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931.
Highly Bright and Photostable Li(Gd,Y)F4:Yb,Er/LiGdF4 Core/Shell Upconversion Nanophosphors for Bioimaging Applications 下载免费PDF全文
Jeehae Shin Youngsun Kim Jiyeon Lee Sehoon Kim Ho Seong Jang 《Particle & Particle Systems Characterization》2017,34(1)
Intense green‐emitting Li(Gd,Y)F4:Yb,Er/LiGdF4 core/shell (C/S) upconversion nanophosphors (UCNPs) with a tetragonal bipyramidal morphology are synthesized. The morphology and UC luminescence of the Li(Gd,Y)F4:Yb,Er UCNPs are significantly affected by the Li precursors, and bright UC green‐emitting Li(Gd,Y)F4:Yb,Er UCNPs with a tetragonal bipyramidal shape, i.e., UC tetragonal bipyramids (UCTBs), are synthesized using LiOH·H2O as a Li precursor. A LiGdF4 shell is grown on the Li(Gd,Y)F4:Yb,Er UCTBs, and the C/S UCNPs exhibit 4.7 times higher luminescence intensity than core UCTBs. The C/S UCNPs show a high absolute UC quantum yield of 4.6% under excitation with 980 nm near infrared (NIR) light, and the UC luminescence from the C/S UCNPs is stable under continuous irradiation with the 980 nm NIR laser for 1 h. The hydrophobic surfaces of the as‐synthesized C/S UCNPs are modified to hydrophilic surfaces by using poly(acrylic acid) (PAA) for bioimaging applications. They are applied to human cervical adenocarcinoma (HeLa) cell imaging and SK‐MEL‐2 melanoma cell imaging and in vivo imaging, including subcutaneous and intramuscular imaging, and UC luminescence images with high signal‐to‐noise ratio are obtained. Furthermore, sentinel‐lymph‐node imaging is successfully conducted with the PAA‐capped Li(Gd,Y)F4:Yb,Er/LiGdF4 C/S UCNPs under illumination with NIR light. 相似文献
932.
Electric Field‐Aided Formation Combined with a Nanoimprinting Technique for Replicating a Plant Leaf
The surface of the taro plant leaf was replicated using a nanoimprinting technique (NIT) supplemented with an electric field. This field‐aided nanoimprinting method (FA‐NIT) consists of two steps: applying an electric field to a liquid polymer under the plant leaves and the curing process of the polymer with the applied electric field. An appropriate electric field was needed to induce the electrokinetic phenomena of a liquid polymer to obtain a good replicated surface. The roughness fabricated by the FA‐NIT was about 45% higher than the one prepared by NIT. The FA‐NIT method is a good supplementary technique to improve the quality of NIT.
933.
Junwon Han Byung Ho Jeon Chang Y. Ryu James J. Semler Young K. Jhon Jan Genzer 《Macromolecular rapid communications》2009,30(18):1543-1548
Interaction chromatography has been employed to validate that adsorption of poly[styrene‐co‐(4‐bromostyrene)] (PBrxS) random copolymers, where x denotes the mole fraction of 4‐bromostyrene (4–BrS) in PBrxS in solution depends on the average number of adsorptive segments, the type of adsorbing substrate, and on the co‐monomer sequence distribution in PBrxS.
934.
We have investigated the doubly excited 1,3
P
e resonance states of positronium negative ion with Coulomb and screened Coulomb potentials using highly accurate correlated
exponential wavefunctions. For Coulomb interaction, the stabilization and the complex-rotation methods are employed to extract
resonance parameters (resonance positions and widths). We have obtained two 1
P
e resonances and three 3
P
e resonances below the n = 3 Ps threshold. In addition to Feshbach resonances lying below n = 3 Ps threshold, we have calculated one 3
P
e shape resonances lying above the Ps (n = 2) threshold. For screened Coulomb (Yukawa) interaction, we employ the stabilization method to extract resonance parameters
as functions screening parameter. The resonance energies and widths for 1,3
P
e resonance states of Ps− below the n = 3 Ps threshold for different screening parameters ranging from infinity (Coulomb case) to small values are reported, along
with the Ps(3S) and Ps(3P) threshold energies. The screened Coulomb results for the 1,3
P
e resonance states are reported for the first time in the literature. 相似文献
935.
We present a systematic study of the structure, magnetization, resistivity, and Hall effect properties of pulsed laser deposited Fe- and Cu-codoped In2O3 and indium-tin-oxide (ITO) thin films. Both the films show a clear ferromagnetism and anomalous Hall effect at 300 K. The saturated magnetic moments are almost the same for the two samples, but their remanent moments Mr and coercive fields HC are quite different. Mr and HC values of ITO film are much smaller than that of In2O3. The ITO sample shows a typical semiconducting behavior in whole studied temperature range, while the In2O3 thin film is metallic in the temperature range between 147 and 285 K. Analysis of different conduction mechanisms suggest that charge carriers are not localized in the present films. The profile of the anomalous Hall effect vs. magnetic field was found to be identical to the magnetic hysteresis loops, indicating the possible intrinsic nature of ferromagnetism in the present samples. 相似文献
936.
