全文获取类型
收费全文 | 528065篇 |
免费 | 4727篇 |
国内免费 | 1281篇 |
专业分类
化学 | 269053篇 |
晶体学 | 7645篇 |
力学 | 25996篇 |
综合类 | 17篇 |
数学 | 67784篇 |
物理学 | 163578篇 |
出版年
2021年 | 5031篇 |
2020年 | 5477篇 |
2019年 | 6221篇 |
2018年 | 8413篇 |
2017年 | 8560篇 |
2016年 | 11626篇 |
2015年 | 6178篇 |
2014年 | 10438篇 |
2013年 | 23485篇 |
2012年 | 18335篇 |
2011年 | 21789篇 |
2010年 | 16420篇 |
2009年 | 16281篇 |
2008年 | 20659篇 |
2007年 | 20508篇 |
2006年 | 18612篇 |
2005年 | 16620篇 |
2004年 | 15469篇 |
2003年 | 13956篇 |
2002年 | 13848篇 |
2001年 | 14732篇 |
2000年 | 11343篇 |
1999年 | 8752篇 |
1998年 | 7602篇 |
1997年 | 7471篇 |
1996年 | 6928篇 |
1995年 | 6257篇 |
1994年 | 6264篇 |
1993年 | 6017篇 |
1992年 | 6376篇 |
1991年 | 6865篇 |
1990年 | 6577篇 |
1989年 | 6486篇 |
1988年 | 6321篇 |
1987年 | 6134篇 |
1986年 | 5871篇 |
1985年 | 7408篇 |
1984年 | 7769篇 |
1983年 | 6532篇 |
1982年 | 6817篇 |
1981年 | 6326篇 |
1980年 | 6003篇 |
1979年 | 6504篇 |
1978年 | 6741篇 |
1977年 | 6631篇 |
1976年 | 6586篇 |
1975年 | 6304篇 |
1974年 | 6129篇 |
1973年 | 6424篇 |
1972年 | 4706篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
121.
122.
Romanenko G. V. Letyagin G. A. Maryunina K. Yu. Bogomyakov A. S. Nishihara S. Inoue K. Ovcharenko V. I. 《Russian Chemical Bulletin》2020,69(8):1530-1536
Russian Chemical Bulletin - The study is concerned with structural rearrangements in the crystals of heterospin complexes Cu(hfac)2 with nitroxide radicals LR (hfac is hexafluoroacetylacetonate, LR... 相似文献
123.
Amphiphilic block copolymer self‐assemblies of poly(NVP)‐b‐poly(MDO‐co‐vinyl esters): Tunable dimensions and functionalities 下载免费PDF全文
Guillaume G. Hedir A. Pitto‐Barry Andrew P. Dove Rachel K. O'Reilly 《Journal of polymer science. Part A, Polymer chemistry》2015,53(23):2699-2710
Functional, degradable polymers were synthesized via the copolymerization of vinyl acetate (VAc) and 2‐methylene‐1,3‐dioxepane (MDO) using a macro‐xanthate CTA, poly(N‐vinylpyrrolidone), resulting in the formation of amphiphilic block copolymers of poly(NVP)‐b‐poly(MDO‐co‐VAc). The behavior of the block copolymers in water was investigated and resulted in the formation of self‐assembled nanoparticles containing a hydrophobic core and a hydrophilic corona. The size of the resultant nanoparticles was able to be tuned with variation of the hydrophilic and hydrophobic segments of the core and corona by changing the incorporation of the macro‐CTA as well as the monomer composition in the copolymers, as observed by Dynamic Light Scattering, Static Light Scattering, and Transmission Electron Microscopy analyses. The concept was further applied to a VAc derivative monomer, vinyl bromobutanoate, to incorporate further functionalities such as fluorescent dithiomaleimide groups throughout the polymer backbone using azidation and “click” chemistry as postpolymerization tools to create fluorescently labeled nanoparticles. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2699–2710 相似文献
124.
