首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1437篇
  免费   26篇
  国内免费   8篇
化学   1099篇
晶体学   23篇
力学   20篇
数学   91篇
物理学   238篇
  2023年   6篇
  2022年   5篇
  2021年   6篇
  2020年   14篇
  2019年   25篇
  2018年   18篇
  2017年   13篇
  2016年   25篇
  2015年   30篇
  2014年   34篇
  2013年   86篇
  2012年   84篇
  2011年   88篇
  2010年   46篇
  2009年   65篇
  2008年   79篇
  2007年   78篇
  2006年   79篇
  2005年   81篇
  2004年   92篇
  2003年   83篇
  2002年   69篇
  2001年   24篇
  2000年   17篇
  1999年   14篇
  1998年   20篇
  1997年   22篇
  1996年   23篇
  1995年   14篇
  1993年   8篇
  1992年   9篇
  1991年   16篇
  1990年   14篇
  1989年   13篇
  1988年   8篇
  1987年   14篇
  1986年   6篇
  1985年   22篇
  1984年   9篇
  1983年   8篇
  1982年   6篇
  1981年   12篇
  1980年   10篇
  1979年   5篇
  1978年   7篇
  1977年   11篇
  1976年   8篇
  1975年   6篇
  1974年   6篇
  1973年   9篇
排序方式: 共有1471条查询结果,搜索用时 0 毫秒
991.
992.
We show the existence of weak solutions to the partial differential equation which describes the motion by R-curvature in R d , by the continuum limit of a class of infinite particle systems. We also show that weak solutions of the partial differential equation are viscosity solutions and give the uniqueness result on both weak and viscosity solutions.  相似文献   
993.
Photoinitiator-bound celluloses (Cell-AQ and Cell-BP) were prepared by reaction of epoxy-activated cellulose with, respectively, 1-aminoanthraquinone (AQNH2) and 4-aminobenzophenone (BPNH2) in N,N-dimethylformamide at 70°C. About 60% of the initial epoxy groups (1·90–2·10 mmol/(g cellulose)) was found to participate in the reaction under alkaline conditions. The photoinitiator-bound celluloses exhibited an activity towards photoinduced formation of hydrogen peroxide in aqueous solutions of -glucose, and isopropyl alcohol. The amount of hydrogen peroxide formed was higher for the Cell-BP than the Cell-AQ. Moreover, the photoinitiator-bound celluloses showed an ability to initiate photografting of methyl methacrylate at 60°C in a water medium, indicating a higher percentage of grafting and a lower percentage of homopolymer compared to photoinitiator-sensitized celluloses, which were prepared by immersing a cellulose sample in acetone solutions of AQNH2 and BPNH2 and drying under vacuum to remove the solvent. It was found that the photoinitiator residues introduced into the cellulose substrate are capable of abstracting hydrogen atoms from the substrate.  相似文献   
994.
The 1- and 4-substituted-5H-benzo[a]phenoxazin-5-ones (substitutents: nitro, amino and acetylamino) were prepared by the condensation of o-aminophenol with 5-substituted-2,3-dichloro-1,4-naphthoquinones. The resulting compounds were subjected to reduction, acetylation and dehalogenation.  相似文献   
995.
996.
Within grinding machines the load acting on the particles and the loading rate are widely distributed. According to studies on the breakage mechanism of brittle materials, the mechanical properties which relate to breakage vary with the loading rate. In order to elucidate the grinding mechanism within the grinding machines, it is necessary to obtain the relationships between these properties and loading rate. In this study, the variation of strength, fracture energy, new surface area produced by fracture and fracture energy with the loading rate (ranging from 10?1 to 109 N/s) was investigated by means of compression tests on a large number of spherical specimens. As a result, a singularity of crushing behavior was observed under an impact loading corresponding to a duration of time of loading the same as the natural period of the spherical specimen. The crushing efficiency is especially at its maximum.  相似文献   
997.
Present Status of Industrial Application of Cyclodextrins in Japan   总被引:2,自引:0,他引:2  
The application of CDs in the food, cosmetic and textile industrial fields as solubilizing agents, stabilizers, emulsifiers etc., is reviewed briefly. ManyCD-containing commodities that have been put to practical use are introduced. Technical developments of CDs and their commercialization have had a multilateral impact on economic activities in our country. The expansiveeffects of CD production on other industrial fields and the economic impactare discussed.  相似文献   
998.
The γ-radiolysis behavior of poly(l-chloro-1-alkynes) \[ [\rlap{--} ({\rm CCI} = {\rm CR}\rlap{--} )_n ;{\rm R} = n - {\rm alkyl}] \] greatly changed with the length of alkyl group and with the presence or absence of oxygen. When γ-irradiated in air, poly(l-chloro-1-hexyne) (R = n-C4H9) decomposed to oligomers; its Gs value was as large as 5.4. When irradiated in vacuum, this polymer partly gelled. In contrast, poly(l-chloro-1-decyne) (R = n-C8H17) partly gelled even by irradiation in air. A high-dose irradiation of this polymer in vacuum resulted in the quantitative formation of a gel. The polymers irradiated in air contained carbonyl and hydroxyl groups, indicating the participation of oxidation reaction. Comparison with their thermolysis leads to a conclusion that these Cl-containing polyacetylenes are radiation-sensitive irrespective of their high thermal stability.  相似文献   
999.
There is discordant information in the literature on the composition of the zirconium-arsenazo complex in solution. A detailed spectrophotometric study indicates that at pH 1.3, 1.7 and 3.5 the complex is formed by one mole of zirconium reacting with one mole of arsenazo (R), giving the empirical formula ZrR.  相似文献   
1000.
Electric conductivity variations of undoped, n-type and p-type hydrogenated amorphous silicon (a-Si:H) thin films irradiated with various energy protons are systematically investigated. Dark conductivity (DC) and photoconductivity (PC) of the undoped samples increase at first due to proton irradiation and then decrease dramatically with increasing proton fluence. The increase in DC and PC becomes greater with increased proton energy. However, this increase is metastable and gradually decreases with time at room temperature. Similar results are observed in the n-type a-Si:H, whereas only a monotonic decrease is observed in DC and PC for the p-type samples. The increase of both DC and PC due to proton irradiation is attributed to metastable donor center generation. On further irradiation both the DC and PC decrease by the accumulation of radiation-induced defects, which act as deep traps and compensate carriers. The decrease in DC and PC becomes less pronounced as the proton energy increase and can be fitted along a universal line when the proton fluence is converted into displacement per atom (dpa).  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号