全文获取类型
收费全文 | 28852篇 |
免费 | 4466篇 |
国内免费 | 4168篇 |
专业分类
化学 | 21669篇 |
晶体学 | 437篇 |
力学 | 1527篇 |
综合类 | 359篇 |
数学 | 3203篇 |
物理学 | 10291篇 |
出版年
2024年 | 34篇 |
2023年 | 416篇 |
2022年 | 643篇 |
2021年 | 884篇 |
2020年 | 941篇 |
2019年 | 1020篇 |
2018年 | 838篇 |
2017年 | 769篇 |
2016年 | 1277篇 |
2015年 | 1289篇 |
2014年 | 1554篇 |
2013年 | 2081篇 |
2012年 | 2485篇 |
2011年 | 2518篇 |
2010年 | 1940篇 |
2009年 | 1845篇 |
2008年 | 2081篇 |
2007年 | 1891篇 |
2006年 | 1783篇 |
2005年 | 1521篇 |
2004年 | 1273篇 |
2003年 | 1127篇 |
2002年 | 1225篇 |
2001年 | 963篇 |
2000年 | 775篇 |
1999年 | 641篇 |
1998年 | 451篇 |
1997年 | 483篇 |
1996年 | 412篇 |
1995年 | 368篇 |
1994年 | 320篇 |
1993年 | 269篇 |
1992年 | 245篇 |
1991年 | 190篇 |
1990年 | 181篇 |
1989年 | 155篇 |
1988年 | 102篇 |
1987年 | 81篇 |
1986年 | 85篇 |
1985年 | 68篇 |
1984年 | 44篇 |
1983年 | 32篇 |
1982年 | 27篇 |
1981年 | 21篇 |
1980年 | 19篇 |
1978年 | 14篇 |
1976年 | 9篇 |
1975年 | 12篇 |
1973年 | 11篇 |
1972年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 296 毫秒
101.
Qiu Hong WU He Xiang WANG Kun GAO State Key Laboratory of Applied Organic Chemistry College of Chemistry Chemical Engineering Lanzhou University Lanzhou 《中国化学快报》2006,17(2)
Many Ligularia species have long been used as traditional folk medicine for theirantibiotic, antiphlogistic and antitussive activities1, and were found to be an importantsource of eremophilane. In the course of our search for bioactive sesquiterpenoids, w… 相似文献
102.
连通图的离散度是用s(G)来表示的,s(G)=max{ω(G-S)-|S|:ω(G-S)>1,SV(G)}.给出了两个完全图乘积的和一个完全图与路的乘积的离散度.还给出了两个完全图乘积的坚韧度. 相似文献
103.
Yong LU Hong WANG Ye LIU Ming Yuan HE 《中国化学快报》2006,17(10):1397-1400
Recently, miniature H2 generator to power fuel cells for portable/micro electronic devices and passenger propulsion has been the focus of intense research activities1-3. One of the strategies is to find simple CO-free H2 production with novel microreactor… 相似文献
104.
