Synthesis of 8-arylated catechin and epicatechin derivatives via Suzuki cross-coupling

8-Arylated catechin and epicatechin derivatives have been prepared in good to excellent yields via Suzuki cross-coupling in the presence of Pd₂(dba)₃ as the Pd(0) source and Sphos as the phosphine ligand.     

Bestimmung von Butylhydroxytoluol (BHT) in Mischfuttermitteln mittels HPLC

Ohne Zusammenfassung

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Determination of butylated hydroxytoluene (BHT) in mixed feed by means of HPLC

     

Darstellung und Reaktionen der 2.2.3-Trimethyl-cyclohexanon-(4)-carbonsäure

Zusammenfassung Die durch Einwirkung von konz. Schwefelsäure auf Camphandion-(2.3) in der Kälte entstehenden Substanzen werden durch Derivate charakterisiert und ihre Entstehung diskutiert.Herrn Professor Dr.Friedrich Asinger zum 60. Geburtstag gewidmet.Verstorben am 12. Dezember 1966.     

Über die Reaktionen von Guanidin bzw. Harnstoff mit Cyanhydrinen

Action of guanidine or urea on cyclohexanone-, cyclopentanone-, cycloheptanone-and acetonecyanohydrine3 a?3 d generates very different products: 3 a reacts with guanidine inDMF to yield 1,3-diazaspiro[4.5]decane-2,4-diimine (5 a). Heating the components without solvent affords 7,14-diazadispiro[5.1.5.2]pentadecan-15-one(7)^15–17, the guanidine not participating in the reaction; similarly3 b is transformed by guanidine to a pentacyclic dispirocompound (possible formulae19 and20), whereas3 d reacts to give 3,3,5,5-tetramethylpiperazine-2,6-dione(21)¹⁹. In 3-pentanone guanidine-cyanide condensates itself to give 2,4-diamino-triazine (22)^{21, 22}. Action of urea on3 a?3 d yields the 4-imino-1,3-diazaspiroalkan-2-ones6 a?6 c and the 4-imino-5,5-dimethylimidazolidin-2-one6 d ^6–8 resp. If the reaction of urea and3 d is carried out inDMF, however, 5,5-dimethyl-4-ureido-3-imidazolin-2-one (28) (or the tautomeric carbamoyliminoimidazolidinone27) is produced. The structures of the compounds prepared are proved by NMR-, IR- and mass spectra.     

Polarized recoil nuclei from nuclear reactions induced by polarized lithium ions

The production of vector polarized recoil nuclei was investigated for nuclear reactions initiated by vector polarized⁶Li and⁷Li beams of energies up to 20 MeV. The vector polarization was detected by theβ-asymmetry of the decaying recoil nuclei implanted into various stopper materials. Considerable polarization values were observed for⁸Li produced in the systems⁷Li+⁹Be,⁷Li+⁷Li and⁶Li+⁷Li, and for¹²B in the systems⁷Li+⁷Li and⁶Li+¹¹B. However, no polarization has been observed for heavier nuclei with unknown nuclear moments. The relaxation of the vector polarization of⁸Li implanted into various stopper materials at room temperature was investigated in detail. For a gold stopper it was found to be much larger when compared to earlier results.