Infrared combination and difference bands of the NO dimer

The mid-infrared (1500-3800 cm⁻¹) absorption spectrum of gaseous nitric oxide has been studied at low temperature (99 K) with a long absorption path (160 m) in order to observe weak combination, difference, and overtone bands of the NO dimer. About ten new bands were assigned with greater or lesser certainty. Combined with previous results, they lead to a set of 12 secure and 7 tentative vibrational term values for (NO)₂, essentially doubling our knowledge of NO dimer vibrational states. The strongest non-fundamental bands in this region, other than the ν₁ (symmetric N-O stretch) + ν₅ (asymmetric N-O stretch) overtone, involve combinations of ν₅ with ν₃ (intermolecular stretch). Excitation of ν₅ results in increased frequencies for the intermolecular modes ν₂, ν₃, and ν₄. A new value of 155.5 cm⁻¹ was obtained for ν₄, the elusive infrared-inactive out-of-plane fundamental vibration.     

高温超导带材交流损耗的数值计算与分析

高温超导带材在许多领域得到越来越广泛的应用。交流损耗计算对于高温超导带材具有重要意义。该文介绍了两种交流损耗的数值计算模型,并以其中一种模型为例,对带材的交流损耗进行计算,与Norris公式计算结果作了比较,证明结果有效。最后提出了交流损耗数值计算中存在的问题。     

Testing the odontocete acoustic prey debilitation hypothesis: no stunning results

The hypothesis that sounds produced by odontocetes can debilitate fish was examined. The effects of simulated odontocete pulsed signals on three species of fish commonly preyed on by odontocetes were examined, exposing three individuals of each species as well as groups of four fish to a high-frequency click of a bottlenose dolphin [peak frequency (PF) 120 kHz, 213-dB peak-to-peak exposure level (EL)], a midfrequency click modeled after a killer whale's signal (PF 55 kHz, 208-dB EL), and a low-frequency click (PF 18 kHz, 193-dB EL). Fish were held in a 50-cm diameter net enclosure immediately in front of a transducer where their swimming behavior, orientation, and balance were observed with two video cameras. Clicks were presented at constant rates and in graded sweeps simulating a foraging dolphin's "terminal buzz." No measurable change in behavior was observed in any of the fish for any signal type or pulse modulation rate, despite the fact that clicks were at or near the maximum source levels recorded for odontocetes. Based on the results, the hypothesis that acoustic signals of odontocetes alone can disorient or "stun" prey cannot be supported.     

双折射调谐器设计的等色图原理

提出双折射调谐器设计的等色图方法，给出原理。分析表明当晶片光轴处在以折射光线为轴线、顶角为４５°的圆锥面上时，双折射调谐器具有最快的波长调谐速率；当光轴位于过折射光线并与入射面成４５°或１３５°的平面内时，调谐器抑制非所需波长的能力最强。由此给出光轴相对晶片表面的两个优化取向，对石英晶片它们分别为１８．７１２°和５９．９２２°。文中还给出了三块晶片组合的调谐器的设计例子，对其调谐特性进行了简要的讨论。     

高功率激光装置光传输管道污染规律及对光学表面损伤性能的影响

研究高功率激光装置光传输管道内部洁净度变化规律,分析其对内部重要光学元件光学性能的影响规律,提出污染控制措施。对光传输管道内部的气溶胶进行采样,并利用空气品质分析仪及扫描电镜对其进行分析,得到光传输管道内部洁净度变化规律和污染源;采用内部放置透射膜元件的方法,研究洁净度等级水平对透射膜的微观结构和透射率的影响,并利用"1-on-1"的测试方式进行透射膜元件的损伤阈值测试。研究结果表明:光传输管道内部的洁净度在激光辐照后迅速上升至万级水平,透射膜元件在此环境下其透过率严重下降,下降幅度为2.5%,且表面微观形貌发生变化。光学透射薄膜表面损伤阈值随表面污染水平呈现线性下降规律,最大下降幅度约为10%。污染监测和成分分析结果表明管道内部灰尘及杂散光或者鬼光束辐照金属产生的等离子体是管道内污染的主要源头,在此基础上提出了正压密封保持的技术手段确保内部光学表面洁净度水平,延长使用寿命。     

双δ激光脉冲作用下Paul阱中单离子的规则与混沌运动

考虑赝势近似下囚禁于Paul阱中的单离子与双δ脉冲型周期势相互作用系统的规则与混沌运动.应用积分方程方法得到系统的经典运动精确解,通过数值方法作出相空间轨道图和平均能量的时间演化曲线.结合分析与数值结果,发现两个有趣的结论.即在离子与单δ脉冲作用出现共振失稳的情形,在双δ脉冲作用下却出现了稳定的规则运动;离子随着双δ脉冲中两个脉冲之间的时间间隔减小而由规则运动转为混沌运动,其平均能量扩散的快慢与混沌运动的混乱程度相关.还研究了系统的共振失稳,发现通过调节激光波矢可以控制这种不稳定性.     

Cr~(4 )∶YAG能级结构的全量子力学计算

采用基于分子轨道理论CIS(ConfigurationInteractionofSinglySubstitution)的全量子力学方法计算了掺杂Ca和Cr离子的YAG晶体中 [CrO4 ]4 -团簇离子的能级结构。结果给出了Cr4 团簇 2 0个谱项能级随Cr -O键距的变化 ,对比表明在间距为 173pm时 ,能级结构在可见光及近红外范围的主要光谱特征与实验结果符合得较好     

Molecular dynamics study of mechanical properties of carbon nanotube-embedded gold composites

The mechanical properties of nano-single crystal gold and carbon nanotube-embedded gold (CNT/Au) composites under axial tension were investigated using molecular dynamics (MD) simulation method. The interactions between atoms were modeled using the many-body tight-binding (TB) potential and the empirical Tersoff potential coupled with the Lennard-Jones (L-J) potential. We get the yield strain and the yield stress of nano-single crystal gold 0.092, 5.74 GPa, respectively. The computational results show that the increase in Young's modulus of the long CNT-embedded gold composite over pure gold is much large. From the simulation, we also find that the yield stress and the yield strain of short CNT-embedded gold composite are evidently less than that of the nano-single crystal gold.     

Nature of magnetic coupling between Mn ions in As-grown Ga1-xMnxAs studied by X-ray magnetic circular dichroism

The magnetic properties of as-grown Ga1-xMnxAs have been investigated by the systematic measurements of temperature and magnetic field dependent soft x-ray magnetic circular dichroism (XMCD). The intrinsic XMCD intensity at high temperatures obeys the Curie-Weiss law, but a residual spin magnetic moment appears already around 100 K, significantly above the Curie temperature (T_{C}), suggesting that short-range ferromagnetic correlations are developed above T_{C}. The present results also suggest that the antiferromagnetic interaction between the substitutional and interstitial Mn (Mn_{int}) ions exists and that the amount of the Mn_{int} affects T_{C}.     

A novel thiourea-hydrazone-based switch-on fluorescent chemosensor for acetate

A novel sensor for acetate containing thiourea and hydrazone structure has been synthesized. The anion recognition via hydrogen-bonding interactions could be monitored by anion complexation, which induced changes in UV-vis and fluorescence spectra. In particular, the recognition process could be easily detected by the ‘naked-eye’. Further insights to the nature of interactions between receptor 1 and AcO⁻ were obtained by ¹H NMR titration experiments.