Comparator for spectroscopic measurements using an interferometer and photoelectric scanning (cospinsca)

Summary A screw comparator has been modified into an automatic interference fringe counting comparator which allows determination of displacements with a precision of 0.25 micron.With a photoelectric setting device the reproducibility of setting on a photographic image of a symmetrical spectral line is about 0.5 micron. Automatic recording of fringe counting numbers and total light absorption by the line image is also provided for. The salient features of the apparatus are described and some results of measurements are discussed.     

Near‐wall profiles of mean flow and turbulence quantities predicted by eddy‐viscosity turbulence models

This paper presents for the simple flow over a flat plate the near‐wall profiles of mean flow and turbulence quantities determined with seven eddy‐viscosity turbulence models: the one‐equation turbulence models of Menter and Spalart & Allmaras; the k‐ω two‐equation model proposed by Wilcox and its TNT, BSL and SST variants and the $k-\sqrt{k}L$ two‐equation model. The results are obtained at several Reynolds numbers ranging from 10⁷ to 2.5 × 10⁹. Sets of nine geometrically similar Cartesian grids are adopted to demonstrate that the numerical uncertainty of the finest grid predictions is negligible. The profiles obtained numerically have relevance for the application of so‐called ‘wall function’ boundary conditions. Such wall functions refer to assumptions about the flow in the viscous sublayer and the ‘log law’ region. It turns out that these assumptions are not always satisfied by our results, which are obtained by computing the flow with full near‐wall resolution. In particular, the solution in the ‘log‐law’ region is dependent on the turbulence model and on the Reynolds number, which is a disconcerting result for those who apply wall functions. Copyright © 2009 John Wiley & Sons, Ltd.     

Contribution of steric and electrostatic repulsion forces to the stability of styrene latices copolymerized with acrylic acid

Acrylic acid (AA) is used in many emulsion polymerization formulations to improve the colloidal stability of the latex product. The improved stability originates from electrostatic repulsion complemented with steric repulsion. The strength of the electrostatic and steric repulsion forces in a styrene (S)/AA copolymer latex was investigated at different pH values, electrolyte concentrations, and temperatures. A comparison was made with an S homopolymer latex. Transmission electron microscopic pictures, combined with visual inspections, provided understanding of the mechanisms leading to coagulation in polystyrene (PS)/AA copolymer latices. Colloidal stability of the unswollen sodium dodecyl sulfate stabilized PS latex is based on electrostatic repulsion. Destabilization by sodium chloride resulted in aggregation. The acidic PS/AA latex remained stable against aggregation at high electrolyte concentrations because of steric repulsion. The acidic PS/AA latex showed a strong tendency to flocculate at increasing electrolyte concentrations. Flocculation was not observed for high‐pH PS/AA latices at high electrolyte concentrations. Steric repulsion of the acid PS/AA latex was lost at temperatures higher than the critical coagulation temperature (35 °C), and flocculation was followed by aggregation and coalescence. The high‐pH PS/AA latex was stable even at high electrolyte concentrations and temperatures up to 80 °C because of strong electrosteric stabilization. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2985–2995, 2003     

Pulsed laser deposition vs. matrix assisted pulsed laser evaporation for growth of biodegradable polymer thin films

Thin films of poly (lactide-co-glycolide) (PLGA), a biodegradable polymer, were deposited on Si wafers by both conventional pulsed laser deposition (PLD) and matrix assisted pulsed laser evaporation (MAPLE) using chloroform (CHCl₃) as a matrix solvent. This research represents an initial study to investigate the deposition characteristics of each technique at comparable conditions to gain insight into the transport and degradation mechanisms of each approach. The deposited materials were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (¹H NMR), and gel permeation chromatography (GPC) with refractive index (RI) detection. While FTIR and NMR results do not show a measurable departure from the native, in sharp contrast GPC results show a significant change (up to 95%) in molecular weight for both deposition methods. This result makes it clear that it is possible to overlook substantial degradation when incomplete chemical analysis is conducted.Optical transmission measurements of the starting MAPLE targets yielded laser penetration depths on the order of 0.362 cm and 0.209 cm for pure CHCl₃ and 1 wt. % PLGA in CHCl₃, respectively. Straightforward application of the Beer–Lambert law for laser energy deposition predicts a negligible temperature rise of less than 1 K at the target surface, which is in clear contradiction with ablation rates of 1.85 μm/pulse experimentally measured for polymer loaded samples. With an ablation process of this magnitude, the material ejection is likely due to contributions of nonlinear or non-homogeneous laser light absorption rather than evaporation. Severe non-uniformity of the final surface morphologies of the MAPLE films, similar to solvent wicking artifacts found in spin casting supports the spallation scenario in MAPLE. PACS 81.15.Fg; 79.20.Ds; 78.66.Qn; 42.70Jk     

On beam propagation methods for modelling in integrated optics

In this paper the main features of the Fourier transform and finite difference beam propagation methods are summarized. Limitations and improvements, related to the paraxial approximation, finite differencing and tilted structures are discussed. This revised version was published online in November 2006 with corrections to the Cover Date.     

Opposing effects of cation binding and hydration on the bending rigidity of anionic lipid bilayers

We correlate the molecularly realistic self-consistent field predictions for the mean bending modulus kc of charged lipid vesicles with experimental observations of the size R of corresponding vesicles that are produced by the freeze-thaw method. We elaborate on the Ansatz that the bending modulus is related to the membrane persistence length and that this length scale sets the radius of the vesicles. Alkali cations have a remarkable effect on the mean bending modulus and thus on the equilibrium radius of negatively charged entropically stabilized dioleoylphosphatidylglycerol (DOPG) vesicles. Where cation hydration typically results in thicker and thus stiffer membranes, specific adsorption to the bilayer surface results in a decrease of the surface charge density and the thickness of the membrane-associated electric double layer. As a result of these opposing effects on kc and R, the largest DOPG vesicles are found in the presence of K+, which combines an intermediate hydration enthalpy and PG-binding affinity.     

Benzin

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