Precision angle sensor using an optical lever inside a Sagnac interferometer

We built an ultra-low-noise angle sensor by combining a folded optical lever and a Sagnac interferometer. The instrument has a measured noise floor of 1.3 prad/√Hz at 2.4 kHz. We achieve this record angle sensitivity using a proof-of-concept apparatus with a conservative N=11 bounces in the optical lever. This technique could be extended to reach subpicoradian/√Hz sensitivities with an optimized design.     

An atomic gravitational wave interferometric sensor in low earth orbit (AGIS-LEO)

We propose an atom interferometer gravitational wave detector in low Earth orbit (AGIS-LEO). Gravitational waves can be observed by comparing a pair of atom interferometers separated by a 30 km baseline. In the proposed configuration, one or three of these interferometer pairs are simultaneously operated through the use of two or three satellites in formation flight. The three satellite configuration allows for the increased suppression of multiple noise sources and for the detection of stochastic gravitational wave signals. The mission will offer a strain sensitivity of ${<10^{-18}/\sqrt{{\rm Hz}}}$ in the 50mHz?C10Hz frequency range, providing access to a rich scientific region with substantial discovery potential. This band is not currently addressed with the LIGO, VIRGO, or LISA instruments. We analyze systematic backgrounds that are relevant to the mission and discuss how they can be mitigated at the required levels. Some of these effects do not appear to have been considered previously in the context of atom interferometry, and we therefore expect that our analysis will be broadly relevant to atom interferometric precision measurements. Finally, we present a brief conceptual overview of shorter-baseline $({\lesssim100\,{\rm m}})$ atom interferometer configurations that could be deployed as proof-of-principle instruments on the International Space Station (AGIS-ISS) or an independent satellite.     

Novel affinity ligands for chromatography using combinatorial chemistry

Spatially addressable combinatorial libraries were synthesized by solution phase chemistry and screened for binding to human serum albumin. Members of arylidene diamide libraries were among the best hits found, having submicromolar binding affinities. The results were analyzed by the frequency with which particular substituents appeared among the most potent compounds. After immobilization of the ligands either through the oxazolone or the amine substituent, characterization by surface plasmon resonance showed that ibuprofen affected the binding kinetics, but phenylbutazone did not. It is therefore likely that these compounds bind to Site 2 in sub domain IIIA of human serum albumin (HSA).     

Facile Tuning of Luminescent Platinum(II) Schiff Base Complexes from Yellow to Near‐Infrared: Photophysics,Electrochemistry, Electrochemiluminescence and Theoretical Calculations

The photophysical and related properties of platinum(II) Schiff base complexes can be finely and predictably tuned over a wide range of wavelengths by small and easily implemented changes to ligand structure. A series of such complexes, differing only in the number and positioning of methoxy substituents on the phenoxy ring, were synthesised and their photophysical, electrochemical and electrochemiluminescent (ECL) properties investigated. Theoretical calculations were performed in order to gain further insight into the relationship between structure and properties in these materials. By positioning methoxy groups para and/or ortho to either the imine or the oxygen group on the ligand, electron density could be directed selectively toward the LUMO or HOMO as required. This allowed the emission colour (both photoluminescent and electrochemiluminescent) to be tuned over a wide range between 587 and 739 nm. The variation in orbital energies was also manifested in the positions of the absorption bands and the redox properties of the complexes, as well as in the NMR shifts for the uncoordinated ligands. All reported complexes displayed intense electrochemiluminescence (ECL), which could be initiated either by annihilation or co‐reactant pathways. The relationship between the electrochemical and photophysical properties and the efficiency of the ECL is discussed. For two of the complexes solid‐state ECL could be generated from electrodeposited layers of the complex.     

History of Polyolefins

The history of polyolefins actually began in the 1890s with the synthesis of polymethylene from diazomethane. In the 1930s researchers in England discovered that ethylene at high pressure and in the presence of oxygen polymerized to a high molecular weight resin. Further research there and in the United States at still higher pressures yielded essentially straight chain, higher density polyethylenes. Early in the 1950s, groups in the United States and Europe independently discovered that linear, high-density polyethylenes could be made at low pressure over heterogeneous catalysts. Concurrently, groups catalytically produced polyolefin plastics from propylene and higher a-olefins. The inventorship of crystalline polypropylene was awarded to Phillips Petroleum Co. by United States courts in early 1980 (subject to final appeal). Commercial production of low-density polyethylene began in England (ICI) in 1939. High-pressure plants appeared in the United States (Du Pont and Union Carbide) and in Germany during World War II. Production of linear polyethylene started in late 1956 in the United States (Phillips). A semiworks Koppers plant began polyethylene production for commercial use earlier in 1956. Other plants quickly followed suit, using Phillips and Ziegler processes. Polypropylene production began in Europe and in the United States in 1957-1958. Two other polyolefin plastics have been produced in small commercial quantities, starting about 1965: poly(4-methyl-l-pentene) and poly-1-butene.     

Breakdown limits on Gigavolt-per-meter electron-beam-driven wakefields in dielectric structures

First measurements of the breakdown threshold in a dielectric subjected to GV/m wakefields produced by short (30-330 fs), 28.5 GeV electron bunches have been made. Fused silica tubes of 100 microm inner diameter were exposed to a range of bunch lengths, allowing surface dielectric fields up to 27 GV/m to be generated. The onset of breakdown, detected through light emission from the tube ends, is observed to occur when the peak electric field at the dielectric surface reaches 13.8+/-0.7 GV/m. The correlation of structure damage to beam-induced breakdown is established using an array of postexposure inspection techniques.     

Halo formation and emittance growth of positron beams in plasmas

An ultrarelativistic 28.5 GeV, 700-microm-long positron bunch is focused near the entrance of a 1.4-m-long plasma with a density n(e) between approximately equal to 10(13) and approximately equal to 5 x 10(14) cm(-3). Partial neutralization of the bunch space charge by the mobile plasma electrons results in a reduction in transverse size by a factor of approximately equal to 3 in the high emittance plane of the beam approximately equal to 1 m downstream from the plasma exit. As n(e) increases, the formation of a beam halo containing approximately 40% of the total charge is observed, indicating that the plasma focusing force is nonlinear. Numerical simulations confirm these observations. The bunch with an incoming transverse size ratio of approximately 3 and emittance ratio of approximately 5 suffers emittance growth and exits the plasma with approximately equal sizes and emittances.     

N-Heterocyclic Olefins on a Silicon Surface

The adsorption of N-heterocyclic olefins (NHOs) on silicon is investigated in a combined scanning tunneling microscopy, X-ray photoelectron spectroscopy, and density functional theory study. We find that both of the studied NHOs bind covalently, with ylidic character, to the silicon adatoms of the substrate and exhibit good thermal stability. The adsorption geometry strongly depends on the N-substituents: for large N-substituents, an upright adsorption geometry is favored, while a flat-lying geometry is found for the NHO with smaller wingtips. These different geometries strongly influence the quality and properties of the obtained monolayers. The upright geometry leads to the formation of ordered monolayers, whereas the flat-lying NHOs yield a mostly disordered, but denser, monolayer. The obtained monolayers both show large work function reductions, as the higher density of the flat-lying monolayer is found to compensate for the smaller vertical dipole moments. Our findings offer new prospects in the design of tailor-made ligand structures in organic electronics and optoelectronics, catalysis, and material science.