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71.
3‐Alkyl/aryl‐3‐ureido‐1H,3H‐quinoline‐2,4‐diones ( 2 ) and 3a‐alkyl/aryl‐9b‐hydroxy‐3,3a,5,9b‐tetrahydro‐1H‐imidazo[4,5‐c]quinoline‐2,4‐diones ( 3 ) react in boiling concentrated HCl to give 5‐alkyl/aryl‐4‐(2‐aminophenyl)‐1,3‐dihydro‐2H‐imidazol‐2‐ones ( 6 ). The same compounds were prepared by the same procedure from 2‐alkyl/aryl‐3‐ureido‐1H‐indoles ( 4 ), which were obtained from the reaction of 3‐alkyl/aryl‐3‐aminoquinoline‐2,4(1H,3H)‐diones ( 1 ) with 1,3‐diphenylurea or by the transformation of 3a‐alkyl/aryl‐9b‐hydroxy‐3,3a,5,9b‐tetrahydro‐1H‐imidazo[4,5‐c]quinoline‐2,4‐diones ( 3 ) and 5‐alkyl/aryl‐4‐(2‐aminophenyl)‐1,3‐dihydro‐2H‐imidazol‐2‐ones ( 6 ) in boiling AcOH. The latter were converted into 1,3‐bis[2‐(2‐oxo‐2,3‐dihydro‐1H‐imidazol‐4‐yl)phenyl]ureas ( 5 ) by treatment with triphosgene. All compounds were characterized by 1H‐ and 13C‐NMR and IR spectroscopy, as well as atmospheric pressure chemical‐ionisation mass spectra. 相似文献
72.
V. Holý J. Kuběna W. W. van den Hoogenhof I. Vávra 《Applied Physics A: Materials Science & Processing》1995,60(1):93-96
The correlation of roughness profiles of different interfaces in a periodical multilayer affects the reciprocalspace distribution of the diffusely reflected X-ray intensity. This distribution has been calculated by means of the Distorted-Wave Born Approximation (DWBA) method and compared with the results of X-ray reflectometry on periodical metallic multilayers. It has been shown that the measurement of the reciprocal-space distribution of diffusely scattered intensity is a suitable non-destructive method to investigate the roughness replication in multilayers. 相似文献
73.
Petr Jansa Ondřej Hradil Ondřej Baszczyňski Martin Dračínský Blanka Klepetářová Antonín Holý Jan Balzarini Zlatko Janeba 《Tetrahedron》2012,68(3):865-871
Polysubstituted pyrimidinylphosphonic and 1,3,5-triazinylphosphonic acids with potential biological properties were prepared in high yields by the microwave-assisted Michaelis–Arbuzov reaction of trialkyl phosphite with the corresponding halopyrimidines and halo-1,3,5-triazines, respectively, followed by the standard deprotection of the phosphonate group using TMSBr in acetonitrile. 4,6-Diamino-5-chloropyrimidin-2-ylphosphonic acid (7a) was found to exhibit a weak to moderate anti-influenza activity (28–50 μM) and may represent a novel hit for further SAR studies and antiviral improvement. 相似文献
74.
The stability constants of the 1:1 complexes formed between Mg(2+), Ca(2+), Sr(2+), Ba(2+), Mn(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), or Cd(2+) (=M(2+)) and 1-methyl-4-aminobenzimidazole (MABI) or 1,4-dimethylbenzimidazole (DMBI) were determined by potentiometric pH titrations in aqueous solution (25 degrees C; I = 0.5 M, NaNO(3)). Some of the stability constants were also measured by UV spectrophotometry. The acidity constants of the species H(2)(MABI)(2+) and H(DMBI)(+) were determined by the same methods, some twice. Comparison of the stability constants of the M(MABI)(2+) and M(DMBI)(2+) complexes with those calculated from log versus p straight-line plots, which were established previously for sterically unhindered benzimidazole-type ligands (=L), reveals that the stabilities of the M(MABI)(2+) and M(DMBI)(2+) complexes are significantly reduced due to steric effects of the C4 substituents on metal ion binding at N3. This effect is more pronounced in the M(DMBI)(2+) complexes. Considering the steric equivalence of methyl and (noncoordinating) amino groups (as they occur in adenines), it is concluded that the same extent of steric inhibition by the (C6)NH(2) group is to be expected on metal ion binding at N7 with adenine derivatives. The basicity of the amino group in MABI is significantly higher than in its corresponding adenine derivative. Indeed, it is concluded that in the M(MABI)(2+) complexes chelate formation involving the amino group occurs to some extent. The formation degrees of these "closed" species are calculated; they vary for the complexes of Mn(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), or Cd(2+) between about 50 and 90%. The stability of the M(MABI)(2+) and M(DMBI)(2+) complexes with the alkaline earth ions is very low but unaffected by the C4 substituent; this probably indicates that in these instances outersphere complexes (with a water molecule between N3 and the metal ion) are formed. 相似文献
75.
