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排序方式: 共有238条查询结果,搜索用时 31 毫秒
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42.
Zhao X Outlaw RA Wang JJ Zhu MY Smith GD Holloway BC 《The Journal of chemical physics》2006,124(19):194704
Carbon nanosheets are a unique nanostructure that, at their thinnest configuration, approach a single freestanding graphene sheet. Temperature desorption spectroscopy (TDS) has shown that the hydrogen adsorption and incorporation during growth of the nanosheets by radio frequency plasma-enhanced chemical vapor deposition are significant. A numerical peak fitting to the desorption spectra (300-1273 K) via the Polanyi-Wigner equation showed that desorption followed a second order process, presumably by the Langmuir-Hinshelwood mechanism. Six peaks provide the best fit to the TDS spectra. Surface desorption activation energies were determined to be 0.59, 0.63, and 0.65 eV for the external graphite surface layers and 0.85, 1.15, and 1.73 eV for desorption and diffusion from the bulk. In contrast to TDS data from previously studied a-C:H films [Schenk et al. J. Appl. Phys. 77, 2462 (1995)], a greater amount of hydrogen bound as sp(2) hybridized carbon was observed. A previous x-ray diffraction study of these films has shown a significant graphitic character with a crystallite dimension of L(a)=10.7 nm. This result is consistent with experimental results by Raman spectroscopy that show as-grown carbon nanosheets to be crystalline as commercial graphite with a crystallite size of L(a)=11 nm. Following TDS, Raman data indicate that the average crystallite increased in size to L(a)=15 nm. 相似文献
43.
为实现三维光存储中折射率失配引起的球差补偿,建立了光学存储系统模型,获得了折射率失配引起的波前偏差函数与存储深度的表达式.采用泽尔尼克循环多项式对波前偏差函数进行补偿展开.在双光子荧光和单光子共焦荧光读出方式下,均可获得读出荧光强度与存储深度的关系:在折射率失配引起的球差未得到补偿矫正的情况下,存储深度在200 μm左右读出荧光强度基本上下降为零;当折射率失配引起的初级球差被补偿矫正后,读出荧光强度随存储深度的下降得到较好改善;当折射率失配引起的二级球差被补偿矫正后,存储深度在1 mm内存储点强度随深度基本上没有明显地变化.并且对像差补偿方法进行了具体地分析. 相似文献
44.
We study the deformation, spreading, and fingering of small droplets of a yield-stress fluid subjected to a centrifugal force
on a rotating substrate. At low rotation rates and for small enough droplets, the droplets deform elastically but retain their
essentially circular contact line. For large enough droplet volumes and rotation speeds, however, one or more fingers eventually
form and grow at the edge of the drop. This fingering is qualitatively different from the contact line instability observed
in other fluids, and appears to be a localized phenomenon that occurs when the stress at some point on the perimeter of the
drop exceeds the yield stress. 相似文献
45.
用分子动力学方法和不同参数的指数 6势函数计算了T =30 4K的高密度氦的等温压缩线和能量分布 .给出了能精确描述高密度氦原子间相互作用的指数 6势函数优化参数 .并用优化的势函数计算了高密度氦T =30 0K和T =2 98K的等温压缩线 ,计算结果和实验值非常吻合 .进一步用优化的势函数模拟了高温高密度氦的状态方程及其结构 ,发现当把 ρ限定为 1 .6 0g /cm3 时 ,其径向分布函数的第 2个峰将在 2 0 0 0~ 30 40K区间消失 ,表明此时发生了固 液相变过程 . 相似文献
46.
硅基材料是新一代高容量锂离子蓄电池负极材料的典型代表,近年来已成为理论研究和应用研究的热点.本文介绍了锂离子电池硅基负极材料的制备方法、电化学性能及其研究现状,分析了硅材料作为锂离子电池负极材料存在的问题;讨论了硅材料作为锂离子电池负极材料的研究前景.并指出若能克服目前存在问题,将有望成为新一代锂离子电池负极材料. 相似文献
47.
The enthalpy of hydrolysis of solid tungsten thiotetrafluoride, WF(in4)S, in aqueous sodium hydroxide solution is -528.2 kJ mo1-1. Hence its standard enthalpy of formation has been calculated to be -1150.5 kJ mo1-1. 相似文献
48.
On the lamb solution and Rayleigh-wave-induced cracking 总被引:1,自引:0,他引:1
This paper examines the extension of surface microcracks induced by a surface or Rayleigh wave (R-wave). This problem is examined
both theoretically and experimentally. The theoretical approach involves a full-field reappraisal of the Lamb solution for
a surface wave propagating in a homogeneous, isotropic, elastic, two-dimensional material for the cases of plane strain and
plane stress. Using the Griffith-Irwin energy-release-rate fracture criterion for cracks under combined Mode I and Mode II
loading, a prediction is made of the path and final length of the surface microcrack extension produced by the R-wave. Predictions
of the crack-extension direction are also obtained using the maximum normal-stress fracture criterion. The experimental approach
uses dynamic photoelasticity to observe the isochromatic patterns associated with an R-wave propagating along the narrow edge
of a transparent birefringent plate, examining in detail the process of crack extension. When the theoretically and experimentally
obtained results are compared, reasonable agreement is obtained. 相似文献
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