Ketones derived from phyllocladene

Phyllocladene has been converted into some 15- and 16-oxo derivatives. The rotary dispersion curves of these indicate that XV is the most likely structure for mirene.     

First-order Kondo-frustated antiferromagnetic ordering in the heavy electron compound YbAs

¹⁷⁰Yb Mössbauer measurements show that the heavy electron compound YbAs undergoes a first order paramagnetic-antiferromagnetic transition centered at T_N=0.58K. The saturated 4f-shell magnetic moments are reduced by 47% relative to the value predicted by a crystal field model. A study of the line shapes below T_N in the presence of an external field shows that the RKKY exchange energy is about 20 times bigger than k_B T_N. These results show that YbAs presents a magnetic order frustrated by the Kondo effect.supported by CNPq     

Enumeration of matrices of given rank with submatrices of given rank

The authors determine the number of (n+m)×t matrices A¹ of rank r+v, over a finite field GF(q), whose last m rows are those of a given matrix A of rank r+v over GF(q) and whose first n rows have a given rank u.     

Intermolecular potential and second virial coefficient of the water-nitrogen complex

The authors construct a rigid-body (five-dimensional) potential energy surface for the water-nitrogen complex using the systematic intermolecular potential extrapolation routine. The intermolecular potential is then extrapolated to the limit of a complete basis set. An analytic fit of this surface is obtained, and, using this, the global minimum energy is found. The minimum is located in an arrangement in which N2 is near the H atom of H2O, almost collinear with the OH bond. The best estimate of the binding energy is 441 cm-1 (1 cm-1 approximately 1.986 43x10(-23) J). The extrapolated potential is then used to calculate the second cross virial coefficient over a wide temperature range (100-3000 K). These calculated second virial coefficients are generally consistent with experimental data, but for the most part the former have smaller uncertainties.     

Magnetic density of states at low energy in geometrically frustrated systems

Using muon-spin-relaxation measurements we show that the pyrochlore compound Gd(2)Ti(2)O(7), in its magnetically ordered phase below approximately 1 K, displays persistent spin dynamics down to temperatures as low as 20 mK. The characteristics of the induced muon relaxation can be accounted for by a scattering process involving two magnetic excitations, with a density of states characterized by an upturn at low energy and a small gap depending linearly on the temperature. We propose that such a density of states is a generic feature of geometrically frustrated magnetic materials.     

Measurement of H2O broadening of O2 A-band transitions and implications for atmospheric remote sensing

We present laboratory measurements of H(2)O-broadened (16)O(2) A-band (b(1)Σ(g)(+) ← X(3)Σ(g)(-)(0,0)) absorption spectra acquired with a laser-based photoacoustic spectroscopy method. This absorption band is widely used in a variety of high-precision atmospheric remote sensing applications. We report H(2)O broadening parameters for six of the strongest transitions in this band, and we show that these measured values are nominally 1.5-2 times greater than the corresponding air-broadening parameters. Simulations of atmospheric transmission spectra in the O(2) A-band that incorporate our measured H(2)O broadening parameters indicate that H(2)O present at concentrations typically found in the Earth's atmosphere can influence the column-integrated transmission relative to the dry air case. Further, because of spatial and seasonal variations in humidity, failure to account for the enhanced H(2)O pressure broadening effects can lead to concomitant biases in atmospheric O(2) A-band retrievals of quantities such as surface pressure and path length in greenhouse gas retrievals.