L. Resse L.G.S. Oliveira C.I.L. de Araujo A.R. Pereira R.L. Silva 《Physics letters. A》2019,383(14):1655-1659
In this work, we have used the MuMax3 software to simulate devices consisting of a ferromagnetic thin film placed over a heavy metal thin film. The devices are two interconnected partial-disks where a Néel domain wall is formed in the disks junction. In our simulations we investigate devices with disk radius nm and different distance d between the disks centers (from nm to nm). By applying strong sinusoidal external magnetic fields, we find a mechanism able to create, annihilate and even manipulate a skyrmion in each side of the device. This mechanism is discussed in terms of interactions between skyrmion and domain wall. The Néel domain wall formed in the center of the device interacts with the Néel skyrmion, leading to a process of transporting a skyrmion from one disk to the other periodically. Our results have relevance for potential applications in spintronics such as logical devices. 相似文献
125.
126.
Journal of Experimental and Theoretical Physics - A systematic nonperturbative scheme for calculating the ground state energy is adapted for studying systems of strongly correlated electrons on a... 相似文献
127.
Archiv der Mathematik - A generalized Baumslag–Solitar group is a finitely generated group that acts on a tree with infinite cyclic edge and vertex stabilizers. A group G is residually a... 相似文献
128.
Ortiz Adolfo Yang Jianhua Coccolo Mattia Seoane Jesús M. Sanjuán Miguel A. F. 《Nonlinear dynamics》2020,102(4):2323-2337
Nonlinear Dynamics - The main purpose of this paper is to study both the underdamped and the overdamped dynamics of the nonlinear Helmholtz oscillator with a fractional-order damping. For that... 相似文献
129.
A zinc coordination polymer derived from pyridine-2,6-dicarboxylate (PDC), {[Zn2(PDC)2]}n, was successfully prepared via conventional, sonication and microwave-irradiation methods. The composition and characteristics of the obtained coordination polymers (CPs) were investigated by elemental analysis, TGA/DTA, X-ray diffraction and spectroscopic techniques. The so obtained CPs were heat-treated in the air at 600 °C for 2 h to produce ZnO of nanosized particles (NPs). It is of interest to note that the synthesis approach of the precursor greatly affects both the nanoparticle size and the structure of the resulting ZnO NPs. Moreover, the smallest particle size was associated with the sample derived from the ultrasonically prepared precursor. TEM analysis revealed that all samples have sphere-like morphologies. Structural analysis of the prepared ZnO samples was conducted and compared using Rietveld analysis of their PXRD patterns. Optical band gap calculations based on analysis of the UV–vis spectra of ZnO samples using Tauc's power law were achieved. The highest band gap of 3.63 eV was observed for ZnO sample obtained from the ultrasonically prepared precursor. Furthermore, the photocatalytic activity of ZnO NPs for the removal of Eosin Y color was monitored. The highest removal efficiency was recorded for ZnO originated from the ultrasonically synthesized precursor. Enhancement of removal efficiency that reached 98% was attained in only a period of 8 min. Its recycling test showed that it can be reused without structural changes over four cycling experiments. 相似文献
130.
Probing the Catalytic Activity of Reduced Graphene Oxide Decorated with Au Nanoparticles Triggered by Visible Light 下载免费PDF全文
Dr. Jiale Wang Dr. Fabiane J. Trindade Caroline B. de Aquino Joana C. Pieretti Prof. Dr. Sergio H. Domingues Prof. Dr. Romulo A. Ando Prof. Dr. Pedro H. C. Camargo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(27):9889-9894
Hybrid materials in which reduced graphene oxide (rGO) is decorated with Au nanoparticles (rGO–Au NPs) were obtained by the in situ reduction of GO and AuCl4?(aq) by ascorbic acid. On laser excitation, rGO could be oxidized as a result of the surface plasmon resonance (SPR) excitation in the Au NPs, which generates activated O2 through the transfer of SPR‐excited hot electrons to O2 molecules adsorbed from air. The SPR‐mediated catalytic oxidation of p‐aminothiophenol (PATP) to p,p′‐dimercaptoazobenzene (DMAB) was then employed as a model reaction to probe the effect of rGO as a support for Au NPs on their SPR‐mediated catalytic activities. The increased conversion of PATP to DMAB relative to individual Au NPs indicated that charge‐transfer processes from rGO to Au took place and contributed to improved SPR‐mediated activity. Since the transfer of electrons from Au to adsorbed O2 molecules is the crucial step for PATP oxidation, in addition to the SPR‐excited hot electrons of Au NPs, the transfer of electrons from rGO to Au contributed to increasing the electron density of Au above the Fermi level and thus the Au‐to‐O2 charge‐transfer process. 相似文献