We give interesting characterizations using subcontinuity. Let X, Y be topological spaces. We study subcontinuity of multifunctions from X to Y and its relations to local compactness, local total boundedness and upper semicontinuity. If Y is regular, then F is subcontinuous iff [`(F)]\bar F is USCO. A uniform space Y is complete iff for every topological space X and for every net {F
a
}, F
a
⊂ X × Y, of multifunctions subcontinuous at x ∈ X, uniformly convergent to F, F is subcontinuous at x. A Tychonoff space Y is Čech-complete (resp. G
m-space) iff for every topological space X and every multifunction F ⊂ X × Y the set of points of subcontinuity of F is a G
δ
-subset (resp. G
m-subset) of X. 相似文献
76.
Populations are shaped by the spatial structure of their environment: space organizes interactions between individuals locally, and gives rise to a global population structure. Both local and global population structures can have a profound influence on the evolutionary dynamics of a population. To characterize this influence, we use genetic algorithms with several distinct contact structures to evolve cellular automata, which perform a density classification task. We find that local contact structures (modeled as graphs with various topologies) that limit the number of breeding partners show greater evolvability than well‐mixed populations. Furthermore, we show that the evolvability of well‐mixed populations is enhanced in a metapopulation setting of coupled subpopulations. © 2012 Wiley Periodicals, Inc. Complexity, 2012 相似文献
77.
78.
CZE has been applied for determination of acid-base dissociation constants (pKa) of ionogenic groups of newly synthesized amino- and (amino)guanidinopurine nucleotide analogs, such as acyclic nucleoside phosphonate, acyclic nucleoside phosphonate diesters and other related compounds. These compounds bear characteristic pharmacophores contained in various important biologically active substances, such as cytostatics and antivirals. The pKa values of ionogenic groups of the above compounds were determined by nonlinear regression analysis of the experimentally measured pH dependence of their effective electrophoretic mobilities. The effective mobilities were measured by CZE performed in series of BGEs in a broad pH range (3.50-11.25), at constant ionic strength (25 mM) and temperature (25 degrees C). pKa values were determined for the protonated guanidinyl group in (amino)guanidino 9-alkylpurines and in (amino)guanidinopurine nucleotide analogs, such as acyclic nucleoside phosphonates and acyclic nucleoside phosphonate diesters, for phosphonic acid to the second dissociation degree (-2) in acyclic nucleoside phosphonates of amino and (amino)guanidino 9-alkylpurines, and for protonated nitrogen in position 1 (N1) of purine moiety in acyclic nucleoside phosphonates of amino 9-alkylpurines. Thermodynamic pKa of protonated guanidinyl group was estimated to be in the range of 7.75-10.32, pKa of phosphonic acid to the second dissociation degree achieved values of 6.64-7.46, and pKa of protonated nitrogen in position 1 of purine was in the range of 4.13-4.89, depending on the structure of the analyzed compounds. 相似文献
79.
Continuum simulations of self-organized lateral compositional modulation growth in InAs/AlAs short-period superlattices on InP substrate are presented. The results of the simulations correspond quantitatively to the results of synchrotron x-ray diffraction experiments. The time evolution of the compositional modulation during epitaxial growth can be explained only including a nonlinear dependence of the elastic energy of the growing epitaxial layer on its thickness. From the fit of the experimental data to the growth simulations we have determined the parameters of this nonlinear dependence. It was found that the modulation amplitude does not depend on the values of the surface diffusion constants of particular elements. 相似文献
80.
K. Holý R. Bohm A. Polášková J. Štelina O. Holá I. Sýkora 《Journal of Radioanalytical and Nuclear Chemistry》1996,209(2):315-323
Simultaneous measurements of the222Rn concentration in the outdoor atmosphere of Bratislava and in the soil air over one year period have been made. Daily and seasonal variations of the222Rn concentration in both media were found. Some attributes of these variations as well as methods of measurements are presented in this work. 相似文献