Methods to synthesize magnetic Fe3O4 nanoparticles and to modify the surface of particles are presented in the present investigation. Fe3O4 magnetic nanoparticles were prepared by the co-precipitation of Fe3+ and Fe2+, NH3·H2O was used as the precipitating agent to adjust the pH value, and the aging of Fe3O4 magnetic nanoparticles was accelerated by microwave (MW) irradiation. The obtained Fe3O4 magnetic nanoparticles were characterized by Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), X-ray powder diffraction (XRD) and vibrating sample magnetometer (VSM). The average size of Fe3O4 crystallites was found to be around 8–9 nm. Thereafter, the surface of Fe3O4 magnetic nanoparticles was modified by stearic acid. The resultant sample was characterized by FT-IR, scanning electron microscopy (SEM), XRD, lipophilic degree (LD) and sedimentation test. The FT-IR results indicated that a covalent bond was formed by chemical reaction between the hydroxyl groups on the surface of Fe3O4 nanoparticles and carboxyl groups of stearic acid, which changed the polarity of Fe3O4 nanoparticles. The dispersion of Fe3O4 in organic solvent was greatly improved. Effects of reaction time, reaction temperature and concentration of stearic acid on particle surface modification were investigated. In addition, Fe3O4/polystyrene (PS) nanocomposite was synthesized by adding surface modified Fe3O4 magnetic nanoparticles into styrene monomer, followed by the radical polymerization. The obtained nanocomposite was tested by thermogravimetry (TG), differential scanning calorimetry (DSC) and XRD. Results revealed that the thermal stability of PS was not significantly changed after adding Fe3O4 nanoparticles. The Fe3O4 magnetic fluid was characterized using UV–vis spectrophotometer, Gouy magnetic balance and laser particle-size analyzer. The testing results showed that the magnetic fluid had excellent stability, and had susceptibility of 4.46×10−8 and saturated magnetization of 6.56 emu/g. In addition, the mean size d (0.99) of magnetic Fe3O4 nanoparticles in the fluid was 36.19 nm. 相似文献
105.
A nanoscale
multivalent platinum drug based on a poly(amidoamine) [PAMAM] dendrimer (generation
4.5, carboxylate surface) has been synthesized and fully characterized using
a variety of spectroscopic, chromatographic and thermal methods. Treatment
of the dendrimer with an aqueous solution containing an excess diaquo(cis-1,2-diaminocyclohexane)platinum(II) produces
a conjugate containing approximately forty (diaminocyclohexane)platinum(II)
moieties at the surface of the dendrimer. This material undergoes smooth two-stage
thermal decomposition to provide residual platinum oxide reflecting the platinum
loading in the drug. 相似文献
106.
On Polynomial Functions over Finite Commutative Rings 总被引:1,自引:0,他引:1
Jian Jun JIANG Guo Hua PENG Qi SUN Qi Fan ZHANG 《数学学报(英文版)》2006,22(4):1047-1050
Let R be an arbitrary finite commutative local ring. In this paper, we obtain a necessary and sufficient condition for a function over R to be a polynomial function. Before this paper, necessary and sufficient conditions for a function to be a polynomial function over some special finite commutative local rings were obtained. 相似文献
107.
Kimin Hong Jungju Lee Jinhan Lee Young-Dong Ko Jin-Seok Chung Jin-Gyu Kim 《Journal of magnetism and magnetic materials》2006
We investigated the change of magnetic properties of the electroplated Cu/Co alloys and multilayers caused by organic additives and high temperature annealing. When plated with a pure Cu/Co electrolyte, the alloy contained ∼25% of Cu and ∼75% of Co. The alloy was made of hcp-Co, fcc-Co and Cu(1 1 1) and was super-paramagnetic at room temperature. As we add a few organic additives in the plating electrolyte, the hcp-Co of the films disappeared. The organic additives contained in the electrolytes changed paramagnetic Cu/Co multilayers to ferromagnets. High-temperature thermal annealing increased coercivity due to the growth of the Co grains. 相似文献
108.
A Bayesian approach is used to analyze the seismic events with magnitudes at least 4.7 on Taiwan. Following the idea proposed
by Ogata (1988,Journal of the American Statistical Association,83, 9–27), an epidemic model for the process of occurrence times given the observed magnitude values is considered, incorporated
with gamma prior distributions for the parameters in the model, while the hyper-parameters of the prior are essentially determined
by the seismic data in an earlier period. Bayesian inference is made on the conditional intensity function via Markov chain
Monte Carlo method. The results yield acceptable accuracies in predicting large earthquake events within short time periods. 相似文献
109.
This paper has demonstrated that the Schwartz alternating process must converge if D-N alternating process has converged. Its technique is that the overlapping regions in Schwartz alternating process are considered as independent domains, then Schwartz alternating process could be transformed into D-N alter-nating process. Finally the convergence estimation of Schwartz alternating process could be obtained. The results show that its convergence rate is same as that of D-N alternating process. 相似文献
110.