分析、误差分析及实验结果判断方面的应用. 相似文献
96.
Supramolecular side chain liquid crystalline polymers (SCLCPs) based on poly(3-carboxypropylmethylsiloxane-co-dimethylsiloxane) (PSIX, X=100, 76, 60, 41 or 23, denoting the mole percentage of 3-carboxypropylmethylsiloxane unit in the polymer) and stilbazole derivatives have been obtained through intermolecular hydrogen bonding (H-bonding) interactions between the carboxylic acid and the pyridyl moieties. The formation of H-bonding and self-assembly results in the formation of new mesogenic units, in which H-bonds function as molecular connectors. FTIR shows the existence of H-bonding in the complexes. The polymeric complexes behave as single component liquid crystalline polymers and exhibit stable and enantiotropic mesophases. The liquid crystalline properties of the supramolecular SCLCPs were studied using differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction, and were found to exhibit smectic A phases with focal-conic textures. The thermal stability of the SCLCP increases on increasing the carboxylic acid content in the polysiloxane and the concentration of the stilbazole derivative in the complex. However, the thermal stability decreases on increasing the chain length of the stilbazole derivative. The crystal phase was not formed even on cooling to the glass transition temperature of the polymeric complex. 相似文献
97.
98.
Wei Hong Jinxiong Zhou Zhigang Suo 《Journal of the mechanics and physics of solids》2008,56(5):1779-1793
A large quantity of small molecules may migrate into a network of long polymers, causing the network to swell, forming an aggregate known as a polymeric gel. This paper formulates a theory of the coupled mass transport and large deformation. The free energy of the gel results from two molecular processes: stretching the network and mixing the network with the small molecules. Both the small molecules and the long polymers are taken to be incompressible, a constraint that we enforce by using a Lagrange multiplier, which coincides with the osmosis pressure or the swelling stress. The gel can undergo large deformation of two modes. The first mode results from the fast process of local rearrangement of molecules, allowing the gel to change shape but not volume. The second mode results from the slow process of long-range migration of the small molecules, allowing the gel to change both shape and volume. We assume that the local rearrangement is instantaneous, and model the long-range migration by assuming that the small molecules diffuse inside the gel. The theory is illustrated with a layer of a gel constrained in its plane and subject to a weight in the normal direction. We also predict the scaling behavior of a gel under a conical indenter. 相似文献
99.
Y. S. Hong K. C. Kim V. I. Volkov V. D. Skirda C. -H. Lee 《Applied magnetic resonance》2005,29(2):351-361
The diffusion phenomenon of a nonionic surfactant, polyoxyethylene sorbitan monooleate (POE-SMO), micelle in aqueous solution
was investigated by pulsed field gradient nuclear magnetic resonance (PFG NMR) with a high gradient strength of 17.4 T/m at
the diffusion timet
d varied from 3 to 300 ms. This high gradient strength allowed us to measure the slow self-diffusion coefficient of POE-SMO
micelle, and the short diffusion time below 10 ms showed the restricted diffusion of the micelle. At the shortt
d the self-diffusion of the micelle was restricted and the restricted sizes were 1.8, 1.5, and 0.8 μm for the POE-SMO concentration
of 100, 200 and 300 mM, respectively, and 0.6 μm for the POE-SMO only. The possible reason of this restriction was assumed
to be the formation of a spatial network or a micellar clustering. Furthermore, a proton exchange between water molecule and
surfactant OH group on the micelle surface was proposed. With respect to this proposal, the residence time of the proton at
the micelle surface and the thickness of the surface were investigated from proton self-diffusion coefficients by PFG NMR. 相似文献
100.
A novel algorithm, alternatively minimizing coupled vector (COV) resolution error and PARAFAC error algorithm, is proposed in this paper. This algorithm can overcome the problem of slow convergence and is insensitive to the estimation of component number, such problems are unavoidable while using the traditional parallel factors analysis (PARAFAC) algorithm. In other words, this algorithm is capable of improving the computing speed and providing accurate resolutions provided that the number of factors used in the computation is no less than that of the actual underlying ones. The characteristic performances were demonstrated with a novel fluorescence data array. 相似文献