Jeong Ho Ryu Hyong Sik Won Youn-Gon Park Sang Hyun Kim Won Young Song Hideo Suzuki Chulsoo Yoon 《Applied Physics A: Materials Science & Processing》2009,95(3):747-752
Rare-earth-doped oxynitride or nitride compounds have been reported to be photoluminescent and may then serve as new phosphors
because of their good thermal and chemical stabilities. In this work, Eu2+-doped β-SiAlON phosphor with a composition of Eu
x
Si6−z
Al
z
O
z
N8−z
(x=0.018, z=0.23) was prepared by gas-pressured solid state reaction. The crystallinity and particle morphology of the prepared phosphor
were characterized. The Stokes shift and zero-phonon line were calculated mathematically and estimated from the spectral data.
The temperature dependence of photoluminescence was measured from 25 to 250°C. The prepared Eu2+-doped β-SiAlON green phosphor showed superior thermal quenching property compared to silicate (SrBaSiO4:Eu2+) green phosphor. The white light-emitting diode (LED) back-lighting unit (BLU) using the prepared β-SiAlON:Eu2+ green phosphor exhibited higher color gamut than a commercial silicate phosphor. 相似文献
937.
A strip-shield improves the efficiency of a solenoid coil in probes for high-field solid-state NMR of lossy biological samples 总被引:1,自引:1,他引:0
Chin H. Wu Christopher V. Grant Gabriel A. Cook Sang Ho Park Stanley J. Opella 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2009,200(1):74-80
A strip-shield inserted between a high inductance double-tuned solenoid coil and the glass tube containing the sample improves the efficiency of probes used for high-field solid-state NMR experiments on lossy aqueous samples of proteins and other biopolymers. A strip-shield is a coil liner consisting of thin copper strips layered on a PTFE (polytetrafluoroethylene) insulator. With lossy samples, the shift in tuning frequency is smaller, the reduction in Q, and RF-induced heating are all significantly reduced when the strip-shield is present. The performance of 800 MHz 1H/15N and 1H/13C double-resonance probes is demonstrated on aqueous samples of membrane proteins in phospholipid bilayers. 相似文献
938.
T. William Bentley Robert O. Jones Dae Ho Kang In Sun Koo 《Journal of Physical Organic Chemistry》2009,22(9):799-806
Rate constants for a wide range of binary aqueous mixtures and product selectivities (S) in ethanol–water (EW) and methanol–water (MW) mixtures, are reported at 25 °C for solvolyses of benzenesulfonyl chloride and the 4‐chloro‐derivative. S is defined as follows using molar concentrations: S = ([ester product]/[acid product]) × ([water solvent]/[alcohol solvent]). Additional selectivity data are reported for solvolyses of 4‐Z‐substituted sulfonyl chlorides (Z = OMe, Me, H, Cl and NO2) in 2,2,2‐trifluoroethanol–water. To explain these results and previously published data on kinetic solvent isotope effects (KSIEs) and on other solvolyses of 4‐nitro and 4‐methoxybenzenesulfonyl chloride, a mechanistic spectrum involving a change from third order to second order is proposed. The molecularity of these reactions is discussed, along with new term ‘SN3–SN2 spectrum’ and its connection with the better established term ‘SN2–SN1 spectrum’. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
939.
CHEN Ying-Tian ZHANG Yang HU Sen Ho Tso-Hsiu Boon Ham Lim Chen Sin Lim Kok Keong Chong Boon Kok Tan 《理论物理通讯》2009,(10):750-760
In this article, we report the principle and conceptual design of a fundamentally different technology in fabricating high precision aberration free optical devices. The tip-tilt of facet in a mirror array is produced by digitally controlled line-tilts of rows and columns. It has not only provided a cost-effective designing methodology in optical physics but also led to a much finer precision of 1 mili arc sec or less. As examples of the application of the proposed digitalised optics, two case studies have been given: a 10 m Schmidt telescope (off-axis) and an 8 m Cassegrain telescope (on-axis). 相似文献
940.
C.H. Lin S.Y. Chen N.J. Ho D. Gan P. Shen 《Journal of Physics and Chemistry of Solids》2009,70(12):1505-1510
The α-Cr2O3 single-crystal nanocondensates were fabricated by pulsed laser ablation in air and characterized by analytical electron microscopy regarding shape-dependent local internal stress of the anisotropic crystal. The nanocondensates formed predominantly as rhombohedra with well-developed surfaces and occasionally hexagonal plate with thin edges and blunt corners. Such nanocondensates showed Raman shift for the CrO6 polyhedra, indicating a local compressive stress up to ca. 4 GPa on the average. Careful analysis of the lattice fringes revealed a local compressive stress (0.5% strain) at the thin edge of the hexagonal plates and a local tensile stress (0.3–1.0% strain) near the relaxed , , and (0 0 0 1) surfaces of truncated rhombohedra. The combined effects of nanosize, capillarity force at sharp edge, and specific surface relaxation account for the retention of a local internal compressive stress built up in an anisotropic crystal during a very rapid heating–cooling process. 相似文献